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Optics Express

Optics Express

  • Editor: Andrew M. Weiner
  • Vol. 21, Iss. 1 — Jan. 14, 2013
  • pp: 1030–1040

Pr3+-doped heavy metal germanium tellurite glasses for irradiative light source in minimally invasive photodynamic therapy surgery

J. Yang, B. J. Chen, E. Y. B. Pun, B. Zhai, and H. Lin  »View Author Affiliations


Optics Express, Vol. 21, Issue 1, pp. 1030-1040 (2013)
http://dx.doi.org/10.1364/OE.21.001030


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Abstract

Pr3+-doped medium-low phonon energy heavy metal germanium tellurite (NZPGT) glasses have been fabricated and the intense multi-peak red fluorescence emissions of Pr3+ are exhibited. Judd-Ofelt parameters Ω2 = 3.14 × 10−20cm2, Ω4 = 10.67 × 10−20cm2 and Ω6 = 3.95 × 10−20cm2 indicate a high asymmetrical and covalent environment in the optical glasses. The spontaneous emission probabilities Aij corresponding to the 1D23H4, 3P03H6, and 3P03F2 transitions are derived to be 1859.6, 6270.1 and 17276.3s−1, respectively, and the relevant stimulated emission cross-sections σem are 5.20 × 10−21, 14.14 × 10−21 and 126.77 × 10−21cm2, confirming that the effectiveness of the red luminescence in Pr3+-doped NZPGT glasses. Under the commercial blue LED excitation, the radiant flux and the quantum yield for the red fluorescence of Pr3+ are solved to be 219μW and 11.80%, respectively. 85.24% photons of the fluorescence in the visible region are demonstrated to be located in 600−720nm wavelength range, which matches the excitation band of the most photosensitizers (PS), holding great promise for photodynamic therapy (PDT) treatment and clinical trials.

© 2013 OSA

OCIS Codes
(060.2310) Fiber optics and optical communications : Fiber optics
(160.5690) Materials : Rare-earth-doped materials
(250.5230) Optoelectronics : Photoluminescence

ToC Category:
Medical Optics and Biotechnology

History
Original Manuscript: November 15, 2012
Revised Manuscript: December 21, 2012
Manuscript Accepted: December 24, 2012
Published: January 9, 2013

Virtual Issues
Vol. 8, Iss. 2 Virtual Journal for Biomedical Optics

Citation
J. Yang, B. J. Chen, E. Y. B. Pun, B. Zhai, and H. Lin, "Pr3+-doped heavy metal germanium tellurite glasses for irradiative light source in minimally invasive photodynamic therapy surgery," Opt. Express 21, 1030-1040 (2013)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-21-1-1030


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