Electroluminescence of nanopatterned silicon with carbon implantation and solid phase epitaxial regrowth
Optics Express, Vol. 15, Issue 21, pp. 14099-14106 (2007)
http://dx.doi.org/10.1364/OE.15.014099
Acrobat PDF (775 KB)
Abstract
Electroluminescence at 1.28μm is observed in a nanopatterned silicon test structure that has been subjected to carbon implantation followed by solid-phase epitaxial regrowth for recrystalization. The sub-bandgap luminescence comes from a di-carbon complex known as ‘G center’. Enrichment of silicon with carbon atoms has been achieved in a procedure consisting of two implantations and solid-phase epitaxial regrowth. Nanopatterning was done using an anodized aluminum oxide membrane as a mask for reactive ion etching. Along with the electroluminescence, an enhanced photoluminescence was measured.
© 2007 Optical Society of America
1. Introduction
G. T. Reed and A. P. Knights, Silicon Photonics: An Introduction . (Wiley , Chichester, U.K, 2004). [CrossRef]
A. Kenyon, “Erbium in silicon,” Semiconductor Science and Technology 20, R65–R84 (2005). [CrossRef]
H. Ennen, G. Pomrenke, A. Axmann, K. Eisele, W. Haydl, and J. Schneider, “1.54-μm electroluminescence of erbium-doped silicon grown by molecular beam epitaxy,” Appl. Phys. Lett. 46, 381–383 (1985). [CrossRef]
O. Boyraz and B. Jalali, “Demonstration of a silicon raman laser,” Opt. Express 12, 5269–5272 (2005). [CrossRef]
H. S. Rong, Y. H. Kuo, S. B. Xu, A. S. Liu, R. Jones, and M. Paniccia, “A continuous-wave raman silicon laser,” Nature 433, 725–728 (2005). [CrossRef] [PubMed]
L. Pavesi, L. D. Negro, C. Mazzoleni, G. Franzo, and F. Priolo, “Optical gain in silicon nanocrystals,” Nature 408, 440–444 (2000). [CrossRef] [PubMed]
F. lacona, A. Irrera, G. Franz, D. Pacifici, I. Crupi, M. P. Miritello, C. D. Presti, and F. Priolo, “Silicon based light emitting devices: properties and applications of crystalline, amorphous and Er-doped nanoclusters,” IEEE J. Sel. Top. Quantum Electron. 12, 1596–1606 (2006). [CrossRef]
W. L. Ng, M. A. Lourenco, R. M. Gwilliam, S. Ledain, G. Shao, and K. P. Homewood, “An efficient room-temperature silicon-based light-emitting diode,” Nature 410, 192–194 (2001). [CrossRef] [PubMed]
J. Bao, M. Tabbal, T. Kim, S. Charnvanichborikarn, J. S. Williams, M. J. Aziz, and F. Capasso, “Point defect engineered Si sub-bandgap light-emitting diode,” Opt. Express 15, 6727–6733 (2007). [CrossRef] [PubMed]
A. W. Fang, H. Park, O. Cohen, R. Jones, M. J. Paniccia, and J. E. Bowers, “Electrically pumped hybrid AlGaInAs-silicon evanescent laser,” Opt. Express 14, 9203–9210 (2006). [CrossRef] [PubMed]
S. G. Cloutier, P. A. Kossyrev, and J. Xu, “Optical gain and stimulated emission in periodic nanopatterned crystalline silicon,” Nature Mater. 4, 887–891, (2005). [CrossRef]
L. W. Song, X. D. Zhan, B. W. Benson, and G. D. Watking, “bistable interstitial-carbon-substitutional-carbon pair in silicon,” Phys. Rev. B 42, 5765–5782 (1990). [CrossRef]
S. Cloutier, C.-H. Hsu, P. Kosseyrev, and J. M. Xu, “Radiative recombination enhancement in silicon via phonon localization and selection-rule breaking,” Adv. Mater. 18, 841–844 (2006). [CrossRef]
P. N. K. Deenapanray, N. E. Perret, D. J. Brink, F. D. Auret, and J. B. Malherbe, “Characterization of optically active defects created by noble gas ion bombardment of silicon,” J. Appl. Phys. 83, 4075–4080 (1998). [CrossRef]
J. Weber, R. J. Davis, H. U. Habermeier, W. D. Sawyer, and M. Singh, “Photoluminescene detection of impurities introduced in silicon by dry etching processes,” Appl. Phys. A 41, 175–178 (1986). [CrossRef]
L. Canham, K. Barraclough, and D. Robbins, “1.3μm light-emitting diode from silicon electron irradiated at its damage threshold,” Appl. Phys. Lett. 51, 1509–1511 (1987). [CrossRef]
S. G. Cloutier, P. A. Kossyrev, and J. Xu, “Optical gain and stimulated emission in periodic nanopatterned crystalline silicon,” Nature Mater. 4, 887–891, (2005). [CrossRef]
2. Fabrication of carbon rich silicon (Si-C) using solid phase epitaxial regrowth
S. G. Cloutier, P. A. Kossyrev, and J. Xu, “Optical gain and stimulated emission in periodic nanopatterned crystalline silicon,” Nature Mater. 4, 887–891, (2005). [CrossRef]
J. Weber, R. J. Davis, H. U. Habermeier, W. D. Sawyer, and M. Singh, “Photoluminescene detection of impurities introduced in silicon by dry etching processes,” Appl. Phys. A 41, 175–178 (1986). [CrossRef]
S. U. Campisano, G. Foti, P. Baeri, M. G. Grimaldi, and E. Rimini, “Solute trapping by moving interface in ion-implanted silicon,” Appl. Phys. Lett. 37, 719–722 (1980). [CrossRef]
J. W. Strane, S. R. Lee, H. J. Stein, S. T. Picraux, J. K. Watanabe, and J. W. Mayer, “Carbon incorporation into Si at high concentrations by ion implantation and solid phase epitaxy,” J. Appl. Phys. 79, 637–645 (1996). [CrossRef]
J. W. Strane, S. R. Lee, H. J. Stein, S. T. Picraux, J. K. Watanabe, and J. W. Mayer, “Carbon incorporation into Si at high concentrations by ion implantation and solid phase epitaxy,” J. Appl. Phys. 79, 637–645 (1996). [CrossRef]
3. Enhanced G center photoluminescence of nano-patterned Si-C
S. G. Cloutier, P. A. Kossyrev, and J. Xu, “Optical gain and stimulated emission in periodic nanopatterned crystalline silicon,” Nature Mater. 4, 887–891, (2005). [CrossRef]
J. Liang, H. Chik, A. Yin, and J. Xu, “Two-dimensional lateral superlattices of nanostructures: Nonlithographic: Formation by anodic membrane template,” J. Appl. Phys. 91, 2544–2564 (2002). [CrossRef]
4. G center electroluminescence in a nanopatterned Si-C p-n junction
L. W. Song, X. D. Zhan, B. W. Benson, and G. D. Watking, “bistable interstitial-carbon-substitutional-carbon pair in silicon,” Phys. Rev. B 42, 5765–5782 (1990). [CrossRef]
5. Discussion and conclusion
L. W. Song, X. D. Zhan, B. W. Benson, and G. D. Watking, “bistable interstitial-carbon-substitutional-carbon pair in silicon,” Phys. Rev. B 42, 5765–5782 (1990). [CrossRef]
Acknowledgment
References and links
G. T. Reed and A. P. Knights, Silicon Photonics: An Introduction . (Wiley , Chichester, U.K, 2004). [CrossRef] | |
L. Pavesi and D. J. Lockwood, Topics in Applied physics. volume 94: Silicon Photonics . (Springer-Verlag Berlin, Germany, 2004). | |
B. Jalali and S. Fathpour, “Silicon photonics,” J. Lightwave Technol. 24, 4600–4610 (2006). [CrossRef] | |
M. Lipson, “Guiding, modulating, and emitting light on silicon challenges and opportunities,” J. Lightwave Technol. 23, 4222–4238 (2005). [CrossRef] | |
Liu, R. Jones, L. Liao, D. Samara-Rubio, D. Rubin, O. Cohen, R. Nicolaescu, and M. Paniccia, “A highspeed silicon optical modulator based on a metal-oxide-semiconductor capacitor,” Nature 427, 615–618 (2004). [CrossRef] [PubMed] | |
L. Liao, D. Samara-Rubio, M. Morse, A. Liu, D. Hodge, D. Rubin, U. D. Keil, and T. Franck, “High-speed silicon Mach-Zehnder modulator,” Opt. Express 13, 3129–3135 (2005). [CrossRef] [PubMed] | |
L. Naval, B. Jalali, L. Gomelsky, and J. M. Liu, “Optimization of Si1-x Ge x /Si waveguide photodetectors operating at λ = 1.3 μm,” J. Lightwave Technol. 14, 787–797 (1996). [CrossRef] | |
L. Colace, G. Masini, and G. Assanto, “Ge-on-Si approach to the detection of near-infrared light,” IEEE J. Quantum Electron. 35, 1843–1852 (1999). [CrossRef] | |
A. Kenyon, “Erbium in silicon,” Semiconductor Science and Technology 20, R65–R84 (2005). [CrossRef] | |
H. Ennen, G. Pomrenke, A. Axmann, K. Eisele, W. Haydl, and J. Schneider, “1.54-μm electroluminescence of erbium-doped silicon grown by molecular beam epitaxy,” Appl. Phys. Lett. 46, 381–383 (1985). [CrossRef] | |
O. Boyraz and B. Jalali, “Demonstration of a silicon raman laser,” Opt. Express 12, 5269–5272 (2005). [CrossRef] | |
H. S. Rong, Y. H. Kuo, S. B. Xu, A. S. Liu, R. Jones, and M. Paniccia, “A continuous-wave raman silicon laser,” Nature 433, 725–728 (2005). [CrossRef] [PubMed] | |
L. Pavesi, L. D. Negro, C. Mazzoleni, G. Franzo, and F. Priolo, “Optical gain in silicon nanocrystals,” Nature 408, 440–444 (2000). [CrossRef] [PubMed] | |
F. lacona, A. Irrera, G. Franz, D. Pacifici, I. Crupi, M. P. Miritello, C. D. Presti, and F. Priolo, “Silicon based light emitting devices: properties and applications of crystalline, amorphous and Er-doped nanoclusters,” IEEE J. Sel. Top. Quantum Electron. 12, 1596–1606 (2006). [CrossRef] | |
W. L. Ng, M. A. Lourenco, R. M. Gwilliam, S. Ledain, G. Shao, and K. P. Homewood, “An efficient room-temperature silicon-based light-emitting diode,” Nature 410, 192–194 (2001). [CrossRef] [PubMed] | |
J. Bao, M. Tabbal, T. Kim, S. Charnvanichborikarn, J. S. Williams, M. J. Aziz, and F. Capasso, “Point defect engineered Si sub-bandgap light-emitting diode,” Opt. Express 15, 6727–6733 (2007). [CrossRef] [PubMed] | |
A. W. Fang, H. Park, O. Cohen, R. Jones, M. J. Paniccia, and J. E. Bowers, “Electrically pumped hybrid AlGaInAs-silicon evanescent laser,” Opt. Express 14, 9203–9210 (2006). [CrossRef] [PubMed] | |
S. G. Cloutier, P. A. Kossyrev, and J. Xu, “Optical gain and stimulated emission in periodic nanopatterned crystalline silicon,” Nature Mater. 4, 887–891, (2005). [CrossRef] | |
L. W. Song, X. D. Zhan, B. W. Benson, and G. D. Watking, “bistable interstitial-carbon-substitutional-carbon pair in silicon,” Phys. Rev. B 42, 5765–5782 (1990). [CrossRef] | |
S. Cloutier, C.-H. Hsu, P. Kosseyrev, and J. M. Xu, “Radiative recombination enhancement in silicon via phonon localization and selection-rule breaking,” Adv. Mater. 18, 841–844 (2006). [CrossRef] | |
G. Davies, K. Kun, and T. Reade, “Annealing kinetics of the dicarbon radiation-damage center in crystalline silicon,” Phys. Rev. B 44, 12146–12157 (1991). [CrossRef] | |
R. B. Capaz, A. Dal Pino Jr., and J. D. Joannopoulos, “Theory of carbon-carbon pairs in silicon,” Phys. Rev. B 58, 9845–9850 (1998). [CrossRef] | |
G. Davies, “the optical properties of luminescence centres in silicon,” Phys. Rep. 176, 83–188 (1989). [CrossRef] | |
G. Davies, H. Brian, E. Lightowlers, K. Barraclough, and M. Thomaz, “The temperature dependence of the 969 meV ‘G’ optical transition in silicon,” Semiconductor Science and Technology 4, 200–206 (1989). [CrossRef] | |
M. Potsidi and C. Londos, “The CiCs(Si-i) defect in silicon: An infrared spectroscopy study,” J. Appl. Phys. 100, 033523-033523-4 (2006). [CrossRef] | |
G Davies, E C Lightowlers, and M. do Carmo, “Carbon-related vibronic bands in electron-irradiated silicon,” J. Phys. C 16, 5503–5515 (1983). [CrossRef] | |
E. Lavrov, L. Hoffmann, and B. B. Nielsen, “Local vibrational modes of the metastable dicarbon center (CsCi) in silicon,” Phys. Rev. B 60, 8081–8086, (1999). [CrossRef] | |
A. Dolgolenko, M. Varentsov, and G. Gaidar, “Energy level position of bistable CiCs defect in the B configuration in the forbidden band of n-Si,” Physica Status Solidi B 241, 2914–2922 (2004). [CrossRef] | |
P. N. K. Deenapanray, N. E. Perret, D. J. Brink, F. D. Auret, and J. B. Malherbe, “Characterization of optically active defects created by noble gas ion bombardment of silicon,” J. Appl. Phys. 83, 4075–4080 (1998). [CrossRef] | |
J. Weber, R. J. Davis, H. U. Habermeier, W. D. Sawyer, and M. Singh, “Photoluminescene detection of impurities introduced in silicon by dry etching processes,” Appl. Phys. A 41, 175–178 (1986). [CrossRef] | |
L. Canham, K. Barraclough, and D. Robbins, “1.3μm light-emitting diode from silicon electron irradiated at its damage threshold,” Appl. Phys. Lett. 51, 1509–1511 (1987). [CrossRef] | |
S. U. Campisano, G. Foti, P. Baeri, M. G. Grimaldi, and E. Rimini, “Solute trapping by moving interface in ion-implanted silicon,” Appl. Phys. Lett. 37, 719–722 (1980). [CrossRef] | |
J. W. Strane, S. R. Lee, H. J. Stein, S. T. Picraux, J. K. Watanabe, and J. W. Mayer, “Carbon incorporation into Si at high concentrations by ion implantation and solid phase epitaxy,” J. Appl. Phys. 79, 637–645 (1996). [CrossRef] | |
J. Liang, H. Chik, A. Yin, and J. Xu, “Two-dimensional lateral superlattices of nanostructures: Nonlithographic: Formation by anodic membrane template,” J. Appl. Phys. 91, 2544–2564 (2002). [CrossRef] |
OCIS Codes
(230.3670) Optical devices : Light-emitting diodes
(250.5230) Optoelectronics : Photoluminescence
ToC Category:
Optical Devices
History
Original Manuscript: July 25, 2007
Revised Manuscript: September 27, 2007
Manuscript Accepted: September 28, 2007
Published: October 11, 2007
Citation
Efraim Rotem, Jeffrey M. Shainline, and Jimmy M. Xu, "Electroluminescence of nanopatterned silicon with carbon implantation and solid phase epitaxial regrowth," Opt. Express 15, 14099-14106 (2007)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-15-21-14099
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References
- G. T. Reed and A. P. Knights, Silicon Photonics: An Introduction. (Wiley, Chichester, U.K, 2004). [CrossRef]
- L. Pavesi and D. J. Lockwood, Topics in Applied physics. volume 94: Silicon Photonics. (Springer-Verlag Berlin, Germany, 2004).
- B. Jalali and S. Fathpour, "Silicon photonics," J. Lightwave Technol. 24, 4600-4610 (2006). [CrossRef]
- M. Lipson, "Guiding, modulating, and emitting light on silicon challenges and opportunities," J. Lightwave Technol. 23, 4222-4238 (2005). [CrossRef]
- Liu, R. Jones, L. Liao, D. Samara-Rubio, D. Rubin, O. Cohen, R. Nicolaescu, and M. Paniccia, "A high-speed silicon optical modulator based on a metal-oxide-semiconductor capacitor," Nature 427, 615-618 (2004). [CrossRef] [PubMed]
- L. Liao, D. Samara-Rubio, M. Morse, A. Liu, D. Hodge, D. Rubin, U. D. Keil, and T. Franck, "High-speed silicon Mach-Zehnder modulator," Opt. Express 13, 3129-3135 (2005). [CrossRef] [PubMed]
- L. Naval, B. Jalali, L. Gomelsky, and J. M. Liu, "Optimization of Si1?xGex/Si waveguide photodetectors operating at ? = 1.3 ?m," J. Lightwave Technol. 14, 787-797 (1996). [CrossRef]
- L. Colace, G. Masini, and G. Assanto, "Ge-on-Si approach to the detection of near-infrared light," IEEE J. Quantum Electron. 35, 1843-1852 (1999). [CrossRef]
- A. Kenyon, "Erbium in silicon," Semicond. Sci. Technol. 20, R65-R84 (2005). [CrossRef]
- H. Ennen, G. Pomrenke, A. Axmann, K. Eisele, W. Haydl, and J. Schneider, "1.54-µm electroluminescence of erbium-doped silicon grown by molecular beam epitaxy," Appl. Phys. Lett. 46, 381-383 (1985). [CrossRef]
- O. Boyraz and B. Jalali, "Demonstration of a silicon raman laser," Opt. Express 12, 5269-5272 (2005). [CrossRef]
- H. S. Rong, Y. H. Kuo, S. B. Xu, A. S. Liu, R. Jones, and M. Paniccia, "A continuous-wave raman silicon laser," Nature 433, 725-728 (2005). [CrossRef] [PubMed]
- L. Pavesi, L. D. Negro, C. Mazzoleni, G. Franzo, and F. Priolo, "Optical gain in silicon nanocrystals," Nature 408, 440-444 (2000). [CrossRef] [PubMed]
- F. lacona, A. Irrera, G. Franz, D. Pacifici, I. Crupi, M. P. Miritello, C. D. Presti, and F. Priolo, "Silicon based light emitting devices: properties and applications of crystalline, amorphous and Er-doped nanoclusters," IEEE J. Sel. Top. Quantum Electron. 12, 1596-1606 (2006). [CrossRef]
- W. L. Ng, M. A. Lourenco, R. M. Gwilliam, S. Ledain, G. Shao, K. P. Homewood, "An efficient room-temperature silicon-based light-emitting diode," Nature 410, 192-194 (2001). [CrossRef] [PubMed]
- J. Bao, M. Tabbal, T. Kim, S. Charnvanichborikarn, J. S. Williams, M. J. Aziz, and F. Capasso, "Point defect engineered Si sub-bandgap light-emitting diode," Opt. Express 15, 6727-6733 (2007). [CrossRef] [PubMed]
- A. W. Fang, H. Park, O. Cohen, R. Jones, M. J. Paniccia, and J. E. Bowers, "Electrically pumped hybrid AlGaInAs-silicon evanescent laser," Opt. Express 14, 9203-9210 (2006). [CrossRef] [PubMed]
- S. G. Cloutier, P. A. Kossyrev and J. Xu, "Optical gain and stimulated emission in periodic nanopatterned crystalline silicon," Nature Mater. 4, 887-891, (2005). [CrossRef]
- L. W. Song, X. D. Zhan, B. W. Benson, and G. D. Watking, "bistable interstitial-carbon-substitutional-carbon pair in silicon," Phys. Rev. B 42, 5765-5782 (1990). [CrossRef]
- S. Cloutier, C.-H. Hsu, P. Kosseyrev, and J. M. Xu, "Radiative recombination enhancement in silicon via phonon localization and selection-rule breaking," Adv. Mater. 18, 841-844 (2006). [CrossRef]
- G. Davies, K. Kun, and T. Reade, "Annealing kinetics of the dicarbon radiation-damage center in crystalline silicon," Phys. Rev. B 44, 12146-12157 (1991). [CrossRef]
- R. B. Capaz, A. Dal Pino, Jr., and J. D. Joannopoulos, "Theory of carbon-carbon pairs in silicon," Phys. Rev. B 58, 9845-9850 (1998). [CrossRef]
- G. Davies, "the optical properties of luminescence centres in silicon," Phys. Rep. 176, 83-188 (1989). [CrossRef]
- G. Davies, H. Brian, E. Lightowlers, K. Barraclough, and M. Thomaz, "The temperature dependence of the 969 meV ‘G’ optical transition in silicon," Semicond. Sci. Technol. 4, 200-206 (1989). [CrossRef]
- M. Potsidi and C. Londos, "The CiCs(Si-i) defect in silicon: An infrared spectroscopy study," J. Appl. Phys. 100, 033523-033523-4 (2006). [CrossRef]
- G Davies, E C Lightowlers and M. do Carmo, "Carbon-related vibronic bands in electron-irradiated silicon," J. Phys. C 16, 5503-5515 (1983). [CrossRef]
- E. Lavrov, L. Hoffmann, and B. B. Nielsen, "Local vibrational modes of the metastable dicarbon center (CsCi) in silicon," Phys. Rev. B 60, 8081-8086, (1999). [CrossRef]
- A. Dolgolenko, M. Varentsov, and G. Gaidar, "Energy level position of bistable CiCs defect in the B configuration in the forbidden band of n-Si," Physica Status Solidi B 241, 2914-2922 (2004). [CrossRef]
- P. N. K. Deenapanray, N. E. Perret, D. J. Brink, F. D. Auret, and J. B. Malherbe, "Characterization of optically active defects created by noble gas ion bombardment of silicon," J. Appl. Phys. 83, 4075-4080 (1998). [CrossRef]
- J. Weber, R. J. Davis, H. U. Habermeier, W. D. Sawyer, and M. Singh, "Photoluminescene detection of impurities introduced in silicon by dry etching processes," Appl. Phys. A 41, 175-178 (1986). [CrossRef]
- L. Canham, K. Barraclough, and D. Robbins, "1.3µm light-emitting diode from silicon electron irradiated at its damage threshold," Appl. Phys. Lett. 51, 1509-1511 (1987). [CrossRef]
- S. U. Campisano, G. Foti, P. Baeri, M. G. Grimaldi, and E. Rimini, "Solute trapping by moving interface in ion-implanted silicon," Appl. Phys. Lett. 37, 719-722 (1980). [CrossRef]
- J. W. Strane, S. R. Lee, H. J. Stein, S. T. Picraux, J. K. Watanabe, and J. W. Mayer, "Carbon incorporation into Si at high concentrations by ion implantation and solid phase epitaxy," J. Appl. Phys. 79, 637-645 (1996). [CrossRef]
- J. Liang, H. Chik, A. Yin, and J. Xu, "Two-dimensional lateral superlattices of nanostructures: Nonlithographic: Formation by anodic membrane template," J. Appl. Phys. 91, 2544-2564 (2002). [CrossRef]
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