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Optics Express

Optics Express

  • Editor: Andrew M. Weiner
  • Vol. 22, Iss. 4 — Feb. 24, 2014
  • pp: 4357–4370

Giant circular dichroism enhancement and chiroptical illusion in hybrid molecule-plasmonic nanostructures

Yineng Liu, Rongyao Wang, and Xiangdong Zhang  »View Author Affiliations


Optics Express, Vol. 22, Issue 4, pp. 4357-4370 (2014)
http://dx.doi.org/10.1364/OE.22.004357


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Abstract

Recently, there are great interest in studying the interaction between chiral molecules and plasmonic particles, because a weak circular dichroism (CD) signal in the ultraviolet (UV) region from chiral molecules can be both enhanced and transferred to the visible wavelength range by using plasmonic particles. Thus, ultrasensitive probe of tiny amounts of chiral substance by CD are worth waiting for. Here we present another way to strongly enhance CD of chiral molecules by using plasmonic particle cluster, which need not transfer to the visible wavelength. The method to calculate CD of chiral molecules in nanosphere clusters has been developed by means of multiple scattering of electromagnetic multipole fields. Our calculated results show that 2 orders of magnitude CD enhancement in the UV region for chiral molecules can be realized. Such a CD enhancement is very sensitive to the cluster structure. The cluster structure can cause chiroptical illusion in which a mirror symmetry in the CD spectra of opposite enantiomeric molecules is broken. The correction of quantum size effect on the phenomenon has also been considered. Our findings open up an alternative avenue for the ultrasensitive detection and illusion of chiral information.

© 2014 Optical Society of America

OCIS Codes
(240.6680) Optics at surfaces : Surface plasmons
(280.1415) Remote sensing and sensors : Biological sensing and sensors

ToC Category:
Plasmonics

History
Original Manuscript: January 3, 2014
Manuscript Accepted: February 10, 2014
Published: February 18, 2014

Virtual Issues
Vol. 9, Iss. 4 Virtual Journal for Biomedical Optics

Citation
Yineng Liu, Rongyao Wang, and Xiangdong Zhang, "Giant circular dichroism enhancement and chiroptical illusion in hybrid molecule-plasmonic nanostructures," Opt. Express 22, 4357-4370 (2014)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-22-4-4357


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