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InGaN working electrodes with assisted bias generated from GaAs solar cells for efficient water splitting

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Abstract

Hydrogen generation through water splitting by n-InGaN working electrodes with bias generated from GaAs solar cell was studied. Instead of using an external bias provided by power supply, a GaAs-based solar cell was used as the driving force to increase the rate of hydrogen production. The water-splitting system was tuned using different approaches to set the operating points to the maximum power point of the GaAs solar cell. The approaches included changing the electrolytes, varying the light intensity, and introducing the immersed ITO ohmic contacts on the working electrodes. As a result, the hybrid system comprising both InGaN-based working electrodes and GaAs solar cells operating under concentrated illumination could possibly facilitate efficient water splitting.

© 2013 Optical Society of America

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Figures (5)

Fig. 1
Fig. 1 Schematic layer structures of the working electrodes.
Fig. 2
Fig. 2 The experimental setup of water splitting via the n-InGaN photoanode with assisted bias generated from GaAs solar cell.
Fig. 3
Fig. 3 (a)typical photocurrents with different electrolytes were marked on the I-V curve of the GaAs solar cell (b) typical spectral response taken from the PEC cells with working electrode made of n-In0.15Ga0.85N/n-GaN heterostructure.
Fig. 4
Fig. 4 Typical photocurrents obtained with different incident light intensities were marked on the I-V curve of the GaAs solar cell.
Fig. 5
Fig. 5 Typical photocurrents of the PEC cells with and without the immersed ITO fingers were marked on the I-V curve of the GaAs solar cell.
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