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Optics Express

Optics Express

  • Editor: Andrew M. Weiner
  • Vol. 21, Iss. 10 — May. 20, 2013
  • pp: 12849–12864

The three-electron bond =Si<O2:∙Yb absorption center of pre-darkened ytterbium-doped silica

Kent E. Mattsson  »View Author Affiliations


Optics Express, Vol. 21, Issue 10, pp. 12849-12864 (2013)
http://dx.doi.org/10.1364/OE.21.012849


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Abstract

The formation and bleaching of color centers during annealing of pre-darkened ytterbium-doped silica fibers is modeled by three-electron bond (TEB) = Si<O2:∙Yb absorption centers. The nature of a center and underlying mechanism for its annealing in formation, shift and dissociation of chemical bonds is described in terms of a Markov statistical model with state change set by Bose-Einstein phonon statistics. The center hold one terminal and four active states with activation energies for transitions among these found to match bond energies of molecular oxygen in ionic character bonds of 1 and 1½ bond order. Experimentally observed in- and decrease in absorption during ramp and isothermal annealing of pre-darkened ytterbium co-doped silica fibers are hereby matched by a set of = Si<O2:∙Yb centers.

© 2013 OSA

OCIS Codes
(060.2290) Fiber optics and optical communications : Fiber materials
(060.2320) Fiber optics and optical communications : Fiber optics amplifiers and oscillators

ToC Category:
Fiber Optics and Optical Communications

History
Original Manuscript: March 25, 2013
Revised Manuscript: May 7, 2013
Manuscript Accepted: May 10, 2013
Published: May 17, 2013

Citation
Kent E. Mattsson, "The three-electron bond =Si<O2:∙Yb absorption center of pre-darkened ytterbium-doped silica," Opt. Express 21, 12849-12864 (2013)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-21-10-12849


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References

  1. Y.-S. Liu, T. C. Galvin, T. Hawkins, J. Ballato, L. Dong, P. R. Foy, P. D. Dragic, and J. G. Eden, “Linkage of oxygen deficiency defects and rare earth concentrations in silica glass optical fiber probed by ultraviolet absorption and laser excitation spectroscopy,” Opt. Express20(13), 14494–14507 (2012). [CrossRef] [PubMed]
  2. K. E. Mattsson, “Photo darkening of rare earth doped silica,” Opt. Express19(21), 19797–19812 (2011). [CrossRef] [PubMed]
  3. S. Yoo, C. Basu, A. J. Boyland, C. Sones, J. Nilsson, J. K. Sahu, and D. Payne, “Photodarkening in Yb-doped aluminosilicate fibers induced by 488 nm irradiation,” Opt. Lett.32(12), 1626–1628 (2007). [CrossRef] [PubMed]
  4. M. Engholm and L. Norin, “Preventing photodarkening in ytterbium-doped high power fiber lasers; correlation to the UV-transparency of the core glass,” Opt. Express16(2), 1260–1268 (2008). [CrossRef] [PubMed]
  5. L. Skuja, “Optically active oxygen-deficiency-related centers in amorphous silicon dioxide,” J. Non-Cryst. Solids239(1–3), 16–48 (1998). [CrossRef]
  6. S. Girard, Y. Ouerdane, B. Tortech, C. Marcandella, T. Robin, B. Dadier, J. Baggio, P. Paillet, V. Ferlet-Cavrois, A. Boukenter, J.-P. Meunier, J. R. Schwank, M. R. Shaneyfelt, P. E. Dodd, and E. W. Blackmore, “Radiation Effects on ytterbium- and Ytterbium/erbium-Doped Double-Clad Optical Fibers,” IEEE Trans. Nucl. Sci.56(6), 3293–3299 (2009). [CrossRef]
  7. T. Deschamps, H. Vezin, C. Gonnet, and N. Ollier, “Evidence of AlOHC responsible for the radiation-induced darkening in Yb doped fiber,” Opt. Express21(7), 8382–8392 (2013). [CrossRef] [PubMed]
  8. R. Schnadt and J. Schneider, “The Electronic Structure of the Trapped-Hole Center in Smoky Quartz,” Phys. Kondens. Materie11, 19–42 (1970).
  9. S. Jetschke and U. Röpke, “Power-law dependence of the photodarkening rate constant on the inversion in Yb doped fibers,” Opt. Lett.34(1), 109–111 (2009). [CrossRef] [PubMed]
  10. S. Yoo, A. J. Boyland, R. J. Standish, and J. K. Sahu, “Measurement of photodarkening in Yb-doped aluminosilicate fibres at elevated temperature,” Electron. Lett.46(3), 233–244 (2010). [CrossRef]
  11. M. J. Söderlund, J. J. Montiel i Ponsoda, J. P. Koplow, and S. Honkanen, “Heat-induced darkening and spectral broadening in photodarkened ytterbium-doped fiber under thermal cycling,” Opt. Express17(12), 9940–9946 (2009). [CrossRef] [PubMed]
  12. M. Leich, U. Röpke, S. Jetschke, S. Unger, V. Reichel, and J. Kirchhof, “Non-isothermal bleaching of photodarkened Yb-doped fibers,” Opt. Express17(15), 12588–12593 (2009). [CrossRef] [PubMed]
  13. M. J. Söderlund, J. J. Montiel i Ponsoda, J. P. Koplow, and S. Honkanen, “Thermal bleaching of photodarkening-induced loss in ytterbium-doped fibers,” Opt. Lett.34(17), 2637–2639 (2009). [CrossRef] [PubMed]
  14. L. Pauling, “The nature of silicon-oxygen bonds,” Am. Mineral.65, 321 (1980).
  15. V. O. Sokolov and V. B. Sulimov, “Threefold coordinated oxygen atom in silica glass,” J. Non-Cryst. Solids217(2–3), 167–172 (1997). [CrossRef]
  16. C. C. Robinson and J. T. Fournier, “Co-ordination of Yb3+ in phosphate, silicate, and germinate glasses,” J. Phys. Chem. Solids31(5), 895–904 (1970). [CrossRef]
  17. D. L. Griscom, E. J. Friebele, K. J. Long, and J. W. Fleming, “Fundamental defect centers in glass: Electron spin resonance and optical absorption studies of irradiated phosphorous-doped silica glass and optical fibers,” J. Appl. Phys.54(7), 3743–3762 (1983). [CrossRef]
  18. P. H. Krupenie, “The spectrum of molecular oxygen,” J. Phys. Chem. Ref. Data1(2), 423–534 (1972). [CrossRef]
  19. Table of periodic properties of the Elements, Sargent-Welch, Skokie, IL, (1980).
  20. A. V. Kimmel, P. V. Sushko, and A. L. Shluger, “Structure and spectroscopic properties of trapped holes in silica,” J. Non-Cryst. Solids353(5-7), 599–604 (2007). [CrossRef]
  21. A. F. Holleman, E. Wiberg, and N. Wiberg, Inorganic Chemistry (Academic Press, 2001) p.131.
  22. K. Arai, H. Namikawa, K. Kumata, T. Honda, Y. Ishii, and T. Handa, “Aluminum or phosphorous co-doping effects on the fluorescence and structural properties of neodymium-doped silica glass,” J. Appl. Phys.59(10), 3430 (1986). [CrossRef]
  23. M. J. Söderlund, J. J. Montiel i Ponsoda, J. P. Koplow, and S. Honkanen, “Thermal bleaching of photodarkening in ytterbium-doped fibers,” Proc. SPIE7580, 75800B, 75800B-8 (2010). [CrossRef]

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