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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 18, Iss. 18 — Aug. 30, 2010
  • pp: 19009–19019
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Long range surface plasmons on asymmetric suspended thin film structures for biosensing applications

Qiao Min, Chengkun Chen, Pierre Berini, and Reuven Gordon  »View Author Affiliations


Optics Express, Vol. 18, Issue 18, pp. 19009-19019 (2010)
http://dx.doi.org/10.1364/OE.18.019009


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Abstract

We show that long-range surface plasmons (LRSPs) are supported in a physically asymmetric thin film structure, consisting of a low refractive index medium on a metal slab, supported by a high refractive index dielectric layer (membrane) over air, as a suspended waveguide. For design purposes, an analytic formulation is derived in 1D yielding a transcendental equation that ensures symmetry of the transverse fields of the LRSP within the metal slab by constraining its thicknesses and that of the membrane. Results from the formulation are in quantitative agreement with transfer matrix calculations for a candidate slab waveguide consisting of an H2O-Au-SiO2-air structure. Biosensor-relevant figures of merit are compared for the asymmetric and symmetric structures, and it is found that the asymmetric structure actually improves performance, despite higher losses. The finite difference method is also used to analyse metal stripes providing 2D confinement on the structure, and additional constraints for non-radiative LRSP guiding thereon are discussed. These results are promising for sensors that operate with an aqueous solution that would otherwise require a low refractive index-matched substrate for the LRSP.

© 2010 OSA

1. Introduction

While surface plasmons are of great interest for many applications [1

1. W. L. Barnes, A. Dereux, and T. W. Ebbesen, “Surface plasmon subwavelength optics,” Nature 424(6950), 824–830 (2003). [CrossRef] [PubMed]

], including biosensors [2

2. B. Liedberg, C. Nylander, and I. Lundstrom, “Surface plasmon resonance for gas detection and biosensing,” Sens. Actuators 4, 299–304 (1983). [CrossRef]

10

10. J. Homola, “Surface plasmon resonance sensors for detection of chemical and biological species,” Chem. Rev. 108(2), 462–493 (2008). [CrossRef] [PubMed]

], waveguides and photonic circuits [11

11. P. Berini, “Plasmon-polariton waves guided by thin lossy metal films of finite width: Bound modes of symmetric structures,” Phys. Rev. B 61(15), 10484–10503 (2000). [CrossRef]

23

23. A. V. Krasavin and A. V. Zayats, “Three-dimensional numerical modeling of photonic integration with dielectric-loaded SPP waveguides,” Phys. Rev. B 78(4), 045425 (2008). [CrossRef]

], a major challenge remains overcoming propagation losses, for which long-range surface plasmons (LRSPs) have been investigated extensively [24

24. P. Berini, “Long-range surface plasmon-polaritons,” Adv. Opt. Phot. 1(3), 484–588 (2009). [CrossRef]

]. The long propagating lengths achievable with LRSPs potentially enable numerous applications, including biosensors having a high sensitivity and a low detection limit [8

8. P. Berini, “Bulk and surface sensitivities of surface plasmon waveguides,” N. J. Phys. 10(10), 105010 (2008). [CrossRef]

].

Past work on LRSPs was based mainly on symmetric insulator-metal-insulator (IMI) structures, which use a thin metal slab (infinite width) or stripe (finite width) to achieve low loss [24

24. P. Berini, “Long-range surface plasmon-polaritons,” Adv. Opt. Phot. 1(3), 484–588 (2009). [CrossRef]

]. (The LRSP in the thin metal slab and stripe correspond to the sb and ssb0 modes respectively [24

24. P. Berini, “Long-range surface plasmon-polaritons,” Adv. Opt. Phot. 1(3), 484–588 (2009). [CrossRef]

].) Allowing the structure to become slightly asymmetric introduces cut-off conditions for the LRSP, constraining the dimensions of the metal slab or stripe, or the operating wavelength [25

25. D. Sarid, “Long-range surface-plasma waves on very thin metal-films,” Phys. Rev. Lett. 47(26), 1927–1930 (1981). [CrossRef]

30

30. I. Breukelaar, R. Charbonneau, and P. Berini, “Long-Range Surface Plasmon-Polariton Mode Cutoff and Radiation in Embedded Strip Waveguides,” J. Appl. Phys. 100(4), 043104 (2006). [CrossRef]

]. As the LRSP in an asymmetric structure approaches cut-off, its propagation length increases, but its confinement rapidly diminishes as does its coupling efficiency to finite-sized beams.

In practice, such symmetric (or slightly asymmetric) LRSP waveguides are not always convenient. Within the context of biosensors, for example, matching the refractive index of an aqueous sensing solution requires a cladding material having a refractive index of about 1.31 - 1.33 (depending on the operating wavelength). Few candidate materials exist satisfying this requirement; two are Teflon and Cytop. Teflon has an index that is slightly below that of de-ionised water and Cytop has an index that is slightly above. Both have been used to support metal slabs or stripes propagating LRSPs through aqueous solutions [31

31. A. W. Wark, H. J. Lee, and R. M. Corn, “Long-range surface plasmon resonance imaging for bioaffinity sensors,” Anal. Chem. 77(13), 3904–3907 (2005). [CrossRef] [PubMed]

34

34. R. Daviau, E. Lisicka-Skrzek, R. N. Tait, and P. Berini, “Broadside excitation of surface plasmon waveguides on Cytop,” Appl. Phys. Lett. 94(9), 091114 (2009). [CrossRef]

].

Enlarging the set of materials that could be used requires finding structures that are physically asymmetric but still support LRSPs. One approach involves combining thin layers of materials, as in Ref. [35

35. R. Slavík and J. Homola, “Optical multilayers for LED-based surface plasmon resonance sensors,” Appl. Opt. 45(16), 3752–3759 (2006). [CrossRef] [PubMed]

], where a Teflon/Ta2O5 bi-layer system was used to match (effectively) the index of the aqueous environment on the other side of an Au slab. A second approach involves combining a finite 1D photonic crystal, which can support Bloch surface waves in the bandgap, with an Au slab (and the bounding medium on the other side) such that a symmetric LRSP field distribution is achieved throughout the structure [36

36. V. N. Konopsky and E. V. Alieva, “Long-range propagation of plasmon polaritons in a thin metal film on a one-dimensional photonic crystal surface,” Phys. Rev. Lett. 97(25), 253904 (2006). [CrossRef]

]. A third approach is to minimally perturb the symmetry by using an ultrathin freestanding dielectric membrane to support the metal film and allowing the sensing environment to bound both sides of the structure [37

37. P. Berini, R. Charbonneau, and N. Lahoud, “Long-range surface plasmons on ultrathin membranes,” Nano Lett. 7(5), 1376–1380 (2007). [CrossRef] [PubMed]

,38

38. P. Berini, R. Charbonneau, and N. Lahoud, “Long-range surface plasmons along membrane-supported metal stripes,” IEEE J. Sel. Top. Quantum Electron. 14(6), 1479–1495 (2008). [CrossRef]

].

Building on these ideas, we propose in this paper a novel asymmetric insulator-metal-insulator-insulator (IMII) structure that can support LRSP waves. The IMII waveguide works by effectively restoring the symmetry of the LRSP transverse fields within the metal film. The generic 1D IMII slab waveguide is investigated analytically first, and a TM (transverse-magnetic) transcendental equation that ensures LRSP propagation is derived. Cases implemented with specific materials are then verified quantitatively by the transfer matrix method (TMM), by which the surface sensitivity [8

8. P. Berini, “Bulk and surface sensitivities of surface plasmon waveguides,” N. J. Phys. 10(10), 105010 (2008). [CrossRef]

] and the figure of merit [39

39. P. Berini, “Figures of merit for surface plasmon waveguides,” Opt. Express 14(26), 13030–13042 (2006). [CrossRef] [PubMed]

] of the proposed waveguide are also obtained. The corresponding 2D metal stripe structure is then investigated by the finite difference method (FDM), which shows parametric regimes where effective LRSP guiding can be accomplished. Results are given for a candidate structure relevant to biosensing, consisting of an H2O - Au - SiO2 - air suspended structure, which has a potential advantage over the membrane waveguide of Refs. [37

37. P. Berini, R. Charbonneau, and N. Lahoud, “Long-range surface plasmons on ultrathin membranes,” Nano Lett. 7(5), 1376–1380 (2007). [CrossRef] [PubMed]

] and [38

38. P. Berini, R. Charbonneau, and N. Lahoud, “Long-range surface plasmons along membrane-supported metal stripes,” IEEE J. Sel. Top. Quantum Electron. 14(6), 1479–1495 (2008). [CrossRef]

] in that integration with microfluidic channels should be easier to achieve.

2. LRSP along an IMII slab structure (1D)

2.1 Geometry of the IMII slab waveguide

The 1D IMII structure is studied first in order to provide insight into the conditions under which the LRSP may be supported. Figure 1(a)
Fig. 1 (a) Schematic of a 1D IMII slab waveguide; the layers from top to bottom are H2O, Au, SiO2 and air, respectively. (b) Sketch of the transverse magnetic field of the symmetry constrained LRSP (dashed curves) having identical field values along the upper and lower boundaries of the Au layer.
shows an example implementation of a structure that is of interest for biosensing. All layers are infinite in the x and y directions. The LRSP is assumed to propagate along the + x-direction at a vacuum wavelength of λ0 =1310 nm according to e+j βx (e-j ωt time dependence assumed). The H2O region is semi-infinite and its relative permittivity is (1.3159 + j1.639 × 10−5)2. The second layer is a Au slab, which has a relative permittivity of −86.08 + j8.322 and a thickness t. Beneath the Au slab is a supporting dielectric membrane of thickness d, such as SiO2 having a relative permittivity of 2.0932. The bottom semi-infinite layer is air, having a relative permittivity of 1. (The values of relative permittivity originate from Ref. [38

38. P. Berini, R. Charbonneau, and N. Lahoud, “Long-range surface plasmons along membrane-supported metal stripes,” IEEE J. Sel. Top. Quantum Electron. 14(6), 1479–1495 (2008). [CrossRef]

]).

This structure is practical, provided that the SiO2 layer is thick enough to be mechanically stable and deposited without too much compressive strain. It can be fabricated by etching through an underlying Si substrate (not shown) to release the SiO2 layer, thereby creating a free-standing SiO2 membrane supported around its perimeter [37

37. P. Berini, R. Charbonneau, and N. Lahoud, “Long-range surface plasmons on ultrathin membranes,” Nano Lett. 7(5), 1376–1380 (2007). [CrossRef] [PubMed]

]. The sensitivity of the LRSP in this structure to changes in an adlayer located at the Au/ H2O interface is high, based on results obtained for similar structures [8

8. P. Berini, “Bulk and surface sensitivities of surface plasmon waveguides,” N. J. Phys. 10(10), 105010 (2008). [CrossRef]

], and based on computations given below.

2.2 Theoretical model of the IMII: restored LRSP symmetry in the metal

In the symmetric IMI structure, the transverse LRSP mode fields are symmetric about the centre plane bisecting the metal slab, so a transverse field is identical along its top and bottom boundaries. Building on this point, one approach to obtaining a low-loss IMII structure is to find the thickness of the dielectric layer d that restores the symmetry of the transverse LRSP mode fields within the metal slab. Practically, this is achieved by enforcing that the transverse magnetic field (and transverse electric field) be identical along its boundaries, as sketched in Fig. 1(b). Although field symmetry over the full cross-section is not achieved, symmetry within the metal slab is achieved, thus capturing an IMII configuration that supports a LRSP; this LRSP shall henceforth be referred to as the “symmetry-constrained LRSP”.

First, we write the transverse magnetic field in the different layers, Hi·y, for a TM mode:

{H1y=Aek1(zt2)                       in H2OH2y=Bek2(z+t2)+Cek2(zt2)         in AuH3y=Dek3(z+t2+d)+Fek3(z+t2)  in SiO2H4y=Gek4(z+t2+d)           in Air
(1)

The corresponding longitudinal electric field in each layer Ei·x is obtained from:
Eix=j1ωε0εiHiyz
(2)
A, B, C, D, F, G are the amplitude coefficients for Hi·y and Ei·x at the boundaries. Subscripts 1-4 indicate the H2O, Au, SiO2 and air layers, respectively, and ki = (β 2-k0 2 εi)1/2 where k0 represents the vacuum wavenumber, εi is the complex relative permittivity of the i th layer and β is the complex TM mode wavenumber. Then by applying the boundary conditions (tangential fields must match) to Eqs. (1) and (2), we obtain the β-d-t transcendental equation for TM modes on this structure:
e2k3d=(r3(Rek2t+ek2t)r2(Rek2tek2t))(r3r4)(r3(Rek2t+ek2t)+r2(Rek2tek2t))(r3+r4)
(3)
where ri=kiεi and R=r2+r1r2r1.In the lossless case (Im{εi,β} = 0) mode cut-off occurs when β = k0ε1 1/2 (mode wavenumber equals the wavenumber of plane waves in H2O). Substituting this condition into Eq. (3) yields the following equation which constrains d and t at the cut-off point of the TM modes:
e2k3d=(r3cosh(k2t)r2sinh(k2t))(r3r4)(r3cosh(k2t)+r2sinh(k2t))(r3+r4)
(4)
As mentioned above, the transverse magnetic field of the LRSP must be identical along the boundaries of the metal slab if the field is to be symmetric therein; this implies B = C. Adding this constraint to the boundary conditions (tangential fields must match), and applying them to Eqs. (1) and (2) yields:
e2k3d=(r3cosh(k2t2)r2sinh(k2t2))(r3r4)(r3cosh(k2t2)+r2sinh(k2t2))(r3+r4)
(5)
and:

tanh(k2t2)=k1ε2k2ε1
(6)

Thus, the introduction of the additional constraint B = C yields two transcendental equations, instead of one (Eq. (3)) as is usually the case; the system is overspecified with this constraint, and to remain consistent, the Eq. (5) and (6) must be simultaneously satisfied to provide the symmetry-constrained LRSP solution.Eq. (6) is generated from the field solutions in the H2O and Au layers only (H1y, H2y, E1x, E2x), and is the same as for the LRSP of the symmetric IMI [26

26. J. J. Burke, G. I. Stegeman, and T. Tamir, “Surface-polariton-like waves guided by thin, lossy metal films,” Phys. Rev. B Condens. Matter 33(8), 5186–5201 (1986). [CrossRef] [PubMed]

]. The symmetry-constrained LRSP satisfies Eqs. (5) and (6) simultaneously in the lossless case only (Im{εi,β} = 0). A solution strategy then consists of first solving Eq. (6) using a root-finding algorithm to determine β for a value of t, and then inserting both values into Eq. (5) to determine d directly. Equations (5) and (6) are thus useful for generating t, d pairs for which the LRSP is symmetry-constrained. Equation (3) always holds (including losses) so the complex mode wavenumber (including attenuation) can then be readily determined for a particular design.

Figure 2(a)
Fig. 2 (a) Symmetry-constrained (blue curve) and cut-off (green curve) thicknesses for the LRSP in the IMII of interest (H2O - Au - SiO2 - air at 1310 nm). (b) Effective index (blue curve) and attenuation (red curve) of the symmetry-constrained LRSP in the IMII of interest (H2O - Au - SiO2 - air at 1310 nm) as a function of the Au slab thickness.
shows the collection of thicknesses t and d satisfying Eq. (5) for the LRSP in the IMII considered (H2O - Au - SiO2 - air at 1310 nm) in the lossless case, and so corresponds to designs for which the LRSP is symmetry-constrained. Note that the thinner the Au slab, the thicker the SiO2 layer must be to compensate for the index discrepancy between H2O and air. For example, for a 50 nm thick Au slab, a 342 nm thick SiO2 layer is needed, but for a 20 nm thick Au slab, a 382 nm thick SiO2 layer is needed. The other curve in Fig. 2(a) corresponds to cut-off configurations obtained using Eq. (4), below which there is no purely bound LRSP. The symmetry-constrained designs are above cut-off but as the metal slab thickness decreases, cut-off is approached.

Figure 2(b) shows the effective index (neff) of the symmetry-constrained LRSP computed using Eq. (5), which increases with Au thickness as expected, approaching limiting values when the Au thickness is larger than ~100 nm. When the Au layer is thinner, the effective index is close to the refractive index of H2O.

2.3 Computations using the transfer matrix method

The transfer matrix method (TMM) is broadly used for solving the modes of multilayer slab waveguides. The formulation reported in Ref. [40

40. C. Chen, P. Berini, D. Feng, S. Tanev, and V. Tzolov, “Efficient and accurate numerical analysis of multilayer planar optical waveguides in lossy anisotropic media,” Opt. Express 7(8), 260–272 (2000). [CrossRef] [PubMed]

] was applied to verify the theory presented in Subsection 2.2.

Figure 3(a)
Fig. 3 (a) Effective index (blue solid) and attenuation (red dashed) of the LRSP on the IMII of interest (H2O - Au - SiO2 - air at 1310 nm) for two thicknesses of the Au slab (20 and 50 nm) computed by the TMM. The values marked by the stars and the pentagons (green and magenta) were computed for the symmetry-constrained LRSP via Eq. (5). (b) Bulk (∂neff/∂nc - blue solid) and surface (∂neff/∂a - red dashed) sensitivities, and (c) surface sensing parameter G (blue solid) and M2 figure of merit (red dashed), of the LRSP on the 1D IMII of interest. (d) Distribution of the Hy field component of the LRSP on the IMII of interest for t = 50 nm and d = 341.7 nm (Blue thick), and on the corresponding IMI (H2O-Au-H2O with t = 50 nm, red thin); the bottom boundary of the Au slab is located at z = 0.
shows the effective index and attenuation of the LRSP in the IMII of interest as a function of the membrane thickness for 20 and 50 nm thick Au slabs computed via the TMM. There is excellent quantitative agreement in the effective index between the TMM results (curves) and the theory for the symmetry-constrained LRSP (Eq. (5) - stars). When the Au slab is 50 nm thick, the symmetry-constrained LRSP occurs at d = 341.7 nm and its effective index and attenuation (TMM) are 1.324633 and 31.39 dB/mm, respectively. When the Au slab is 20 nm thick, the symmetry-constrained LRSP occurs at d = 381.5 nm and its effective index and attenuation (TMM) are 1.3182884 and 3.26 dB/mm, respectively.

The lowest attenuation does not occur for the symmetry-constrained LRSP, but rather for a slightly asymmetric LRSP at a nearby membrane thickness. Further away from the symmetry-constrained design, the LRSP becomes increasingly localised to the Au/H2O interface for increasing d, and to the Au/SiO2 interface for decreasing d. The LRSP tends towards cut-off with decreasing d, explaining the decreasing effective index.

Figure 3(c) shows the surface sensing parameter G and the M2 figure of merit [8

8. P. Berini, “Bulk and surface sensitivities of surface plasmon waveguides,” N. J. Phys. 10(10), 105010 (2008). [CrossRef]

,39

39. P. Berini, “Figures of merit for surface plasmon waveguides,” Opt. Express 14(26), 13030–13042 (2006). [CrossRef] [PubMed]

] for different SiO2 membrane thicknesses, calculated using the TMM. G is the ratio of the surface sensitivity to the normalised attenuation (keff), and is particularly relevant for surface sensing [8

8. P. Berini, “Bulk and surface sensitivities of surface plasmon waveguides,” N. J. Phys. 10(10), 105010 (2008). [CrossRef]

]. M2 measures the confinement-to-loss ratio, where confinement is defined as the mode’s distance from the light-line [39

39. P. Berini, “Figures of merit for surface plasmon waveguides,” Opt. Express 14(26), 13030–13042 (2006). [CrossRef] [PubMed]

]. Both G and M2 are maximised at the same membrane thickness, which is fairly close to the symmetry-constrained design. For example, when the Au slab thickness is t = 50 nm, G and M2 peak at d = 350 nm (the symmetry-constrained membrane thickness in this case is d = 341.7 nm). Thus the symmetry-constrained structure generates good designs for sensing applications.

To investigate the influence of an H2O layer of finite thickness and an additional air top-layer, we also calculated the effective index (neff) with different H2O layer thicknesses for the 50 nm gold layer symmetry-constrained configuration. For a distance of one free-space wavelength (1310 nm), the real part of the effective index of the mode shows only 0.4% change as compared to the semi-infinite H2O layer (shown in Table 1). The percentage change then drops by an order of magnitude for each additional wavelength in thickness.

2.4 Comparison with TE and TM dielectric waveguide modes

The existence of TE and TM modes in the corresponding dielectric slab waveguide (i.e., the IMII without the Au slab) can lead to leakage in the case of the 2D metal stripe waveguide (Section 3). This occurs when the effective index of the LRSP on the IMII becomes less than that of the dielectric slab modes on either side of the Au stripe [38

38. P. Berini, R. Charbonneau, and N. Lahoud, “Long-range surface plasmons along membrane-supported metal stripes,” IEEE J. Sel. Top. Quantum Electron. 14(6), 1479–1495 (2008). [CrossRef]

].

Figure 4(a)
Fig. 4 (a) Effective indices for TE0 (blue curve), TM0 (red curve) and symmetry-constrained LRSP (green curve) modes as a function of SiO2 thickness in the IMII of interest (H2O - Au - SiO2 - air at 1310 nm). (b) Same as Part (a), except using Si3N4 as the membrane (the refractive index of Si3N4 is ~2).
shows the effective index of the symmetry-constrained LRSP in the IMII of interest (H2O - Au - SiO2 - air at 1310 nm), and of the TE0 and TM0 modes in the corresponding dielectric slab waveguide. When the thickness of the membrane (d) is less than 390 nm, the LRSP has a larger effective index than the TE0 and TM0 modes. From Fig. 2(a), this range of thickness (d < 390 nm) corresponds to an Au slab thickness (t) that is greater than 18 nm. It is therefore expected that the corresponding metal stripe waveguide will support a purely bound (non-radiative) symmetry-constrained LRSP for d < 390 nm and t > 18 nm (approximately). Note that this additional constraint leads to a lower bound on the Au thickness, and thus a lower bound on the achievable attenuation.

The effective indices for the case of Si3N4 as the membrane are also computed, as shown in Fig. 4(b). In this case, the effective index of the TE0 mode is larger than that of the symmetry-constrained LRSP over the entire range of membrane thickness, suggesting that Si3N4 is not a good choice for the corresponding metal stripe waveguide.

3. LRSP along an IMII stripe structure (2D)

3.1 Geometry of the IMII stripe waveguide

For waveguide and integrated optics applications, a stripe geometry providing confinement in the plane transverse to the direction of propagation is typically preferred to a slab. Figure 5
Fig. 5 Sketch of a 2D IMII stripe waveguide of width w; the layers are the same as in Fig. 1.
shows the stripe structure that corresponds to the slab of Fig. 1. The metal stripe of width w provides additional confinement in the y dimension, and propagation occurs along the stripe in the x dimension. The same material parameters and operating wavelength (as in Subsection 2.1) are retained and the width of the Au stripe is selected as being w = 5 μm. Due to the geometrical complexity of the structure, theoretical and TMM approaches are not suitable for analysis, so the finite-difference method (FDM) implemented in commercial software [41

41. Lumerical Solutions, Inc., http://www.lumerical.com.

] was used to compute the LRSP mode characteristics.

3.2 Finite difference results

The symmetry-constrained LRSP occurs at d ~330 and 380 nm in the case of the 50 and 20 nm thick Au stripes, respectively (as shown in Fig. 7
Fig. 7 Distribution of the transverse magnetic field (Hy) of the symmetry-constrained LRSP over the cross-section of the stripe IMII of interest (w = 5 μm, H2O - Au - SiO2 - air at 1310 nm); (a) t = 50 nm, d = 330 nm; (b) t = 20 nm, d = 380 nm.
), similarly to the slab waveguide (Fig. 4). One reason for the similarity is the large width selected for the stripe (w = 5 μm) which reduces the interaction of the LRSP fields with the stripe corners. Another reason is the relatively small contrast between the selected membrane material (SiO2) and H2O. Indeed assuming Cytop [34

34. R. Daviau, E. Lisicka-Skrzek, R. N. Tait, and P. Berini, “Broadside excitation of surface plasmon waveguides on Cytop,” Appl. Phys. Lett. 94(9), 091114 (2009). [CrossRef]

] for the membrane (which has an index close to H2O) renders the slab and stripe results essentially indistinguishable. Also, the lower the index of the membrane the larger the design space for the stripe waveguide because radiation into the TE0 and TM0 modes of the dielectric slab (on either side of the stripe) occurs over a smaller range of membrane thickness.

The similarity of the results to the 1D case is interesting because it allows use of the 1D theory (Subsection 2.2) to find good initial symmetry-constrained designs for the stripe waveguide.

Figure 7 shows the transverse magnetic field distribution (Hy) of the LRSP over the cross-section of a stripe IMII with symmetry-constrained thicknesses as computed by the FDM. For a Au stripe thickness of t = 50 nm, the symmetry-constrained LRSP occurs for a membrane thickness of d = 330 nm, and for t = 20 nm, then d = 380 nm. The Hy field along the top boundary of the Au stripe is identical to that along its bottom boundary as observed.

5. Summary and concluding remarks

We demonstrated that LRSPs are supported in a physically asymmetric IMII thin slab structure, consisting of a low index medium on a metal slab on a dielectric layer (membrane) over air, as a suspended waveguide. An analytic formulation was derived in 1D yielding a transcendental equation that ensures symmetry of the transverse fields of the LRSP within the metal slab by constraining the thicknesses of the metal slab and the membrane. Mode characteristics obtained via the formulation for this “symmetry-constrained” LRSP are in quantitative agreement with TMM calculations for a candidate slab waveguide consisting of an H2O-Au-SiO2-air suspended structure. We found that the symmetry-constrained LRSP exhibits fairly low attenuation at a particular metal slab thickness. Furthermore, its attenuation and confinement decreased with decreasing metal thickness, following the conventional IMI. We also found that the thinner the metal slab, the thicker the dielectric layer needs to be to satisfy the symmetry constraint because the LRSP extends further into the dielectric for a thinner metal slab. As expected, the LRSP in this IMII waveguide has a high surface sensitivity as well as high figures of merit (G for surface sensing and M2 for waveguiding) supporting its potential for sensing applications.

The FDM was used to analyze metal stripes (instead of metal slabs) on the same suspended structure. A symmetry-constrained LRSP confined in the plane transverse to the direction of propagation was found thereon, but the metal stripe design space is more limited than that of the corresponding metal slab because of an additional constraint to non-radiative LRSP guiding: the effective index of the LRSP must remain above those of the TE0 and TM0 modes supported by the dielectric slabs on either side of the stripe to ensure no lateral radiation into these modes. This constraint places upper bounds on the thickness and the refractive index of the membrane, and on how thin the stripe may be, thereby also placing a lower bound on the LRSP attenuation. Despite these constraints, practical stripe designs have been found for the candidate structure (w = 5 μm, t = 20 nm, d = 380 nm, yielding a symmetry-constrained LRSP attenuation of ~3.27 dB/mm at λ0 = 1310 nm).

The structures are promising for sensors that operate with an aqueous solution and would otherwise require a low refractive index matched substrate to achieve LRSP guiding.

Acknowledgements

This work was supported by the NSERC Strategic Network for Bioplasmonic Systems (BiopSys), Canada.

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P. Berini, “Plasmon-polariton waves guided by thin lossy metal films of finite width: Bound modes of symmetric structures,” Phys. Rev. B 61(15), 10484–10503 (2000). [CrossRef]

12.

B. Lamprecht, J. R. Krenn, G. Schider, H. Ditlbacher, M. Salerno, N. Felidj, A. Leitner, F. R. Aussenegg, and J. C. Weeber, “Surface plasmon propagation in microscale metal stripes,” Appl. Phys. Lett. 79(1), 51–53 (2001). [CrossRef]

13.

J.-C. Weeber, J. R. Krenn, A. Dereux, B. Lamprecht, Y. Lacroute, and J.-P. Goudonnet, “Near-field observation of surface plasmon polariton propagation on thin metal stripes,” Phys. Rev. B 64(4), 045411 (2001). [CrossRef]

14.

D. F. P. Pile, T. Ogawa, D. K. Gramotnev, Y. Matsuzaki, K. C. Vernon, K. Yamaguchi, T. Okamoto, M. Haraguchi, and M. Fukui, “Two-dimensionally localized modes of a nanoscale gap plasmon waveguide,” Appl. Phys. Lett. 87(26), 261114 (2005). [CrossRef]

15.

R. Zia, M. D. Selker, and M. L. Brongersma, “Leaky and bound modes of surface plasmon waveguides,” Phys. Rev. B 71(16), 165431 (2005). [CrossRef]

16.

W. L. Barnes, “Surface plasmon-polariton length scales: a route to sub-wavelength optics,” J. Opt. A, Pure Appl. Opt. 8(4), S87–S93 (2006). [CrossRef]

17.

S. I. Bozhevolnyi, V. S. Volkov, E. Devaux, J. Y. Laluet, and T. W. Ebbesen, “Channel plasmon subwavelength waveguide components including interferometers and ring resonators,” Nature 440(7083), 508–511 (2006). [CrossRef] [PubMed]

18.

R. Charbonneau, C. Scales, I. Breukelaar, S. Fafard, N. Lahoud, G. Mattiussi, and P. Berini, “Passive integrated optics elements used on long-range surface plasmon polaritons,” J. Lightwave Technol. 24(1), 477–494 (2006). [CrossRef]

19.

J. A. Dionne, L. A. Sweatlock, H. A. Atwater, and A. Polman, “Plasmon slot waveguides: Towards chip-scale propagation with subwavelength-scale localization,” Phys. Rev. B 73, 035407 (2006). [CrossRef]

20.

S. Maier, “Effective mode volume of nanoscale plasmon cavities,” Opt. Quantum Electron. 38(1-3), 257–267 (2006). [CrossRef]

21.

G. Veronis and S. Fan, “Modes of Subwavelength Plasmonic Slot Waveguides,” J. Lightwave Technol. 25(9), 2511–2521 (2007). [CrossRef]

22.

E. Moreno, S. G. Rodrigo, S. I. Bozhevolnyi, L. Martín-Moreno, and F. J. García-Vidal, “Guiding and focusing of electromagnetic fields with wedge plasmon polaritons,” Phys. Rev. Lett. 100(2), 023901 (2008). [CrossRef] [PubMed]

23.

A. V. Krasavin and A. V. Zayats, “Three-dimensional numerical modeling of photonic integration with dielectric-loaded SPP waveguides,” Phys. Rev. B 78(4), 045425 (2008). [CrossRef]

24.

P. Berini, “Long-range surface plasmon-polaritons,” Adv. Opt. Phot. 1(3), 484–588 (2009). [CrossRef]

25.

D. Sarid, “Long-range surface-plasma waves on very thin metal-films,” Phys. Rev. Lett. 47(26), 1927–1930 (1981). [CrossRef]

26.

J. J. Burke, G. I. Stegeman, and T. Tamir, “Surface-polariton-like waves guided by thin, lossy metal films,” Phys. Rev. B Condens. Matter 33(8), 5186–5201 (1986). [CrossRef] [PubMed]

27.

L. Wendler and R. Haupt, “Long-range surface plasmon-polaritons in asymmetric layer structures,” J. Appl. Phys. 59(9), 3289–3291 (1986). [CrossRef]

28.

F. Yang, J. R. Sambles, and G. W. Bradberry, “Long-range surface modes supported by thin films,” Phys. Rev. B Condens. Matter 44(11), 5855–5872 (1991). [CrossRef] [PubMed]

29.

P. Berini, “Plasmon-Polariton Waves Guided by Thin Lossy Metal Films of Finite Width: Bound Modes of Asymmetric Structures,” Phys. Rev. B 63(12), 125417 (2001). [CrossRef]

30.

I. Breukelaar, R. Charbonneau, and P. Berini, “Long-Range Surface Plasmon-Polariton Mode Cutoff and Radiation in Embedded Strip Waveguides,” J. Appl. Phys. 100(4), 043104 (2006). [CrossRef]

31.

A. W. Wark, H. J. Lee, and R. M. Corn, “Long-range surface plasmon resonance imaging for bioaffinity sensors,” Anal. Chem. 77(13), 3904–3907 (2005). [CrossRef] [PubMed]

32.

R. Slavík and J. Homola, “Ultrahigh resolution long range surface plasmon-based sensor,” Sens. Actuators B Chem. 123(1), 10–12 (2007). [CrossRef]

33.

J. Dostálek, A. Kasry, and W. Knoll, “Long Range Surface Plasmons for Observation of Biomolecular Binding Events at Metallic Surfaces,” Plasmonics 2(3), 97–106 (2007). [CrossRef]

34.

R. Daviau, E. Lisicka-Skrzek, R. N. Tait, and P. Berini, “Broadside excitation of surface plasmon waveguides on Cytop,” Appl. Phys. Lett. 94(9), 091114 (2009). [CrossRef]

35.

R. Slavík and J. Homola, “Optical multilayers for LED-based surface plasmon resonance sensors,” Appl. Opt. 45(16), 3752–3759 (2006). [CrossRef] [PubMed]

36.

V. N. Konopsky and E. V. Alieva, “Long-range propagation of plasmon polaritons in a thin metal film on a one-dimensional photonic crystal surface,” Phys. Rev. Lett. 97(25), 253904 (2006). [CrossRef]

37.

P. Berini, R. Charbonneau, and N. Lahoud, “Long-range surface plasmons on ultrathin membranes,” Nano Lett. 7(5), 1376–1380 (2007). [CrossRef] [PubMed]

38.

P. Berini, R. Charbonneau, and N. Lahoud, “Long-range surface plasmons along membrane-supported metal stripes,” IEEE J. Sel. Top. Quantum Electron. 14(6), 1479–1495 (2008). [CrossRef]

39.

P. Berini, “Figures of merit for surface plasmon waveguides,” Opt. Express 14(26), 13030–13042 (2006). [CrossRef] [PubMed]

40.

C. Chen, P. Berini, D. Feng, S. Tanev, and V. Tzolov, “Efficient and accurate numerical analysis of multilayer planar optical waveguides in lossy anisotropic media,” Opt. Express 7(8), 260–272 (2000). [CrossRef] [PubMed]

41.

Lumerical Solutions, Inc., http://www.lumerical.com.

OCIS Codes
(130.2790) Integrated optics : Guided waves
(240.6680) Optics at surfaces : Surface plasmons
(280.1415) Remote sensing and sensors : Biological sensing and sensors

ToC Category:
Optics at Surfaces

History
Original Manuscript: July 23, 2010
Revised Manuscript: August 18, 2010
Manuscript Accepted: August 18, 2010
Published: August 20, 2010

Virtual Issues
Vol. 5, Iss. 13 Virtual Journal for Biomedical Optics

Citation
Qiao Min, Chengkun Chen, Pierre Berini, and Reuven Gordon, "Long range surface plasmons on asymmetric suspended thin film structures for biosensing applications," Opt. Express 18, 19009-19019 (2010)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-18-18-19009


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References

  1. W. L. Barnes, A. Dereux, and T. W. Ebbesen, “Surface plasmon subwavelength optics,” Nature 424(6950), 824–830 (2003). [CrossRef] [PubMed]
  2. B. Liedberg, C. Nylander, and I. Lundstrom, “Surface plasmon resonance for gas detection and biosensing,” Sens. Actuators 4, 299–304 (1983). [CrossRef]
  3. J. Homola, S. S. Yee, and G. Gauglitz, “Surface plasmon resonance sensors: review,” Sens. Actuators B Chem. 54(1-2), 3–15 (1999). [CrossRef]
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  6. A. J. Haes, S. L. Zou, G. C. Schatz, and R. P. Van Duyne, “A nanoscale optical biosensor: The long range distance dependence of the localized surface plasmon resonance of noble metal nanoparticles,” J. Phys. Chem. B 108(1), 109–116 (2004). [CrossRef]
  7. K. A. Tetz, L. Pang, and Y. Fainman, “High-resolution surface plasmon resonance sensor based on linewidth-optimized nanohole array transmittance,” Opt. Lett. 31(10), 1528–1530 (2006). [CrossRef] [PubMed]
  8. P. Berini, “Bulk and surface sensitivities of surface plasmon waveguides,” N. J. Phys. 10(10), 105010 (2008). [CrossRef]
  9. M. E. Stewart, C. R. Anderton, L. B. Thompson, J. Maria, S. K. Gray, J. A. Rogers, and R. G. Nuzzo, “Nanostructured plasmonic sensors,” Chem. Rev. 108(2), 494–521 (2008). [CrossRef] [PubMed]
  10. J. Homola, “Surface plasmon resonance sensors for detection of chemical and biological species,” Chem. Rev. 108(2), 462–493 (2008). [CrossRef] [PubMed]
  11. P. Berini, “Plasmon-polariton waves guided by thin lossy metal films of finite width: Bound modes of symmetric structures,” Phys. Rev. B 61(15), 10484–10503 (2000). [CrossRef]
  12. B. Lamprecht, J. R. Krenn, G. Schider, H. Ditlbacher, M. Salerno, N. Felidj, A. Leitner, F. R. Aussenegg, and J. C. Weeber, “Surface plasmon propagation in microscale metal stripes,” Appl. Phys. Lett. 79(1), 51–53 (2001). [CrossRef]
  13. J.-C. Weeber, J. R. Krenn, A. Dereux, B. Lamprecht, Y. Lacroute, and J.-P. Goudonnet, “Near-field observation of surface plasmon polariton propagation on thin metal stripes,” Phys. Rev. B 64(4), 045411 (2001). [CrossRef]
  14. D. F. P. Pile, T. Ogawa, D. K. Gramotnev, Y. Matsuzaki, K. C. Vernon, K. Yamaguchi, T. Okamoto, M. Haraguchi, and M. Fukui, “Two-dimensionally localized modes of a nanoscale gap plasmon waveguide,” Appl. Phys. Lett. 87(26), 261114 (2005). [CrossRef]
  15. R. Zia, M. D. Selker, and M. L. Brongersma, “Leaky and bound modes of surface plasmon waveguides,” Phys. Rev. B 71(16), 165431 (2005). [CrossRef]
  16. W. L. Barnes, “Surface plasmon-polariton length scales: a route to sub-wavelength optics,” J. Opt. A, Pure Appl. Opt. 8(4), S87–S93 (2006). [CrossRef]
  17. S. I. Bozhevolnyi, V. S. Volkov, E. Devaux, J. Y. Laluet, and T. W. Ebbesen, “Channel plasmon subwavelength waveguide components including interferometers and ring resonators,” Nature 440(7083), 508–511 (2006). [CrossRef] [PubMed]
  18. R. Charbonneau, C. Scales, I. Breukelaar, S. Fafard, N. Lahoud, G. Mattiussi, and P. Berini, “Passive integrated optics elements used on long-range surface plasmon polaritons,” J. Lightwave Technol. 24(1), 477–494 (2006). [CrossRef]
  19. J. A. Dionne, L. A. Sweatlock, H. A. Atwater, and A. Polman, “Plasmon slot waveguides: Towards chip-scale propagation with subwavelength-scale localization,” Phys. Rev. B 73, 035407 (2006). [CrossRef]
  20. S. Maier, “Effective mode volume of nanoscale plasmon cavities,” Opt. Quantum Electron. 38(1-3), 257–267 (2006). [CrossRef]
  21. G. Veronis and S. Fan, “Modes of Subwavelength Plasmonic Slot Waveguides,” J. Lightwave Technol. 25(9), 2511–2521 (2007). [CrossRef]
  22. E. Moreno, S. G. Rodrigo, S. I. Bozhevolnyi, L. Martín-Moreno, and F. J. García-Vidal, “Guiding and focusing of electromagnetic fields with wedge plasmon polaritons,” Phys. Rev. Lett. 100(2), 023901 (2008). [CrossRef] [PubMed]
  23. A. V. Krasavin and A. V. Zayats, “Three-dimensional numerical modeling of photonic integration with dielectric-loaded SPP waveguides,” Phys. Rev. B 78(4), 045425 (2008). [CrossRef]
  24. P. Berini, “Long-range surface plasmon-polaritons,” Adv. Opt. Phot. 1(3), 484–588 (2009). [CrossRef]
  25. D. Sarid, “Long-range surface-plasma waves on very thin metal-films,” Phys. Rev. Lett. 47(26), 1927–1930 (1981). [CrossRef]
  26. J. J. Burke, G. I. Stegeman, and T. Tamir, “Surface-polariton-like waves guided by thin, lossy metal films,” Phys. Rev. B Condens. Matter 33(8), 5186–5201 (1986). [CrossRef] [PubMed]
  27. L. Wendler and R. Haupt, “Long-range surface plasmon-polaritons in asymmetric layer structures,” J. Appl. Phys. 59(9), 3289–3291 (1986). [CrossRef]
  28. F. Yang, J. R. Sambles, and G. W. Bradberry, “Long-range surface modes supported by thin films,” Phys. Rev. B Condens. Matter 44(11), 5855–5872 (1991). [CrossRef] [PubMed]
  29. P. Berini, “Plasmon-Polariton Waves Guided by Thin Lossy Metal Films of Finite Width: Bound Modes of Asymmetric Structures,” Phys. Rev. B 63(12), 125417 (2001). [CrossRef]
  30. I. Breukelaar, R. Charbonneau, and P. Berini, “Long-Range Surface Plasmon-Polariton Mode Cutoff and Radiation in Embedded Strip Waveguides,” J. Appl. Phys. 100(4), 043104 (2006). [CrossRef]
  31. A. W. Wark, H. J. Lee, and R. M. Corn, “Long-range surface plasmon resonance imaging for bioaffinity sensors,” Anal. Chem. 77(13), 3904–3907 (2005). [CrossRef] [PubMed]
  32. R. Slavík and J. Homola, “Ultrahigh resolution long range surface plasmon-based sensor,” Sens. Actuators B Chem. 123(1), 10–12 (2007). [CrossRef]
  33. J. Dostálek, A. Kasry, and W. Knoll, “Long Range Surface Plasmons for Observation of Biomolecular Binding Events at Metallic Surfaces,” Plasmonics 2(3), 97–106 (2007). [CrossRef]
  34. R. Daviau, E. Lisicka-Skrzek, R. N. Tait, and P. Berini, “Broadside excitation of surface plasmon waveguides on Cytop,” Appl. Phys. Lett. 94(9), 091114 (2009). [CrossRef]
  35. R. Slavík and J. Homola, “Optical multilayers for LED-based surface plasmon resonance sensors,” Appl. Opt. 45(16), 3752–3759 (2006). [CrossRef] [PubMed]
  36. V. N. Konopsky and E. V. Alieva, “Long-range propagation of plasmon polaritons in a thin metal film on a one-dimensional photonic crystal surface,” Phys. Rev. Lett. 97(25), 253904 (2006). [CrossRef]
  37. P. Berini, R. Charbonneau, and N. Lahoud, “Long-range surface plasmons on ultrathin membranes,” Nano Lett. 7(5), 1376–1380 (2007). [CrossRef] [PubMed]
  38. P. Berini, R. Charbonneau, and N. Lahoud, “Long-range surface plasmons along membrane-supported metal stripes,” IEEE J. Sel. Top. Quantum Electron. 14(6), 1479–1495 (2008). [CrossRef]
  39. P. Berini, “Figures of merit for surface plasmon waveguides,” Opt. Express 14(26), 13030–13042 (2006). [CrossRef] [PubMed]
  40. C. Chen, P. Berini, D. Feng, S. Tanev, and V. Tzolov, “Efficient and accurate numerical analysis of multilayer planar optical waveguides in lossy anisotropic media,” Opt. Express 7(8), 260–272 (2000). [CrossRef] [PubMed]
  41. Lumerical Solutions, Inc., http://www.lumerical.com .

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