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Observation of unusual optical transitions in thin-film Cu(In,Ga)Se2 solar cellsYu-Kuang Liao, Shou-Yi Kuo, Woei-Tyng Lin, Fang-I Lai, Dan-Hua Hsieh, Min-An Tsai, Shih-Chen Chen, Ding-Wen Chiou, Jen-Chuang Chang, Kaung-Hsiung Wu, Shun-Jen Cheng, and Hao-Chung Kuo »View Author Affiliations
Yu-Kuang Liao,1,4
Shou-Yi Kuo,2,*
Woei-Tyng Lin,3
Fang-I Lai,3
Dan-Hua Hsieh,5
Min-An Tsai,6
Shih-Chen Chen,1
Ding-Wen Chiou,4
Jen-Chuang Chang,4
Kaung-Hsiung Wu,1
Shun-Jen Cheng,1
and Hao-Chung Kuo5,7
1Department of Electro-Physics, National Chiao-Tung University, Hsinchu, Taiwan 2Department of Electronic Engineering, Chang-Gung University,Taoyuan, Taiwan 3Department of Photonic Engineering, Yuan-Ze University, Taoyuan, Taiwan 4Compound Semiconductor Solar Cell Department, Next Generation Solar Cell Division, Green Energy and Environment Research Laboratories, Industrial Technology Research Institute, Hsinchu, Taiwan 5Department of Photonics and Institute of Electro-Optical Engineering, National Chiao-Tung University, Hsinchu, Taiwan 6Photovoltaic Metrology Laboratory, Energy & Environment Metrology Division, Center for Measurement Standards, Industrial Technology Research Institute, Hsinchu, Taiwan 7hckuo@faculty.nctu.edu.tw *Corresponding author: sykuo@mail.cgu.edu.tw |
Optics Express, Vol. 20, Issue S6, pp. A836-A842 (2012)
http://dx.doi.org/10.1364/OE.20.00A836
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Abstract
In this paper, we examine photoluminescence spectra of Cu(In,Ga)Se2 (CIGS) via temperature-dependent and power-dependent photoluminescence (PL). Donor-acceptor pair (DAP) transition, near-band-edge transition were identified by their activation energies. S-shaped displacement of peak position was observed and was attributed to carrier confinement caused by potential fluctuation. This coincides well with the obtained activation energy at low temperature. We also present a model for transition from VSe to VIn and to VCu which illustrates competing mechanisms between DAPs recombinations.
© 2012 OSA
OCIS Codes
(350.6050) Other areas of optics : Solar energy
(160.5335) Materials : Photosensitive materials
ToC Category:
Photovoltaics
History
Original Manuscript: August 20, 2012
Revised Manuscript: September 19, 2012
Manuscript Accepted: September 20, 2012
Published: September 28, 2012
Citation
Yu-Kuang Liao, Shou-Yi Kuo, Woei-Tyng Lin, Fang-I Lai, Dan-Hua Hsieh, Min-An Tsai, Shih-Chen Chen, Ding-Wen Chiou, Jen-Chuang Chang, Kaung-Hsiung Wu, Shun-Jen Cheng, and Hao-Chung Kuo, "Observation of unusual optical transitions in thin-film Cu(In,Ga)Se2 solar cells," Opt. Express 20, A836-A842 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-S6-A836
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References
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- K. Romannathan, M. A. Contreras, C. L. Perkins, S. Asher, F. S. Hasoon, J. Keane, D. Young, M. Romero, W. Metzger, R. Noufi, J. Ward, and A. Duda, “Properties of 19.2% efficiency ZnO/CdS/CuInGaSe2 thin-film solar cells,” Prog. Photovolt. Res. Appl. 11(4), 225–230 (2003). [CrossRef]
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- A. Bell, S. Srinivasan, C. Plumlee, H. Omiya, F. A. Ponce, J. Christen, S. Tanaka, A. Fujioka, and Y. Nakagawa, “Exciton freeze-out and thermally activated relaxation at local potential fluctuations in thick AlxGa1?xN layers,” J. Appl. Phys. 95(9), 4670–4674 (2004). [CrossRef]
- K. Yoshino, H. Yokoyama, K. Maeda, T. Ikari, A. Fukuyama, P. J. Fons, A. Yamada, and S. Niki, “Optical characterizations of CuInSe2 epitaxial layers grown by molecular beam epitaxy,” J. Appl. Phys. 86(8), 4354–4359 (1999). [CrossRef]
- M. A. Contreras, A. M. Gabor, A. L. Tennant, S. Asher, J. Tuttle, and R. Noufi, “16.4% total-area conversion efficiency thin-film polycrystalline MgF2/ZnO/CdS/Cu(In,Ga)Se2/Mo solar cell,” Prog. Photovolt. Res. Appl. 2(4), 287–292 (1994). [CrossRef]
- Y. H. Cho, G. H. Gainer, A. J. Fischer, J. J. Song, S. Keller, U. K. Mishra, and S. P. DenBaars, ““S-shaped” temperature dependent emission shift and carrier dynamics in InGaN/GaN multiple quantum wells,” Appl. Phys. Lett. 73(10), 1370–1372 (1998). [CrossRef]
- M. Leroux, N. Grandjean, B. Beaumont, G. Nataf, F. Semond, J. Massies, and P. Gibart, “Temperature quenching of photoluminescence intensities in undoped and doped GaN,” J. Appl. Phys. 86(7), 3721–3728 (1999). [CrossRef]
- M. Leroux, N. Grandjean, B. Beaumont, G. Nataf, F. Semond, J. Massies, and P. Gibart, “Temperature quenching of photoluminescence intensities in undoped and doped GaN,” J. Appl. Phys. 86(7), 3721–3728 (1999). [CrossRef]
- A. V. Mudryi, V. F. Gremenok, I. A. Victorov, V. B. Zalesski, F. V. Kurdesov, V. I. Kovalevski, M. V. Yakushev, and R. W. Martin, “Optical characterisation of high-quality CuInSe2 thin films synthesised by two-stage selenisation process,” Thin Solid Films 431–432, 193–196 (2003). [CrossRef]
- T. P. Hsieh, C. C. Chuang, C. S. Wu, J. C. Chang, J. W. Guo, and W. C. Chen, “Effects of residual copper selenide on CuInGaSe2 solar cells,” Solid-State Electron. 56(1), 175–178 (2011). [CrossRef]
- S. I. Jung, K. H. Yoon, S. Ahn, J. Gwak, and J. H. Yun, “Fabrication and characterization of wide band-gap CuGaSe2 thin films for tandem structure,” Curr. Appl. Phys. 10(3), S395–S398 (2010). [CrossRef]
- J. Wu, W. Walukiewicz, K. M. Yu, J. W. Ager, E. E. Haller, H. Lu, W. J. Schaff, Y. Saito, and Y. Nanishi, “Unusual properties of fundamental band gap of InN,” Appl. Phys. Lett. 80(21), 3967–3969 (2002). [CrossRef]
- P. Jackson, D. Hariskos, E. Lotter, S. Paetel, R. Wuerz, R. Menner, W. Wischmann, and M. Powalla, “New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20%,” Prog. Photovolt. Res. Appl. 19(7), 894–897 (2011). [CrossRef]
- K. Romannathan, M. A. Contreras, C. L. Perkins, S. Asher, F. S. Hasoon, J. Keane, D. Young, M. Romero, W. Metzger, R. Noufi, J. Ward, and A. Duda, “Properties of 19.2% efficiency ZnO/CdS/CuInGaSe2 thin-film solar cells,” Prog. Photovolt. Res. Appl. 11(4), 225–230 (2003). [CrossRef]
- I. Dirnstorfer, D. M. Hofmann, D. Meister, B. K. Meyer, W. Riedl, and F. Karg, “Postgrowth thermal treatment of CuIn(Ga)Se2: Characterization of doping levels in In-rich thin films,” J. Appl. Phys. 85(3), 1423–1428 (1999). [CrossRef]
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- Y. P. Varshni, “Temperature dependence of the energy gap in semiconductors,” Physica 34(1), 149–154 (1967). [CrossRef]
- A. V. Mudryi, V. F. Gremenok, I. A. Victorov, V. B. Zalesski, F. V. Kurdesov, V. I. Kovalevski, M. V. Yakushev, and R. W. Martin, “Optical characterisation of high-quality CuInSe2 thin films synthesised by two-stage selenisation process,” Thin Solid Films 431–432, 193–196 (2003). [CrossRef]
- M. Wagner, I. Dirnstorfer, D. M. Hofmann, M. D. Lampert, F. Karg, and B. K. Meyer, “Characterization of Cu(In,Ga)Se2 thin films I. Cu-rich layers,” Phys. Status Solidi, A Appl. Res. 167(1), 131–142 (1998). [CrossRef]
- J. Wu, W. Walukiewicz, K. M. Yu, J. W. Ager, E. E. Haller, H. Lu, W. J. Schaff, Y. Saito, and Y. Nanishi, “Unusual properties of fundamental band gap of InN,” Appl. Phys. Lett. 80(21), 3967–3969 (2002). [CrossRef]
- K. Romannathan, M. A. Contreras, C. L. Perkins, S. Asher, F. S. Hasoon, J. Keane, D. Young, M. Romero, W. Metzger, R. Noufi, J. Ward, and A. Duda, “Properties of 19.2% efficiency ZnO/CdS/CuInGaSe2 thin-film solar cells,” Prog. Photovolt. Res. Appl. 11(4), 225–230 (2003). [CrossRef]
- K. Töpper, J. Bruns, R. Scheer, M. Weber, A. Weidinger, and D. Bräunig, “Photoluminescence of CuInS2 thin films and solar cells modified by postdeposition treatments,” Appl. Phys. Lett. 71(4), 482–484 (1997). [CrossRef]
- K. Töpper, J. Bruns, R. Scheer, M. Weber, A. Weidinger, and D. Bräunig, “Photoluminescence of CuInS2 thin films and solar cells modified by post deposition treatments,” Appl. Phys. Lett. 71(4), 482–484 (1997). [CrossRef]
- S. B. Zhang, S. H. Wei, A. Zunger, and H. Katayama-Yoshida, “Defect physics of the CuInSe2 chalcopyrite semiconductor,” Phys. Rev. B 57(16), 9642–9656 (1998). [CrossRef]
- K. Töpper, J. Bruns, R. Scheer, M. Weber, A. Weidinger, and D. Bräunig, “Photoluminescence of CuInS2 thin films and solar cells modified by postdeposition treatments,” Appl. Phys. Lett. 71(4), 482–484 (1997). [CrossRef]
- K. Töpper, J. Bruns, R. Scheer, M. Weber, A. Weidinger, and D. Bräunig, “Photoluminescence of CuInS2 thin films and solar cells modified by post deposition treatments,” Appl. Phys. Lett. 71(4), 482–484 (1997). [CrossRef]
- J. Mattheis, U. Rau, and J. H. Werner, “Light absorption and emission in semiconductors with band gap fluctuations-A study on Cu(In,Ga)Se2 thin films,” J. Appl. Phys. 101(11), 113519 (2007). [CrossRef]
- P. Jackson, D. Hariskos, E. Lotter, S. Paetel, R. Wuerz, R. Menner, W. Wischmann, and M. Powalla, “New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20%,” Prog. Photovolt. Res. Appl. 19(7), 894–897 (2011). [CrossRef]
- T. P. Hsieh, C. C. Chuang, C. S. Wu, J. C. Chang, J. W. Guo, and W. C. Chen, “Effects of residual copper selenide on CuInGaSe2 solar cells,” Solid-State Electron. 56(1), 175–178 (2011). [CrossRef]
- J. Wu, W. Walukiewicz, K. M. Yu, J. W. Ager, E. E. Haller, H. Lu, W. J. Schaff, Y. Saito, and Y. Nanishi, “Unusual properties of fundamental band gap of InN,” Appl. Phys. Lett. 80(21), 3967–3969 (2002). [CrossRef]
- S. C. Chen, Y. K. Liao, H. J. Chen, C. H. Chen, C. H. Lai, Y. L. Chueh, H. C. Kuo, K. H. Wu, J. Y. Juang, S. J. Cheng, T. P. Hsieh, and T. Kobayashi, “Ultrafast carrier dynamics in Cu(In,Ga)Se2 thin films probed by femtosecond pump-probe spectroscopy,” Opt. Express 20(12), 12675–12681 (2012). [CrossRef]
- P. Jackson, D. Hariskos, E. Lotter, S. Paetel, R. Wuerz, R. Menner, W. Wischmann, and M. Powalla, “New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20%,” Prog. Photovolt. Res. Appl. 19(7), 894–897 (2011). [CrossRef]
- A. V. Mudryi, V. F. Gremenok, I. A. Victorov, V. B. Zalesski, F. V. Kurdesov, V. I. Kovalevski, M. V. Yakushev, and R. W. Martin, “Optical characterisation of high-quality CuInSe2 thin films synthesised by two-stage selenisation process,” Thin Solid Films 431–432, 193–196 (2003). [CrossRef]
- K. Yoshino, H. Yokoyama, K. Maeda, T. Ikari, A. Fukuyama, P. J. Fons, A. Yamada, and S. Niki, “Optical characterizations of CuInSe2 epitaxial layers grown by molecular beam epitaxy,” J. Appl. Phys. 86(8), 4354–4359 (1999). [CrossRef]
- T. Yamaguchi, J. Matsufusa, and A. Yoshida, “Optical properties in RF sputtered CuInxGa1?xSe2 thin films,” Appl. Surf. Sci. 70-71, 669–674 (1993). [CrossRef]
- M. J. Romero, H. Du, G. Teeter, Y. Yan, and M. M. Al-Jassin, “Comparative study of luminescence and intrinsic point defects in kesterite Cu2ZnSnS4 and chalcopyrite Cu(In,Ga)Se2 thin films used in photovoltaic applications,” Phys. Rev. B 84(16), 165324 (2011). [CrossRef]
- E. Kuokstis, W. H. Sun, M. Shatalov, J. W. Yang, and M. Asif Khan, “Role of alloy fluctuations in photoluminescence dynamics of AlGaN epilayers,” Appl. Phys. Lett. 88(26), 261905 (2006). [CrossRef]
- K. Yoshino, H. Yokoyama, K. Maeda, T. Ikari, A. Fukuyama, P. J. Fons, A. Yamada, and S. Niki, “Optical characterizations of CuInSe2 epitaxial layers grown by molecular beam epitaxy,” J. Appl. Phys. 86(8), 4354–4359 (1999). [CrossRef]
- S. I. Jung, K. H. Yoon, S. Ahn, J. Gwak, and J. H. Yun, “Fabrication and characterization of wide band-gap CuGaSe2 thin films for tandem structure,” Curr. Appl. Phys. 10(3), S395–S398 (2010). [CrossRef]
- T. Yamaguchi, J. Matsufusa, and A. Yoshida, “Optical properties in RF sputtered CuInxGa1?xSe2 thin films,” Appl. Surf. Sci. 70-71, 669–674 (1993). [CrossRef]
- K. Yoshino, H. Yokoyama, K. Maeda, T. Ikari, A. Fukuyama, P. J. Fons, A. Yamada, and S. Niki, “Optical characterizations of CuInSe2 epitaxial layers grown by molecular beam epitaxy,” J. Appl. Phys. 86(8), 4354–4359 (1999). [CrossRef]
- K. Romannathan, M. A. Contreras, C. L. Perkins, S. Asher, F. S. Hasoon, J. Keane, D. Young, M. Romero, W. Metzger, R. Noufi, J. Ward, and A. Duda, “Properties of 19.2% efficiency ZnO/CdS/CuInGaSe2 thin-film solar cells,” Prog. Photovolt. Res. Appl. 11(4), 225–230 (2003). [CrossRef]
- J. Wu, W. Walukiewicz, K. M. Yu, J. W. Ager, E. E. Haller, H. Lu, W. J. Schaff, Y. Saito, and Y. Nanishi, “Unusual properties of fundamental band gap of InN,” Appl. Phys. Lett. 80(21), 3967–3969 (2002). [CrossRef]
- S. I. Jung, K. H. Yoon, S. Ahn, J. Gwak, and J. H. Yun, “Fabrication and characterization of wide band-gap CuGaSe2 thin films for tandem structure,” Curr. Appl. Phys. 10(3), S395–S398 (2010). [CrossRef]
- N. Rega, S. Siebentritt, J. Albert, S. Nishiwaki, A. Zajogin, M. Ch. Lux-Steiner, R. Kniese, and M. J. Romero, “Excitonic luminescence of Cu(In,Ga)Se2,” Thin Solid Films 480–481, 286–290 (2005). [CrossRef]
- A. V. Mudryi, V. F. Gremenok, I. A. Victorov, V. B. Zalesski, F. V. Kurdesov, V. I. Kovalevski, M. V. Yakushev, and R. W. Martin, “Optical characterisation of high-quality CuInSe2 thin films synthesised by two-stage selenisation process,” Thin Solid Films 431–432, 193–196 (2003). [CrossRef]
- S. B. Zhang, S. H. Wei, A. Zunger, and H. Katayama-Yoshida, “Defect physics of the CuInSe2 chalcopyrite semiconductor,” Phys. Rev. B 57(16), 9642–9656 (1998). [CrossRef]
- S. B. Zhang, S. H. Wei, A. Zunger, and H. Katayama-Yoshida, “Defect physics of the CuInSe2 chalcopyrite semiconductor,” Phys. Rev. B 57(16), 9642–9656 (1998). [CrossRef]
Appl. Phys. Lett.
- K. Töpper, J. Bruns, R. Scheer, M. Weber, A. Weidinger, and D. Bräunig, “Photoluminescence of CuInS2 thin films and solar cells modified by postdeposition treatments,” Appl. Phys. Lett. 71(4), 482–484 (1997). [CrossRef]
- E. Kuokstis, W. H. Sun, M. Shatalov, J. W. Yang, and M. Asif Khan, “Role of alloy fluctuations in photoluminescence dynamics of AlGaN epilayers,” Appl. Phys. Lett. 88(26), 261905 (2006). [CrossRef]
- Y. H. Cho, G. H. Gainer, A. J. Fischer, J. J. Song, S. Keller, U. K. Mishra, and S. P. DenBaars, ““S-shaped” temperature dependent emission shift and carrier dynamics in InGaN/GaN multiple quantum wells,” Appl. Phys. Lett. 73(10), 1370–1372 (1998). [CrossRef]
- J. Wu, W. Walukiewicz, K. M. Yu, J. W. Ager, E. E. Haller, H. Lu, W. J. Schaff, Y. Saito, and Y. Nanishi, “Unusual properties of fundamental band gap of InN,” Appl. Phys. Lett. 80(21), 3967–3969 (2002). [CrossRef]
- K. Töpper, J. Bruns, R. Scheer, M. Weber, A. Weidinger, and D. Bräunig, “Photoluminescence of CuInS2 thin films and solar cells modified by post deposition treatments,” Appl. Phys. Lett. 71(4), 482–484 (1997). [CrossRef]
- U. Rau, “Tunneling-enhanced recombination in CuInGaSe2 heterojunction solar cells,” Appl. Phys. Lett. 74(1), 111–113 (1999). [CrossRef]
Appl. Surf. Sci.
- T. Yamaguchi, J. Matsufusa, and A. Yoshida, “Optical properties in RF sputtered CuInxGa1?xSe2 thin films,” Appl. Surf. Sci. 70-71, 669–674 (1993). [CrossRef]
Curr. Appl. Phys.
- S. I. Jung, K. H. Yoon, S. Ahn, J. Gwak, and J. H. Yun, “Fabrication and characterization of wide band-gap CuGaSe2 thin films for tandem structure,” Curr. Appl. Phys. 10(3), S395–S398 (2010). [CrossRef]
J. Appl. Phys.
- J. Mattheis, U. Rau, and J. H. Werner, “Light absorption and emission in semiconductors with band gap fluctuations-A study on Cu(In,Ga)Se2 thin films,” J. Appl. Phys. 101(11), 113519 (2007). [CrossRef]
- K. Yoshino, H. Yokoyama, K. Maeda, T. Ikari, A. Fukuyama, P. J. Fons, A. Yamada, and S. Niki, “Optical characterizations of CuInSe2 epitaxial layers grown by molecular beam epitaxy,” J. Appl. Phys. 86(8), 4354–4359 (1999). [CrossRef]
- M. Leroux, N. Grandjean, B. Beaumont, G. Nataf, F. Semond, J. Massies, and P. Gibart, “Temperature quenching of photoluminescence intensities in undoped and doped GaN,” J. Appl. Phys. 86(7), 3721–3728 (1999). [CrossRef]
- A. Bell, S. Srinivasan, C. Plumlee, H. Omiya, F. A. Ponce, J. Christen, S. Tanaka, A. Fujioka, and Y. Nakagawa, “Exciton freeze-out and thermally activated relaxation at local potential fluctuations in thick AlxGa1?xN layers,” J. Appl. Phys. 95(9), 4670–4674 (2004). [CrossRef]
- I. Dirnstorfer, D. M. Hofmann, D. Meister, B. K. Meyer, W. Riedl, and F. Karg, “Postgrowth thermal treatment of CuIn(Ga)Se2: Characterization of doping levels in In-rich thin films,” J. Appl. Phys. 85(3), 1423–1428 (1999). [CrossRef]
Opt. Express
- S. C. Chen, Y. K. Liao, H. J. Chen, C. H. Chen, C. H. Lai, Y. L. Chueh, H. C. Kuo, K. H. Wu, J. Y. Juang, S. J. Cheng, T. P. Hsieh, and T. Kobayashi, “Ultrafast carrier dynamics in Cu(In,Ga)Se2 thin films probed by femtosecond pump-probe spectroscopy,” Opt. Express 20(12), 12675–12681 (2012). [CrossRef]
Phys. Rev.
- D. G. Thomas, J. J. Hopfield, and W. M. Augustyniak, “Kinetics of radiative recombination at randomly distributed donors and acceptors,” Phys. Rev. 140(1A), A202–A220 (1965). [CrossRef]
Phys. Rev. B
- S. B. Zhang, S. H. Wei, A. Zunger, and H. Katayama-Yoshida, “Defect physics of the CuInSe2 chalcopyrite semiconductor,” Phys. Rev. B 57(16), 9642–9656 (1998). [CrossRef]
- M. J. Romero, H. Du, G. Teeter, Y. Yan, and M. M. Al-Jassin, “Comparative study of luminescence and intrinsic point defects in kesterite Cu2ZnSnS4 and chalcopyrite Cu(In,Ga)Se2 thin films used in photovoltaic applications,” Phys. Rev. B 84(16), 165324 (2011). [CrossRef]
Phys. Status Solidi, A Appl. Res.
- M. Wagner, I. Dirnstorfer, D. M. Hofmann, M. D. Lampert, F. Karg, and B. K. Meyer, “Characterization of Cu(In,Ga)Se2 thin films I. Cu-rich layers,” Phys. Status Solidi, A Appl. Res. 167(1), 131–142 (1998). [CrossRef]
Phys. Status Solidi., C Curr. Top. Solid State Phys.
- S. Shirakata and T. Nakada, “Photoluminescence and time-resolved photoluminescence in Cu(In,Ga)Se2 thin films and solar cells,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 6(5), 1059–1062 (2009). [CrossRef]
Physica
- Y. P. Varshni, “Temperature dependence of the energy gap in semiconductors,” Physica 34(1), 149–154 (1967). [CrossRef]
Prog. Photovolt. Res. Appl.
- P. Jackson, D. Hariskos, E. Lotter, S. Paetel, R. Wuerz, R. Menner, W. Wischmann, and M. Powalla, “New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20%,” Prog. Photovolt. Res. Appl. 19(7), 894–897 (2011). [CrossRef]
- M. A. Contreras, A. M. Gabor, A. L. Tennant, S. Asher, J. Tuttle, and R. Noufi, “16.4% total-area conversion efficiency thin-film polycrystalline MgF2/ZnO/CdS/Cu(In,Ga)Se2/Mo solar cell,” Prog. Photovolt. Res. Appl. 2(4), 287–292 (1994). [CrossRef]
- K. Romannathan, M. A. Contreras, C. L. Perkins, S. Asher, F. S. Hasoon, J. Keane, D. Young, M. Romero, W. Metzger, R. Noufi, J. Ward, and A. Duda, “Properties of 19.2% efficiency ZnO/CdS/CuInGaSe2 thin-film solar cells,” Prog. Photovolt. Res. Appl. 11(4), 225–230 (2003). [CrossRef]
Sol. Energy Mater. Sol. Cells
- S. Shirakata, K. Ohkubo, Y. Ishii, and T. Nakada, “Effects of CdS buffer layers on photoluminescence properties of Cu(In,Ga)Se2 solar cells,” Sol. Energy Mater. Sol. Cells 93(6-7), 988–992 (2009). [CrossRef]
- J. H. Schon and E. Bucher, “Comparison of point defects in CuInSe2 and CuGaSe2 single crystals,” Sol. Energy Mater. Sol. Cells 57(3), 229–237 (1999). [CrossRef]
Sol. Energy Sol. Cells.
- S. Siebentritt, “What limits the efficiency of chalcopyrite solar cells?” Sol. Energy Sol. Cells. 95(6), 1471–1476 (2011). [CrossRef]
Solid-State Electron.
- T. P. Hsieh, C. C. Chuang, C. S. Wu, J. C. Chang, J. W. Guo, and W. C. Chen, “Effects of residual copper selenide on CuInGaSe2 solar cells,” Solid-State Electron. 56(1), 175–178 (2011). [CrossRef]
Thin Solid Films
- N. Rega, S. Siebentritt, J. Albert, S. Nishiwaki, A. Zajogin, M. Ch. Lux-Steiner, R. Kniese, and M. J. Romero, “Excitonic luminescence of Cu(In,Ga)Se2,” Thin Solid Films 480–481, 286–290 (2005). [CrossRef]
- A. V. Mudryi, V. F. Gremenok, I. A. Victorov, V. B. Zalesski, F. V. Kurdesov, V. I. Kovalevski, M. V. Yakushev, and R. W. Martin, “Optical characterisation of high-quality CuInSe2 thin films synthesised by two-stage selenisation process,” Thin Solid Films 431–432, 193–196 (2003). [CrossRef]
- U. Raw, A. Jasenek, H. W. Schock, F. Engelhardt, and Th. Meyer, “Electronic loss mechanisms in chalcopyrite based heterojunction solar cells,” Thin Solid Films 361–362, 298–302 (2000).
Other
- B. M. Keyes, P. Dippo, W. Metzger, J. AbuShama, and R. Noufi, “Cu(In,Ga)Se2 thin films evolution during growth – a photoluminescence study,” Proceeding of the 29th IEEE Phot. Spec. Conf., 511–514 (2002).
2012, Chen, Opt. Express
- S. C. Chen, Y. K. Liao, H. J. Chen, C. H. Chen, C. H. Lai, Y. L. Chueh, H. C. Kuo, K. H. Wu, J. Y. Juang, S. J. Cheng, T. P. Hsieh, and T. Kobayashi, “Ultrafast carrier dynamics in Cu(In,Ga)Se2 thin films probed by femtosecond pump-probe spectroscopy,” Opt. Express 20(12), 12675–12681 (2012). [CrossRef]
- P. Jackson, D. Hariskos, E. Lotter, S. Paetel, R. Wuerz, R. Menner, W. Wischmann, and M. Powalla, “New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20%,” Prog. Photovolt. Res. Appl. 19(7), 894–897 (2011). [CrossRef]
- T. P. Hsieh, C. C. Chuang, C. S. Wu, J. C. Chang, J. W. Guo, and W. C. Chen, “Effects of residual copper selenide on CuInGaSe2 solar cells,” Solid-State Electron. 56(1), 175–178 (2011). [CrossRef]
- M. J. Romero, H. Du, G. Teeter, Y. Yan, and M. M. Al-Jassin, “Comparative study of luminescence and intrinsic point defects in kesterite Cu2ZnSnS4 and chalcopyrite Cu(In,Ga)Se2 thin films used in photovoltaic applications,” Phys. Rev. B 84(16), 165324 (2011). [CrossRef]
- S. Siebentritt, “What limits the efficiency of chalcopyrite solar cells?” Sol. Energy Sol. Cells. 95(6), 1471–1476 (2011). [CrossRef]
- S. I. Jung, K. H. Yoon, S. Ahn, J. Gwak, and J. H. Yun, “Fabrication and characterization of wide band-gap CuGaSe2 thin films for tandem structure,” Curr. Appl. Phys. 10(3), S395–S398 (2010). [CrossRef]
- S. Shirakata, K. Ohkubo, Y. Ishii, and T. Nakada, “Effects of CdS buffer layers on photoluminescence properties of Cu(In,Ga)Se2 solar cells,” Sol. Energy Mater. Sol. Cells 93(6-7), 988–992 (2009). [CrossRef]
- S. Shirakata and T. Nakada, “Photoluminescence and time-resolved photoluminescence in Cu(In,Ga)Se2 thin films and solar cells,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 6(5), 1059–1062 (2009). [CrossRef]
- J. Mattheis, U. Rau, and J. H. Werner, “Light absorption and emission in semiconductors with band gap fluctuations-A study on Cu(In,Ga)Se2 thin films,” J. Appl. Phys. 101(11), 113519 (2007). [CrossRef]
- E. Kuokstis, W. H. Sun, M. Shatalov, J. W. Yang, and M. Asif Khan, “Role of alloy fluctuations in photoluminescence dynamics of AlGaN epilayers,” Appl. Phys. Lett. 88(26), 261905 (2006). [CrossRef]
- N. Rega, S. Siebentritt, J. Albert, S. Nishiwaki, A. Zajogin, M. Ch. Lux-Steiner, R. Kniese, and M. J. Romero, “Excitonic luminescence of Cu(In,Ga)Se2,” Thin Solid Films 480–481, 286–290 (2005). [CrossRef]
- A. Bell, S. Srinivasan, C. Plumlee, H. Omiya, F. A. Ponce, J. Christen, S. Tanaka, A. Fujioka, and Y. Nakagawa, “Exciton freeze-out and thermally activated relaxation at local potential fluctuations in thick AlxGa1?xN layers,” J. Appl. Phys. 95(9), 4670–4674 (2004). [CrossRef]
- A. V. Mudryi, V. F. Gremenok, I. A. Victorov, V. B. Zalesski, F. V. Kurdesov, V. I. Kovalevski, M. V. Yakushev, and R. W. Martin, “Optical characterisation of high-quality CuInSe2 thin films synthesised by two-stage selenisation process,” Thin Solid Films 431–432, 193–196 (2003). [CrossRef]
- K. Romannathan, M. A. Contreras, C. L. Perkins, S. Asher, F. S. Hasoon, J. Keane, D. Young, M. Romero, W. Metzger, R. Noufi, J. Ward, and A. Duda, “Properties of 19.2% efficiency ZnO/CdS/CuInGaSe2 thin-film solar cells,” Prog. Photovolt. Res. Appl. 11(4), 225–230 (2003). [CrossRef]
- J. Wu, W. Walukiewicz, K. M. Yu, J. W. Ager, E. E. Haller, H. Lu, W. J. Schaff, Y. Saito, and Y. Nanishi, “Unusual properties of fundamental band gap of InN,” Appl. Phys. Lett. 80(21), 3967–3969 (2002). [CrossRef]
- U. Raw, A. Jasenek, H. W. Schock, F. Engelhardt, and Th. Meyer, “Electronic loss mechanisms in chalcopyrite based heterojunction solar cells,” Thin Solid Films 361–362, 298–302 (2000).
- U. Rau, “Tunneling-enhanced recombination in CuInGaSe2 heterojunction solar cells,” Appl. Phys. Lett. 74(1), 111–113 (1999). [CrossRef]
- I. Dirnstorfer, D. M. Hofmann, D. Meister, B. K. Meyer, W. Riedl, and F. Karg, “Postgrowth thermal treatment of CuIn(Ga)Se2: Characterization of doping levels in In-rich thin films,” J. Appl. Phys. 85(3), 1423–1428 (1999). [CrossRef]
- J. H. Schon and E. Bucher, “Comparison of point defects in CuInSe2 and CuGaSe2 single crystals,” Sol. Energy Mater. Sol. Cells 57(3), 229–237 (1999). [CrossRef]
- K. Yoshino, H. Yokoyama, K. Maeda, T. Ikari, A. Fukuyama, P. J. Fons, A. Yamada, and S. Niki, “Optical characterizations of CuInSe2 epitaxial layers grown by molecular beam epitaxy,” J. Appl. Phys. 86(8), 4354–4359 (1999). [CrossRef]
- M. Leroux, N. Grandjean, B. Beaumont, G. Nataf, F. Semond, J. Massies, and P. Gibart, “Temperature quenching of photoluminescence intensities in undoped and doped GaN,” J. Appl. Phys. 86(7), 3721–3728 (1999). [CrossRef]
- M. Wagner, I. Dirnstorfer, D. M. Hofmann, M. D. Lampert, F. Karg, and B. K. Meyer, “Characterization of Cu(In,Ga)Se2 thin films I. Cu-rich layers,” Phys. Status Solidi, A Appl. Res. 167(1), 131–142 (1998). [CrossRef]
- Y. H. Cho, G. H. Gainer, A. J. Fischer, J. J. Song, S. Keller, U. K. Mishra, and S. P. DenBaars, ““S-shaped” temperature dependent emission shift and carrier dynamics in InGaN/GaN multiple quantum wells,” Appl. Phys. Lett. 73(10), 1370–1372 (1998). [CrossRef]
- S. B. Zhang, S. H. Wei, A. Zunger, and H. Katayama-Yoshida, “Defect physics of the CuInSe2 chalcopyrite semiconductor,” Phys. Rev. B 57(16), 9642–9656 (1998). [CrossRef]
- K. Töpper, J. Bruns, R. Scheer, M. Weber, A. Weidinger, and D. Bräunig, “Photoluminescence of CuInS2 thin films and solar cells modified by postdeposition treatments,” Appl. Phys. Lett. 71(4), 482–484 (1997). [CrossRef]
- K. Töpper, J. Bruns, R. Scheer, M. Weber, A. Weidinger, and D. Bräunig, “Photoluminescence of CuInS2 thin films and solar cells modified by post deposition treatments,” Appl. Phys. Lett. 71(4), 482–484 (1997). [CrossRef]
- M. A. Contreras, A. M. Gabor, A. L. Tennant, S. Asher, J. Tuttle, and R. Noufi, “16.4% total-area conversion efficiency thin-film polycrystalline MgF2/ZnO/CdS/Cu(In,Ga)Se2/Mo solar cell,” Prog. Photovolt. Res. Appl. 2(4), 287–292 (1994). [CrossRef]
- T. Yamaguchi, J. Matsufusa, and A. Yoshida, “Optical properties in RF sputtered CuInxGa1?xSe2 thin films,” Appl. Surf. Sci. 70-71, 669–674 (1993). [CrossRef]
- Y. P. Varshni, “Temperature dependence of the energy gap in semiconductors,” Physica 34(1), 149–154 (1967). [CrossRef]
- D. G. Thomas, J. J. Hopfield, and W. M. Augustyniak, “Kinetics of radiative recombination at randomly distributed donors and acceptors,” Phys. Rev. 140(1A), A202–A220 (1965). [CrossRef]
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- Investigating Charge Carrier Mobilities in Nanocrystal-Polymer Hybrid Photovoltaic Devices
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