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Optics Express

Optics Express

  • Editor: Andrew M. Weiner
  • Vol. 22, Iss. 10 — May. 19, 2014
  • pp: 11436–11445

Surface plasmon enhanced photoluminescence of ZnO nanorods by capping reduced graphene oxide sheets

Feng Han, Shuming Yang, Weixuan Jing, Kyle Jiang, Zhuangde Jiang, Huan Liu, and Lei Li  »View Author Affiliations

Optics Express, Vol. 22, Issue 10, pp. 11436-11445 (2014)

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A hybrid structure of reduced graphene oxide (rGO) sheets/ZnO nanorods was prepared and its photoluminescence intensity ratio between the UV and defect emission was enhanced up to 14 times. By controlling the reduction degree of rGO on the surface of ZnO nanorods, the UV emission was tuned with the introduction of localized surface plasmons resonance of rGO sheets. The suppression of the defect emission was ascribed to the charge transfer and decreased with the distance between the rGO and ZnO nanorods.

© 2014 Optical Society of America

OCIS Codes
(160.4670) Materials : Optical materials
(240.6680) Optics at surfaces : Surface plasmons
(260.2510) Physical optics : Fluorescence

ToC Category:

Original Manuscript: February 26, 2014
Revised Manuscript: April 14, 2014
Manuscript Accepted: April 29, 2014
Published: May 5, 2014

Virtual Issues
Vol. 9, Iss. 7 Virtual Journal for Biomedical Optics

Feng Han, Shuming Yang, Weixuan Jing, Kyle Jiang, Zhuangde Jiang, Huan Liu, and Lei Li, "Surface plasmon enhanced photoluminescence of ZnO nanorods by capping reduced graphene oxide sheets," Opt. Express 22, 11436-11445 (2014)

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  1. C. W. Lai, J. An, H. C. Ong, “Surface-plasmon-mediated emission from metal-capped ZnO thin films,” Appl. Phys. Lett. 86(25), 251105 (2005). [CrossRef]
  2. J. B. You, X. W. Zhang, Y. M. Fan, S. Qu, N. F. Chen, “Surface plasmon enhanced ultraviolet emission from ZnO films deposited on Ag Si (001) by magnetron sputtering,” Appl. Phys. Lett. 91(23), 231907 (2007). [CrossRef]
  3. A. P. Abiyasa, S. F. Yu, S. P. Lau, E. S. P. Leong, H. Y. Yang, “Enhancement of ultraviolet lasing from Ag-coated highly disordered ZnO films by surface-plasmon resonance,” Appl. Phys. Lett. 90(23), 231106 (2007).
  4. T. Chen, G. Z. Xing, Z. Zhang, H. Y. Chen, T. Wu, “Tailoring the photoluminescence of ZnO nanowires using Au nanoparticles,” Nanotechnology 19(43), 435711 (2008). [CrossRef] [PubMed]
  5. P. H. Cheng, D. S. Li, Z. Z. Yuan, P. L. Chen, D. Yang, “Enhancement of ZnO light emission via coupling with localized surface plasmon of Ag island film,” Appl. Phys. Lett. 92(4), 041119 (2008). [CrossRef]
  6. K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, A. A. Firsov, “Electric field effect in atomically thin carbon films,” Science 306(5696), 666–669 (2004). [CrossRef] [PubMed]
  7. A. K. Geim, K. S. Novoselov, “The rise of graphene,” Nat. Mater. 6(3), 183–191 (2007). [CrossRef] [PubMed]
  8. X. Wang, L. J. Zhi, N. Tsao, Z. Tomović, J. L. Li, K. Müllen, “Transparent carbon films as electrodes in organic solar cells,” Angew. Chem. Int. Ed. Engl. 47(16), 2990–2992 (2008). [CrossRef] [PubMed]
  9. X. Wang, L. J. Zhi, K. Müllen, “Transparent, conductive graphene electrodes for dye-sensitized solar cells,” Nano Lett. 8(1), 323–327 (2008). [CrossRef] [PubMed]
  10. Y. P. Zhang, H. B. Li, L. K. Pan, T. Lu, Z. Sun, “Capacitive behavior of graphene–ZnO composite film for supercapacitors,” J. Electroanal. Chem. 634(1), 68–71 (2009). [CrossRef]
  11. F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, K. S. Novoselov, “Detection of individual gas molecules adsorbed on graphene,” Nat. Mater. 6(9), 652–655 (2007). [CrossRef] [PubMed]
  12. J. M. Lin, H. Y. Lin, C. L. Cheng, Y. F. Chen, “Giant enhancement of bandgap emission of ZnO nanorods by platinum nanoparticles,” Nanotechnology 17(17), 4391–4394 (2006). [CrossRef]
  13. S. W. Hwang, D. H. Shin, C. O. Kim, S. H. Hong, M. C. Kim, J. Kim, K. Y. Lim, S. Kim, S. H. Choi, K. J. Ahn, G. Kim, S. H. Sim, B. H. Hong, “Plasmon-enhanced ultraviolet photoluminescence from hybrid structures of graphene/ZnO films,” Phys. Rev. Lett. 105(12), 127403 (2010). [CrossRef] [PubMed]
  14. K. Kim, S. M. Lee, Y. S. Do, S. Il Ahn, K. C. Choi, “Enhanced photoluminescence from zinc oxide by plasmonic resonance of reduced graphene oxide,” J. Appl. Phys. 114(7), 074903 (2013). [CrossRef]
  15. W. X. Jing, B. Wang, L. L. Niu, Z. D. Jiang, H. Qi, L. J. Chen, F. Zhou, “Effects of synthesizing parameters on surface roughness and contact angles of ZnO nanowire films,” J. Nanosci. Nanotechnol. 13, 1–6 (2013). [PubMed]
  16. W. S. Hummers, R. E. Offeman, “Preparation of graphitic oxide,” J. Am. Chem. Soc. 80(6), 1339 (1958). [CrossRef]
  17. L. J. Cote, F. Kim, J. X. Huang, “Langmuir-blodgett assembly of graphite oxide single layers,” J. Am. Chem. Soc. 131(3), 1043–1049 (2009). [CrossRef] [PubMed]
  18. Q. B. Zheng, W. H. Ip, X. Y. Lin, N. Yousefi, K. K. Yeung, Z. G. Li, J. K. Kim, “Transparent conductive films consisting of ultralarge graphene sheets produced by Langmuir-Blodgett assembly,” ACS Nano 5(7), 6039–6051 (2011). [CrossRef] [PubMed]
  19. Y. Gao, X. Q. Chen, H. Xu, Y. L. Zou, R. P. Gu, M. S. Xu, A. K. Y. Jen, H. Z. Chen, “Highly-efficient fabrication of nanoscrolls from functionalized graphene oxide by Langmuir–Blodgett method,” Carbon 48(15), 4475–4482 (2010). [CrossRef]
  20. S. Stankovich, D. A. Dikin, R. D. Piner, K. A. Kohlhaas, A. Kleinhammes, Y. Y. Jia, Y. Wu, S. T. Nguyen, R. S. Ruoff, “Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide,” Carbon 45(7), 1558–1565 (2007). [CrossRef]
  21. M. J. McAllister, J. L. Li, D. H. Adamson, H. C. Schniepp, A. A. Abdala, J. Liu, M. Herrera-Alonso, D. L. Milius, R. Car, R. K. Prud’homme, I. A. Aksay, “Single sheet functionalized graphene by oxidation and thermal expansion of graphite,” Chem. Mater. 19(18), 4396–4404 (2007). [CrossRef]
  22. D. X. Yang, A. Velamakanni, G. Bozoklu, S. Park, M. Stoller, R. D. Piner, S. Stankovich, I. Jung, D. A. Field, C. A. Ventrice, R. S. Ruoff, “Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy,” Carbon 47(1), 145–152 (2009). [CrossRef]
  23. L. E. Greene, M. Law, J. Goldberger, F. Kim, J. C. Johnson, Y. F. Zhang, R. J. Saykally, P. D. Yang, “Low-temperature wafer-scale production of ZnO nanowire arrays,” Angew. Chem. Int. Ed. Engl. 42(26), 3031–3034 (2003). [CrossRef] [PubMed]
  24. D. Li, Y. H. Leung, A. B. Djurisi, Z. T. Liu, M. H. Xie, S. L. Shi, S. J. Xu, W. K. Chan, “Different origins of visible luminescence in ZnO nanostructures fabricated by the chemical and evaporation methods,” Appl. Phys. Lett. 85(9), 1601 (2004). [CrossRef]
  25. H. Zhou, H. Alves, D. M. Hofmann, W. Kriegseis, B. K. Meyer, G. Kaczmarczyk, A. Hoffmann, “Behind the weak excitonic emission of ZnO quantum dots: ZnO/Zn(OH)2 core-shell structure,” Appl. Phys. Lett. 80(2), 210 (2002). [CrossRef]
  26. X. Liu, X. Wu, H. Cao, R. P. H. Chang, “Growth mechanism and properties of ZnO nanorods synthesized by plasma-enhanced chemical vapor deposition,” J. Appl. Phys. 95(6), 3141–3147 (2004). [CrossRef]
  27. R. Xie, T. Sekiguchi, T. Ishigaki, N. Ohashi, D. Li, D. Yang, B. Liu, Y. Bando, “Enhancement and patterning of ultraviolet emission in ZnO with an electron beam,” Appl. Phys. Lett. 88(13), 134103 (2006). [CrossRef]
  28. V. Singh, D. Joung, L. Zhai, S. Das, S. I. Khondaker, S. Seal, “Graphene based materials: Past, present and future,” Prog. Mater. Sci. 56(8), 1178–1271 (2011). [CrossRef]
  29. K. Mkhoyan, A. W. Contryman, J. Silcox, D. A. Stewart, G. Eda, C. Mattevi, S. Miller, M. Chhowalla, “Atomic and electronic structure of graphene-oxide,” Nano Lett. 9(3), 1058–1063 (2009). [CrossRef] [PubMed]
  30. X. M. Sun, Z. Liu, K. Welsher, J. T. Robinson, A. Goodwin, S. Zaric, H. J. Dai, “Nano-graphene oxide for cellular imaging and drug delivery,” Nano. Res. 1(3), 203–212 (2008). [CrossRef] [PubMed]
  31. Z. T. Luo, P. M. Vora, E. J. Mele, A. T. C. Johnson, J. M. Kikkawa, “Photoluminescence and band gap modulation in graphene oxide,” Appl. Phys. Lett. 94(11), 111909 (2009). [CrossRef]
  32. K. S. Subrahmanyam, P. Kumar, A. Nag, C. N. R. Rao, “Blue light emitting graphene-based materials and their use in generating white light,” Solid State Commun. 150(37-38), 1774–1777 (2010). [CrossRef]
  33. J. Lu, J. X. Yang, J. Z. Wang, A. Lim, S. Wang, K. P. Loh, “One-Pot synthesis of fluorescent carbon nanoribbons, nanoparticles, and graphene by the exfoliation of graphite in ionic liquids,” ACS Nano 3(8), 2367–2375 (2009). [CrossRef] [PubMed]
  34. K. P. Loh, Q. L. Bao, G. Eda, M. Chhowalla, “Graphene oxide as a chemically tunable platform for optical applications,” Nat. Chem. 2(12), 1015–1024 (2010). [CrossRef] [PubMed]
  35. G. Eda, Y. Y. Lin, C. Mattevi, H. Yamaguchi, H. A. Chen, I. S. Chen, C. W. Chen, M. Chhowalla, “Blue photoluminescence from chemically derived graphene oxide,” Adv. Mater. 22(4), 505–509 (2010). [CrossRef] [PubMed]
  36. T. V. Cuong, V. H. Pham, Q. T. Tran, S. H. Hahn, J. S. Chung, E. W. Shin, E. J. Kim, “Photoluminescence and Raman studies of graphene thin films prepared by reduction of graphene oxide,” Mater. Lett. 64(3), 399–401 (2010). [CrossRef]
  37. R. R. Nair, P. Blake, A. N. Grigorenko, K. S. Novoselov, T. J. Booth, T. Stauber, N. M. R. Peres, A. K. Geim, “Fine structure constant defines visual transparency of graphene,” Science 320(5881), 1308 (2008). [CrossRef] [PubMed]
  38. A. B. Djurisic, W. C. H. Choy, V. A. L. Roy, Y. H. Leung, C. Y. Kwong, K. W. Cheah, T. K. Gundu Rao, W. K. Chan, H. F. Lui, C. Surya, “Photoluminescence and electron paramagnetic resonance of ZnO tetrapod structures,” Adv. Funct. Mater. 14(9), 856–864 (2004). [CrossRef]
  39. C. C. Lin, H. P. Chen, H. C. Liao, S. Y. Chen, “Enhanced luminescent and electrical properties of hydrogen-plasma ZnO nanorods grown on wafer-scale flexible substrates,” Appl. Phys. Lett. 86(18), 183103 (2005). [CrossRef]
  40. X. T. Guo, Z. H. Ni, C. Y. Liao, H. Y. Nan, Y. Zhang, W. W. Zhao, W. H. Wang, “Fluorescence quenching of CdSe quantum dots on graphene,” Appl. Phys. Lett. 103(20), 201909 (2013). [CrossRef]
  41. G. Williams, P. V. Kamat, “Graphene-semiconductor nanocomposites: excited-state interactions between ZnO nanoparticles and graphene oxide,” Langmuir 25(24), 13869–13873 (2009). [CrossRef] [PubMed]

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