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Energy Express

Energy Express

  • Editor: Bernard Kippelen
  • Vol. 20, Iss. S2 — Mar. 12, 2012
  • pp: A360–A365

Photocatalytic alkoxylation of benzene with 3-cyano-1-methylquinolinium ion

Kei Ohkubo, Takaki Kobayashi, and Shunichi Fukuzumi  »View Author Affiliations


Optics Express, Vol. 20, Issue S2, pp. A360-A365 (2012)
http://dx.doi.org/10.1364/OE.20.00A360


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Abstract

One-pot alkoxylation of benzene with alcohols occurs under photoirradiation of 3-cyano-1-methylquinolinium ion in an oxygen-saturated acetonitrile solution containing benzene and alcohols. The photocatalytic reaction mechanism was clarified by nanosecond laser flash photolysis. The photocataytic alkoxylation of benzene is initiated by photoinduced electron transfer from benzene to the singlet excited state of 3-cyano-1-methylquinolinium ion, followed by the nucleophilic addition of alcohols to benzene radical cation. In the case of photoethoxylation, the optimal product and quantum yields of ethoxybenzene were 20% and 10%, respectively.

© 2012 OSA

OCIS Codes
(140.3450) Lasers and laser optics : Laser-induced chemistry
(260.5130) Physical optics : Photochemistry

ToC Category:
Photocatalysis

History
Original Manuscript: December 1, 2011
Revised Manuscript: January 19, 2012
Manuscript Accepted: January 20, 2012
Published: March 9, 2012

Citation
Kei Ohkubo, Takaki Kobayashi, and Shunichi Fukuzumi, "Photocatalytic alkoxylation of benzene with 3-cyano-1-methylquinolinium ion," Opt. Express 20, A360-A365 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-S2-A360


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