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Optics Express

  • Editor: Martijn de Sterke
  • Vol. 16, Iss. 20 — Sep. 29, 2008
  • pp: 15540–15545
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Efficient Yb laser fibers with low photodarkening by optimization of the core composition

Sylvia Jetschke, Sonja Unger, Anka Schwuchow, Martin Leich, and Johannes Kirchhof  »View Author Affiliations


Optics Express, Vol. 16, Issue 20, pp. 15540-15545 (2008)
http://dx.doi.org/10.1364/OE.16.015540


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Abstract

We report on photodarkening (PD) investigations at Yb doped fibers with specific variation of the concentrations of the codopants aluminum and phosphorus, measured during cladding pumping at 915 nm. A core composition with equal content of Al and P is most promising to achieve Yb fibers with low PD, high laser efficiency and low numerical aperture of the laser core despite of high codoping. A laser output power of more than 100 W was demonstrated on such a fiber with a slope efficiency of 72%. The correlation of the PD loss with the NIR-excited cooperative luminescence encourages the supposition that cooperative energy transfer from excited Yb3+ ions to the atomic defect precursors in the core glass enables the formation of color centers in the pump-induced PD process.

© 2008 Optical Society of America

1. Introduction

Pump-induced photodarkening (PD) is a detrimental process limiting the performance of Yb laser fibers in many applications. This feature of the fiber core material was attributed to the excitation of Yb ions [1

1. J. Koponen, M. Söderlund, H. J. Hoffman, D. Kliner, and J. Koplow, “Photodarkening Measurements in Large-Mode-Area Fibers,” Proc. SPIE 6453, 64531E-1-11 (2007).

] and is often characterized by accelerated PD experiments at high Yb inversion, thereby determining the kinetics of the PD loss from transmission measurements of short fiber pieces [2

2. A. V. Shubin, M. V. Yashkov, M. A. Melkumov, S. A. Smirnow, I. A. Bufetov, and E. M. Dianov, “Photodarkening of aluminosilicate and phosphosilicate Yb-doped fibers,” in Conf. Digest of CLEO Europe-EQEC 2007, CJ3-1-THU (2007).

, 3

3. S. Jetschke, S. Unger, U. Röpke, and J. Kirchhof, “Photodarkening in Yb doped fibers: experimental evidence of equilibrium states depending on the pump power,” Opt. Express 15, 14838–14843 (2007). [CrossRef] [PubMed]

]. Transverse variations of the PD loss were studied with both core and cladding pumping and under laser operation [4

4. M. J. Söderlund, J. J. Montiel i Ponsoda, S. K. T. Tammela, K. Ylä-Jarkko, A. Salokatve, and S. Honkanen, “Mode-induced transverse photodarkening loss variations in large-mode-area ytterbium doped silica fibers,” Opt. Express 16, 10633–10640 (2008). [CrossRef] [PubMed]

]. Possible routes to PD are being discussed including observations of similar color centers generated by UV irradiation [5

5. M. Engholm, L. Norin, and D. Aberg, “Strong UV absorption and visible luminescence in ytterbium-doped aluminosilicate glass under UV excitation,” Opt. Lett. 32, 3352–3354 (2007). [CrossRef] [PubMed]

, 6

6. M. Engholm and L. Norin, “Preventing photodarkening in ytterbium-doped high power fiber lasers; correlation to the UV-transparency of the core glass,” Opt. Express 16, 1260–1268 (2008). [CrossRef] [PubMed]

] or two photons of 488 nm [7

7. S. Yoo, C. Basu, A. J. Boland, C. Sones, J. Nilsson, J. K. Sahu, and D. Payne, “Photodarkening in Yb-doped aluminosilicate fibers induced by 488 nm irradiation,” Opt. Lett. 32, 1626–1628 (2007). [CrossRef] [PubMed]

]. The characterization of defects in the silica glass [8

8. P. D. Dragic, C. G. Carlson, and A. Croteau, “Characterization of defect luminescence in Yb doped silica fibers: part I: NBOHC,” Opt. Express 16, 4688–4697 (2008). [CrossRef] [PubMed]

] that could act as precursors is an important contribution to understand the PD process.

A reduction of pump-induced PD was qualitatively described for fibers with enhanced Al-codoping [9

9. T. Kitabayashi, M. Ikeda, M. Nakai, T. Sakai, K. Himeno, and K. Ohashi, “Population Inversion Factor Dependence of Photodarkening of Yb-doped Fibers and its Suppression by Highly Aluminium Doping,” in OFC/NFOE Conference on CD-ROM (Opt. Society of America, Washington, DC, 2006), OThC5 (2006).

]. Very low values of the PD loss and rate constant were measured in fibers purely codoped with a high P content (> 6 mol% P2O5) [2

2. A. V. Shubin, M. V. Yashkov, M. A. Melkumov, S. A. Smirnow, I. A. Bufetov, and E. M. Dianov, “Photodarkening of aluminosilicate and phosphosilicate Yb-doped fibers,” in Conf. Digest of CLEO Europe-EQEC 2007, CJ3-1-THU (2007).

, 10

10. S. Unger, A. Schwuchow, S. Jetschke, V. Reichel, A. Scheffel, and J. Kirchhof, “Optical properties of Yb-doped laser fibers in dependence on codopants and preparation conditions,” Proc. SPIE 6890, 16 (2008).

] instead of Al. But, P evaporation causes a harmful central dip in the refractive index profile and Yb distribution of such fibers; other disadvantages of the P-codoping are the high core NA that complicates the preparation of large-mode-area (LMA) fibers, a high core background loss of > 300 dB/km [10

10. S. Unger, A. Schwuchow, S. Jetschke, V. Reichel, A. Scheffel, and J. Kirchhof, “Optical properties of Yb-doped laser fibers in dependence on codopants and preparation conditions,” Proc. SPIE 6890, 16 (2008).

] as well as the reduction of the Yb absorption and emission cross sections [11

11. M. A. Melkumov, I. A. Bufetov, K. S. Kratsov, A. V. Shubin, and E. M. Dianov, “Lasing parameters of ytterbium-doped fibres doped with P2O5 and Al2O3,” Quantum Electron. 34, 843–848 (2004).

]. Therefore, the laser performance of such fibers is impaired in comparison to the “standard” Yb fibers with Al-codoping [10

10. S. Unger, A. Schwuchow, S. Jetschke, V. Reichel, A. Scheffel, and J. Kirchhof, “Optical properties of Yb-doped laser fibers in dependence on codopants and preparation conditions,” Proc. SPIE 6890, 16 (2008).

].

In this paper, we investigate the influence of combined codoping with Al and P on the photodarkening parameters and other fiber properties.

2. Fiber fabrication and standard characterization

Preforms and fiber samples have been prepared by MCVD (Modified Chemical Vapor Deposition) and solution doping according to a route with carefully controlled process steps described in [12

12. J. Kirchhof, S. Unger, A. Schwuchow, S. Grimm, and V. Reichel, “Materials for high-power fiber lasers,” J. Non-Cryst. Solids 352, 2399–2403 (2006). [CrossRef]

, 13

13. J. Kirchhof, S. Unger, and A. Schwuchow, “Properties of Yb-doped materials for solid and microstructured high power fiber lasers”, in Proceedings of ICMAT 2007 Symposium on Microstructured and Nanostructured Optical Fibers, Singapore, 1–6 July, 2007.

]. The goal of the two series prepared here was to provide similar fibers doped with nearly constant amount of Yb2O3 (about 0.45 mol%) and specific variation of the codopants. The fibers of the series #Al differ primarily in their aluminum content (Tab. 1), while the phosphorus content is kept low and constant (0.5 mol% P2O5). In the series #P with constant aluminum content (about 4.5 mol% Al2O3), the phosphorus concentration is stepwise enhanced up to a molar ratio P/Al of 1 (Tab. 2). All preforms have been collapsed in oxygen atmosphere.

For the standard characterization and the photodarkening experiments, fiber samples with a cladding diameter of 125 µm were drawn; the core diameter is approximately 10 µm. From the preform #4P, a double-cladding fiber with core and cladding diameters of 20 µm and 250/200 µm (double D-shaped) was prepared to perform laser experiments.

The samples were characterized by X-ray microprobe analysis, refractive index profiling, and absorption and fluorescence measurements in VIS and NIR. Important properties are summarized in the Tables 1 and 2. All specified concentrations correspond to the maximum values of the measured concentration profiles. Contrary to fibers with P excess [10

10. S. Unger, A. Schwuchow, S. Jetschke, V. Reichel, A. Scheffel, and J. Kirchhof, “Optical properties of Yb-doped laser fibers in dependence on codopants and preparation conditions,” Proc. SPIE 6890, 16 (2008).

], a very low core background loss αb was measured at all pristine fibers discussed in this paper (Tables 1 and 2).

Refractive index profiles (measured on the preforms but displayed vs. the fiber radius r) are shown in Fig. 1. In Al-codoped fibers, the refractive index is growing with increasing Al content. In the series #P, the refractive index is lowered despite of the increasing P addition. This anomaly is caused by the interaction of Al and P ions and was already described for fibers without Yb [14

14. S. Unger, A. Schwuchow, J. Dellith, and J. Kirchhof, “Codoped materials for high power fiber lasers — diffusion behaviour and optical properties,” Proc. SPIE 6469, 13 (2007).

]. All samples are free from a central index dip.

Fig. 1. Refractive index profiles of the samples from series #Al (a) and series #P (b).

The fluorescence measurements were performed at the fibers with an improved double-perpendicular technique (both, the pump excitation with 980 nm and the collection of fluorescence light were carried out perpendicularly to the fiber axis [10

10. S. Unger, A. Schwuchow, S. Jetschke, V. Reichel, A. Scheffel, and J. Kirchhof, “Optical properties of Yb-doped laser fibers in dependence on codopants and preparation conditions,” Proc. SPIE 6890, 16 (2008).

]) to ensure identical measurement conditions and nearly saturated Yb inversion for all investigated fibers. The Yb3+ near infrared (NIR) fluorescence lifetime was detected to be almost equal in the fibers (810 to 840 µs) except for the fiber #4P with the highest P content (880 µs). The spectra of the cooperative luminescence around 500 nm are shown in Fig. 2; the reduction of the intensity by the enhanced Al and P content, respectively is evident despite of slightly reduced Yb concentrations in the fibers #4Al and #5Al.

Fig. 2. Measured spectra of the NIR-excited cooperative luminescence of the fibers from series #Al (a) and series #P (b).

Table 1. Fiber series #Al (0.5 mol% P2O5, variation of the Al content): sample number, ytterbium content, aluminum content, fiber background loss αb at 1200 and 633 nm, respectively, and determined photodarkening parameters: equilibrium loss αeq and time constant τ.

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Table 2. Fiber series #P (about 4.5 mol% Al2O3, variation of the P content): sample number, ytterbium content, phosphorus content, fiber background loss αb at 1200 and 633 nm, respectively, and determined photodarkening parameters: equilibrium loss αeq and time constant τ.

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Core absorption spectra were measured at thin preform slices to determine the absorption cross section of the Yb3+ions; in Fig. 5(a), results for samples codoped merely with Al and merely with P [15

15. J. Kirchhof, S. Unger, A. Schwuchow, S. Jetschke, and B. Knappe, “Dopant interactions in high-power laser fibers,” Proc. SPIE 5723, 261–272 (2005). [CrossRef]

] are compared with the fiber #4P of this paper (equal content of Al and P). Generally, the Yb3+ absorption cross section spectra for the fibers of the series #Al and #P were found to be almost equal except for the fiber #4P the values of which are lower (about 25% at the main pump wavelengths around 915 nm and 976 nm).

3. Photodarkening measurements

The transmission of probe light (633 nm) was measured in-situ during long-term Yb3+ excitation by cladding pumping of the fibers with 915 nm. The use of a stable, broadband light source (halogen lamp) and the chopper/lock-in technique facilitates low-noise measurements of the photodarkening kinetics. Special care was taken to measure the true core excess loss without falsification by probe light guided in the cladding of the fiber under test without attenuation. A detailed description of the experimental set-up is given in [3

3. S. Jetschke, S. Unger, U. Röpke, and J. Kirchhof, “Photodarkening in Yb doped fibers: experimental evidence of equilibrium states depending on the pump power,” Opt. Express 15, 14838–14843 (2007). [CrossRef] [PubMed]

]. Very short fibers (lengths 1 to 2 cm) were examined to avoid ASE (amplified spontaneous emission) and to permit also the evaluation of high PD losses induced in some fiber types with the applied pump power of 6.1 to 13.2 W.

The pump-induced Yb inversion was estimated from the launched pump power, the saturation power and the cross sections of Yb absorption and emission at 915 nm. The density of excited Yb ions [Yb*] was calculated as the product of the inversion and the density of Yb ions (Yb content see Tables 1 and 2). The pump power was adjusted to reach similar density of excited Yb ions [Yb*] within each fiber series. Therefore, the fibers #1 to #3 of the series #Al were pumped with 6.1 W (Inv. 0.55), but the fibers #4 and #5 with 13.2 W (Inv. 0.69). All fibers of the series #P were pumped with 10.1 W (Inv. 0.66, but 0.62 for fiber #4P).

Fig. 3. Temporal development of the photodarkening loss of the fibers from series #Al (a) at [Yb*] ≈ 1.1· 1026 m-3 and series #P (b) at [Yb*] ≈ 1.3· 1026 m-3. The stretched exponential functions determined by the fitting procedure are shown as thin dashed lines.

The time-dependence of the core excess loss α (t)=-10·log(T(t))/L in units of dB/m (L is the fiber length) was calculated from the measured probe transmission T(t)=P(t)/P0 (P0 and P(t) are the transmitted probe powers before and during photodarkening, respectively). The results are shown in Fig. 3(a) for the series #Al ([Yb*] ≈ 1.1·1026 m-3) and in Fig. 3(b) for the series #P ([Yb*]=1.4·1026 m-3, but 1.2·1026 m-3 for the fiber #4P).

The photodarkening parameters, i.e. the equilibrium loss αeq and the time constant τ, were determined by a fitting procedure with a stretched exponential function defined in [3

3. S. Jetschke, S. Unger, U. Röpke, and J. Kirchhof, “Photodarkening in Yb doped fibers: experimental evidence of equilibrium states depending on the pump power,” Opt. Express 15, 14838–14843 (2007). [CrossRef] [PubMed]

]; these curves are also shown in Fig. 3 as thin dashed lines. The obtained results are summarized in the Tables 1 and 2 for all investigated fibers. For the series #Al, the values of αeq and the rate constant τ-1 are also shown in Fig. 4 as a function of the Al content.

Fig. 4. Photodarkening loss αeq (a) and rate constant τ-1 (b) in dependence on the aluminum content (fiber series #Al, [Yb*] ≈ 1.1· 1026 m-3).

4. Laser measurements

The fiber #4P was characterized in a CW laser set-up by pumping at 980 nm. The resonator has been realized by a dichroitic mirror at the pump launching fiber end (reflectivity nearly 100% for wavelengths > 1000 nm) and perpendicularly cleaved fiber ends. The fiber length has been chosen to absorb most of the pump power (L=6 m). In Fig. 5(b), the measured Yb laser power in dependence on the absorbed pump power is shown. The laser emission in the wavelength range around 1070 nm was monitored by an Optical Spectrum Analysator.

Fig. 5. Spectra of the Yb3+ absorption cross section for different codoping (a) and laser characteristics of the fiber #4P (b).

5. Discussion

Our investigations verify the reduction of photodarkening in Yb doped fibers by the enhancement of the Al content (Fig. 3(a)). A quantitative evaluation can be deduced from the results of the fiber series #Al for both PD parameters (Fig. 4): whereas the PD equilibrium loss drops almost linearly, the rate constant shows a stronger decrease of approximately τ-1~c(Al2O3)-2. (For the fibers #4Al and #5Al with lower Yb content (Tab.1), slightly reduced PD parameter values are expected from earlier investigations [3

3. S. Jetschke, S. Unger, U. Röpke, and J. Kirchhof, “Photodarkening in Yb doped fibers: experimental evidence of equilibrium states depending on the pump power,” Opt. Express 15, 14838–14843 (2007). [CrossRef] [PubMed]

], but this is of minor influence on the relations stated above.)

Additional codoping with phosphorus results in a more pronounced reduction of the PD loss, whereas the time constant is only weakly influenced (Tab. 2 and Fig. 3(b)). For equal concentrations of P and Al, the PD loss is almost completely suppressed.

Fortunately, the reduction of PD in the series #P is accompanied by a reduction of the core refractive index (Fig. 1(b)) due to the interaction of both codopants [14

14. S. Unger, A. Schwuchow, J. Dellith, and J. Kirchhof, “Codoped materials for high power fiber lasers — diffusion behaviour and optical properties,” Proc. SPIE 6469, 13 (2007).

]. Moreover, the central dip of the index profile known from purely P-codoped laser fibers is avoided by this core composition.

As already described in [15

15. J. Kirchhof, S. Unger, A. Schwuchow, S. Jetschke, and B. Knappe, “Dopant interactions in high-power laser fibers,” Proc. SPIE 5723, 261–272 (2005). [CrossRef]

], the Yb3+ absorption cross section σabs in purely P-codoped fibers is reduced to about 50% in comparison to the Al-codoped fibers (Fig. 5(a)). For the combined codoping with Al and P in the Al-excess branch, the Yb3+ absorption cross section is slightly reduced by no more than 25% at the main pump wavelengths around 915 nm and 976 nm. From these results and the low core background loss (Tab. 2) a favorable laser performance of the fibers of series #P could be expected and was verified by the laser examination of the fiber #4P. A laser output power of more than 100 W was demonstrated with a slope efficiency of 72% (Fig. 5(b)).

The reduction of the PD loss by the enhanced P content in the series #P is correlated with a diminished intensity of the NIR-excited cooperative luminescence of Yb3+ ions in the visible range (Fig. 2(b)). A similar correlation was found for the fiber series #Al of this paper (Fig. 2(a)) and for the fiber series with increasing oxygen deficiency in the core glass discussed in [12

12. J. Kirchhof, S. Unger, A. Schwuchow, S. Grimm, and V. Reichel, “Materials for high-power fiber lasers,” J. Non-Cryst. Solids 352, 2399–2403 (2006). [CrossRef]

]. These observations support the assumption, that cooperative energy transfer processes from excited Yb3+ ions or pairs to atomic defect precursors (e.g. [8

8. P. D. Dragic, C. G. Carlson, and A. Croteau, “Characterization of defect luminescence in Yb doped silica fibers: part I: NBOHC,” Opt. Express 16, 4688–4697 (2008). [CrossRef] [PubMed]

]) in the doped silica bridge the energy gap for the generation of color centers, that can otherwise be created by UV irradiation around 230 nm [5

5. M. Engholm, L. Norin, and D. Aberg, “Strong UV absorption and visible luminescence in ytterbium-doped aluminosilicate glass under UV excitation,” Opt. Lett. 32, 3352–3354 (2007). [CrossRef] [PubMed]

, 6

6. M. Engholm and L. Norin, “Preventing photodarkening in ytterbium-doped high power fiber lasers; correlation to the UV-transparency of the core glass,” Opt. Express 16, 1260–1268 (2008). [CrossRef] [PubMed]

] or by two photons of 488 nm [7

7. S. Yoo, C. Basu, A. J. Boland, C. Sones, J. Nilsson, J. K. Sahu, and D. Payne, “Photodarkening in Yb-doped aluminosilicate fibers induced by 488 nm irradiation,” Opt. Lett. 32, 1626–1628 (2007). [CrossRef] [PubMed]

].

6. Conclusions

We investigated the photodarkening kinetics of Yb doped fibers codoped with aluminum and phosphorus. The reduction of the PD loss αeq and the rate constant τ-1 by enhanced codopant concentrations could be quantified, whereof the distinct diminution of the pump-induced loss is most important for the application of Yb laser fibers.

The obvious correlation of the PD loss with the intensity of NIR-excited cooperative luminescence encourages the supposition that efficient cooperative energy transfer processes from excited Yb3+ ions could also assist the formation of color centers.

Acknowledgment

We thank the German Federal Ministry of Education and Research (BMBF) for financial support within the research initiative BRIOLAS.

References and links

1.

J. Koponen, M. Söderlund, H. J. Hoffman, D. Kliner, and J. Koplow, “Photodarkening Measurements in Large-Mode-Area Fibers,” Proc. SPIE 6453, 64531E-1-11 (2007).

2.

A. V. Shubin, M. V. Yashkov, M. A. Melkumov, S. A. Smirnow, I. A. Bufetov, and E. M. Dianov, “Photodarkening of aluminosilicate and phosphosilicate Yb-doped fibers,” in Conf. Digest of CLEO Europe-EQEC 2007, CJ3-1-THU (2007).

3.

S. Jetschke, S. Unger, U. Röpke, and J. Kirchhof, “Photodarkening in Yb doped fibers: experimental evidence of equilibrium states depending on the pump power,” Opt. Express 15, 14838–14843 (2007). [CrossRef] [PubMed]

4.

M. J. Söderlund, J. J. Montiel i Ponsoda, S. K. T. Tammela, K. Ylä-Jarkko, A. Salokatve, and S. Honkanen, “Mode-induced transverse photodarkening loss variations in large-mode-area ytterbium doped silica fibers,” Opt. Express 16, 10633–10640 (2008). [CrossRef] [PubMed]

5.

M. Engholm, L. Norin, and D. Aberg, “Strong UV absorption and visible luminescence in ytterbium-doped aluminosilicate glass under UV excitation,” Opt. Lett. 32, 3352–3354 (2007). [CrossRef] [PubMed]

6.

M. Engholm and L. Norin, “Preventing photodarkening in ytterbium-doped high power fiber lasers; correlation to the UV-transparency of the core glass,” Opt. Express 16, 1260–1268 (2008). [CrossRef] [PubMed]

7.

S. Yoo, C. Basu, A. J. Boland, C. Sones, J. Nilsson, J. K. Sahu, and D. Payne, “Photodarkening in Yb-doped aluminosilicate fibers induced by 488 nm irradiation,” Opt. Lett. 32, 1626–1628 (2007). [CrossRef] [PubMed]

8.

P. D. Dragic, C. G. Carlson, and A. Croteau, “Characterization of defect luminescence in Yb doped silica fibers: part I: NBOHC,” Opt. Express 16, 4688–4697 (2008). [CrossRef] [PubMed]

9.

T. Kitabayashi, M. Ikeda, M. Nakai, T. Sakai, K. Himeno, and K. Ohashi, “Population Inversion Factor Dependence of Photodarkening of Yb-doped Fibers and its Suppression by Highly Aluminium Doping,” in OFC/NFOE Conference on CD-ROM (Opt. Society of America, Washington, DC, 2006), OThC5 (2006).

10.

S. Unger, A. Schwuchow, S. Jetschke, V. Reichel, A. Scheffel, and J. Kirchhof, “Optical properties of Yb-doped laser fibers in dependence on codopants and preparation conditions,” Proc. SPIE 6890, 16 (2008).

11.

M. A. Melkumov, I. A. Bufetov, K. S. Kratsov, A. V. Shubin, and E. M. Dianov, “Lasing parameters of ytterbium-doped fibres doped with P2O5 and Al2O3,” Quantum Electron. 34, 843–848 (2004).

12.

J. Kirchhof, S. Unger, A. Schwuchow, S. Grimm, and V. Reichel, “Materials for high-power fiber lasers,” J. Non-Cryst. Solids 352, 2399–2403 (2006). [CrossRef]

13.

J. Kirchhof, S. Unger, and A. Schwuchow, “Properties of Yb-doped materials for solid and microstructured high power fiber lasers”, in Proceedings of ICMAT 2007 Symposium on Microstructured and Nanostructured Optical Fibers, Singapore, 1–6 July, 2007.

14.

S. Unger, A. Schwuchow, J. Dellith, and J. Kirchhof, “Codoped materials for high power fiber lasers — diffusion behaviour and optical properties,” Proc. SPIE 6469, 13 (2007).

15.

J. Kirchhof, S. Unger, A. Schwuchow, S. Jetschke, and B. Knappe, “Dopant interactions in high-power laser fibers,” Proc. SPIE 5723, 261–272 (2005). [CrossRef]

OCIS Codes
(060.2270) Fiber optics and optical communications : Fiber characterization
(160.2290) Materials : Fiber materials
(160.5690) Materials : Rare-earth-doped materials

ToC Category:
Fiber Optics and Optical Communications

History
Original Manuscript: July 31, 2008
Revised Manuscript: September 4, 2008
Manuscript Accepted: September 10, 2008
Published: September 17, 2008

Citation
Sylvia Jetschke, Sonja Unger, Anka Schwuchow, Martin Leich, and Johannes Kirchhof, "Efficient Yb laser fibers with low photodarkening by optimization of the core composition," Opt. Express 16, 15540-15545 (2008)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-16-20-15540


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References

  1. J. Koponen, M. Söderlund, H. J. Hoffman, D. Kliner, and J. Koplow, "Photodarkening Measurements in Large-Mode-Area Fibers," Proc. SPIE 6453, 64531E-1-11 (2007).
  2. A. V. Shubin, M. V. Yashkov, M. A. Melkumov, S. A. Smirnow, I. A. Bufetov, and E. M. Dianov, "Photodarkening of aluminosilicate and phosphosilicate Yb-doped fibers," in Conf. Digest of CLEO Europe-EQEC 2007, CJ3-1-THU (2007).
  3. S. Jetschke, S. Unger, U. Röpke, and J. Kirchhof, "Photodarkening in Yb doped fibers: experimental evidence of equilibrium states depending on the pump power," Opt. Express 15, 14838-14843 (2007). [CrossRef] [PubMed]
  4. M. J. Söderlund, J. J. Montiel i Ponsoda, S. K. T. Tammela, K. Ylä-Jarkko, A. Salokatve, and S. Honkanen, "Mode-induced transverse photodarkening loss variations in large-mode-area ytterbium doped silica fibers," Opt. Express 16, 10633-10640 (2008). [CrossRef] [PubMed]
  5. M. Engholm, L. Norin, and D. Aberg, "Strong UV absorption and visible luminescence in ytterbium-doped aluminosilicate glass under UV excitation," Opt. Lett. 32, 3352-3354 (2007). [CrossRef] [PubMed]
  6. M. Engholm and L. Norin, "Preventing photodarkening in ytterbium-doped high power fiber lasers; correlation to the UV-transparency of the core glass," Opt. Express 16, 1260-1268 (2008). [CrossRef] [PubMed]
  7. S. Yoo, C. Basu, A. J. Boland, C. Sones, J. Nilsson, J. K. Sahu, and D. Payne, "Photodarkening in Yb-doped aluminosilicate fibers induced by 488 nm irradiation," Opt. Lett. 32, 1626-1628 (2007). [CrossRef] [PubMed]
  8. P. D. Dragic, C. G. Carlson, and A. Croteau, "Characterization of defect luminescence in Yb doped silica fibers: part I: NBOHC," Opt. Express 16, 4688-4697 (2008). [CrossRef] [PubMed]
  9. T. Kitabayashi, M. Ikeda, M. Nakai, T. Sakai, K. Himeno, and K. Ohashi, "Population Inversion Factor Dependence of Photodarkening of Yb-doped Fibers and its Suppression by Highly Aluminium Doping," in OFC/ NFOE Conference on CD-ROM (Opt. Society of America, Washington, DC, 2006), OThC5 (2006).
  10. S. Unger, A. Schwuchow, S. Jetschke, V. Reichel, A. Scheffel, and J. Kirchhof, "Optical properties of Yb-doped laser fibers in dependence on codopants and preparation conditions," Proc. SPIE 6890, 16 (2008).
  11. M. A. Melkumov, I. A. Bufetov, K. S. Kratsov, A. V. Shubin, and E. M. Dianov, "Lasing parameters of ytterbium-doped fibres doped with P2O5 and Al2O3," Quantum Electron. 34, 843-848 (2004).
  12. J. Kirchhof, S. Unger, A. Schwuchow, S. Grimm, and V. Reichel, "Materials for high-power fiber lasers," J. Non-Cryst. Solids 352, 2399-2403 (2006). [CrossRef]
  13. J. Kirchhof, S. Unger, and A. Schwuchow, "Properties of Yb-doped materials for solid and microstructured high power fiber lasers", in Proceedings of ICMAT 2007 Symposium on Microstructured and Nanostructured Optical Fibers, Singapore, 1-6 July, 2007.
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