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Optical property of blended plasmonic nanofluid based on gold nanorods

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Abstract

Present work experimentally characterizes the optical property of blended plasmonic nanofuids based on gold nanorod (AuNR) with different aspect ratios. The existence of localized surface plasmon resonance was verified from measured extinction coefficient of three AuNR solutions, and spectral tunability of AuNR nanofluid was successfully demonstrated in the visible and near-infrared spectral region. The representative aspect ratio and volume fraction of each sample were then calculated from the relation between extinction coefficient and extinction efficiency, which leads to the design of a blended plasmonic nanofluid having broad-band absorption characteristic in the visible and near-infrared spectral region. The results obtained from this study will facilitate the development of a novel volumetric solar thermal collectors using plasmonic nanofluids.

© 2014 Optical Society of America

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Figures (7)

Fig. 1
Fig. 1 TEM images of AuNR samples: (a) ‘Short’; (b) ‘Mid’; and (c) ‘Long’. Histograms of the aspect ratio of each sample are also shown in (d), (e), and (f), respectively. The representative aspect ratio is obtained from the fitting analysis of the measured extinction coefficient.
Fig. 2
Fig. 2 Three-layer model of cuvette filled with nanofluid. ρ and ρ′ represents reflectance of a component to the beam coming from the left and right, respectively.
Fig. 3
Fig. 3 Extinction coefficient of 1/50 diluted AuNR nanofluids. Measured extinction coefficients of CTAB solution (10 mM) as well as DI water are also plotted for comparison purpose. The calculated value of H2O is based the tabulated data in [27].
Fig. 4
Fig. 4 (a) Extinction (solid) and scattering (dashed) efficiency of the suspension of randomly oriented AuNRs with different aspect ratios in water and (b) The linear relation between peak position and nanorod aspect ratio.
Fig. 5
Fig. 5 Calculated extinction coefficient using extinction efficiency compared with measured extinction coefficient.
Fig. 6
Fig. 6 Expected extinction coefficient of blended nanofluid calculating by summing measured extinction coefficient of gold nanorod samples weighted by their portions in the blended nanofluid.
Fig. 7
Fig. 7 Measured and expected extinction coefficient of blended nanofluid at the total volume fraction of 0.0001%.

Tables (1)

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Table 1 Average and standard deviation of diameter, length, and aspect ratio of synthesized AuNR samples.

Equations (2)

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I sample I 0 = ( 1 ρ 1 ) 2 ( 1 ρ 3 ) exp ( s 4 π k 2 λ ) 1 ρ 1 ρ 2 ρ 3 { ρ 2 ( 1 ρ 1 ρ 2 ) + [ exp ( s 4 π k 2 λ ) ] 2 ρ 1 }
κ nanofluid = ( 1 i f i ) κ CTAB + i ( 3 f i 4 r eff , i ) Q ext , i
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