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Optics Express

Optics Express

  • Editor: Andrew M. Weiner
  • Vol. 21, Iss. 13 — Jul. 1, 2013
  • pp: 15904–15911

Precise phasing of 2D-electronic spectra in a fully non-collinear phase-matching geometry

Franz Milota, Craig N. Lincoln, and Jürgen Hauer  »View Author Affiliations


Optics Express, Vol. 21, Issue 13, pp. 15904-15911 (2013)
http://dx.doi.org/10.1364/OE.21.015904


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Abstract

We report an experimental design for two-dimensional electronic spectroscopy (2D-ES) that avoids the need to measure notoriously weak pump-probe spectra. Retaining a fully non-collinear folded boxcar geometry, the described layout replaces pump-probe with heterodyned transient grating (het-TG). The absorptive component of the het-TG signal is measured directly, following a straightforward optimization routine. The use of het-TG achieves an improvement in signal to noise ratio by almost two orders of magnitude. As a result, 2D-ES-signals down to 0.5% can be clearly resolved.

© 2013 OSA

OCIS Codes
(300.6290) Spectroscopy : Spectroscopy, four-wave mixing
(300.6300) Spectroscopy : Spectroscopy, Fourier transforms
(300.6530) Spectroscopy : Spectroscopy, ultrafast

ToC Category:
Spectroscopy

History
Original Manuscript: May 7, 2013
Revised Manuscript: June 5, 2013
Manuscript Accepted: June 7, 2013
Published: June 25, 2013

Citation
Franz Milota, Craig N. Lincoln, and Jürgen Hauer, "Precise phasing of 2D-electronic spectra in a fully non-collinear phase-matching geometry," Opt. Express 21, 15904-15911 (2013)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-21-13-15904


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