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Fabrication of a dual-layer aluminum nanowires polarization filter array |
Optics Express, Vol. 19, Issue 24, pp. 24361-24369 (2011)
http://dx.doi.org/10.1364/OE.19.024361
Acrobat PDF (1733 KB)
Abstract
In this paper we present a procedure for fabricating an array of micropolarization filter array via an optimized interference lithography and microfabrication procedure. The filter array is composed of two linear polarization filters offset by 45 degrees with pixel pitch of 18 microns. The individual polarization filters are composed of aluminum nanowires with 140 nm pitch, 140 nm height and 70 nm width. The maximum extinction ratio of the pixelated filters is measured to be 95 at 700nm wavelength.
© 2011 OSA
1. Introduction
J. G. Ok, H. J. Park, M. K. Kwak, C. A. Pina-Hernandez, S. H. Ahn, and L. J. Guo, “Continuous patterning of nanogratings by nanochannel-guided lithography on liquid resists,” Adv. Mater. (Deerfield Beach Fla.) 23(38), 4444–4448 (2011). [CrossRef] [PubMed]
V. Gruev, R. Perkins, and T. York, “CCD polarization imaging sensor with aluminum nanowire optical filters,” Opt. Express 18(18), 19087–19094 (2010). [CrossRef] [PubMed]
X. Zhao, F. Boussaid, A. Bermak, and V. G. Chigrinov, “Thin Photo-Patterned Micropolarizer Array for CMOS Image Sensors,” IEEE Photon. Technol. Lett. 21(12), 805–807 (2009). [CrossRef]
G. P. Nordin, J. T. Meier, P. C. Deguzman, and M. W. Jones, “Micropolarizer array for infrared imaging polarimetry,” J. Opt. Soc. Am. A 16(5), 1168–1174 (1999). [CrossRef]
V. Gruev, R. Perkins, and T. York, “CCD polarization imaging sensor with aluminum nanowire optical filters,” Opt. Express 18(18), 19087–19094 (2010). [CrossRef] [PubMed]
2. Overview of polarization properties
R. Perkins and V. Gruev, “Signal-to-noise analysis of Stokes parameters in division of focal plane polarimeters,” Opt. Express 18(25), 25815–25824 (2010). [CrossRef] [PubMed]
J. S. Tyo, “Optimum linear combination strategy for an N-channel polarization-sensitive imaging or vision system,” J. Opt. Soc. Am. A 15(2), 359–366 (1998). [CrossRef]
3. Microfabrication procedure for dual layer nanowire filter array
T. Weber, T. Käsebier, E. B. Kley, and A. Tünnermann, “Broadband iridium wire grid polarizer for UV applications,” Opt. Lett. 36(4), 445–447 (2011). [CrossRef] [PubMed]
M. L. Schattenburg, R. J. Aucoin, and R. C. Fleming, “Optically matched trilevel resist process for nanostructure fabrication,” J. Vac. Sci. Technol. B 13(6), 3007–3011 (1995). [CrossRef]
- (1) The starting substrate for the filter array is a microscope glass slide. The glass slide is first planerized via a chemical mechanical polishing (CMP) procedure optimized for glass substrates. The variations of the glass surface within an area of 3 cm by 3 cm are +/−5 nm. The surface of the glass slide is cleaned by soaking the sample in isopropyl alcohol and acetone separately. The glass sample is then placed in a reactive ion etching tool and the surface is further cleaned with oxygen via reactive ion etching (RIE) power of 300 W for 20 minutes.
- (2) The glass surface is coated with 140 nm of aluminum and 20 nm of SiO2 via e-beam deposition and chemical vapor deposition respectively. The SiO2 will be used as a hard mask to etch the aluminum layer.
- (3) Thin layer of photoresist is spin coated on the sample. A diluted S1805 photoresist is spin coated at 4500 rpm for 45 seconds and ~150 nm thick photoresist is created on the surface of the sample. The sample is then baked at 90° C for one minute (Fig. 2a).
- (4) The interference pattern generated by the neodymium-doped yttrium aluminum garnet laser is used to pattern the photoresist. The photoresist is exposed to the interference pattern for 35 seconds. After the exposure is completed, the sample is placed in a developer for 1 minute, followed by DI water rinse for 1 minute (Fig. 2b).
- (5) The sample is placed in the reactive ion etching inductively coupled plasma (RIE/ICP) tool and the following recipe is executed:The bottom plate of the RIE chamber is heated at 70° C. For the procedure described in Table 1 , step 1 is used to purge the chamber from any residual gasses; step 2 is used to transfer the pattern from the photoresist to the SiO2 surface (Fig. 2c); step 3 is used to etch the AlO2 followed by etching of the Al in step 4 (Fig. 2d). At the end of the procedure the chamber is purged in order to remove any residual chemicals that might be accumulated on the surface of the sample during the etching procedure. At the end of this step, the glass slide contains uniform aluminum nanowires across a circular area of 3 cm.Table 1 Reactive Ion Etching Recipe for Etching Aluminum NanowiresTable 1 Reactive Ion Etching Recipe for Etching Aluminum Nanowires
- (6) A negative SU-8 2002 photoresist is applied next on the sample. The negative photoresist, SU-8 2002, is hydrophobic and requires the applied surface to be absolutely free of any water molecules. The photoresist is spin coated at 500 rpm for 10 seconds and then at 3000 rpm for 50 seconds with 500 rpm per second acceleration. The resulting photoresist thickness is 2 μm. It is important to have a very good precise ramp up from 500 to 3000 rpm in order to obtain thickness of 2 μm (Fig. 2e).
- (7) The sample is baked at 65° C for 1 min and then at 95° C for 2 min on a hot plate. It is recommended that the sample cools down at 65° C for 1 min in order to gradually decrease the temperature of the sample. Gradual increase and decrease of the temperature during the baking process avoids rapid temperature differences and prevents the photoresist from cracking.
- (8) The photoresist is exposed at 375 nm wavelength for 22 seconds at 5mW/cm2 intensity using a Karl Zuess mask aligner. The mask used to pattern the photoresist contains 18 μm by 18 μm square checkerboard patterns (Fig. 2e). The sample is post-baked at 65° C for 1 min and then at 95° C for 3 min. The sample is cooled down at 65° C for 1 min in order to gradually decrease the temperature and minimize stress and cracking on the photoresist. The photoresist is developed for 3 min in an SU-8 developer using an ultrasound bath and gently rinsed with isopropyl alcohol at the end of the procedure. If white colored liquid appears on the surface, the photoresist is not completely developed and it is submerged in the developer again (Fig. 2f).
- (9) The sample is placed in the RIE/ICP tool and the recipe described in Table 2 is executed. The RIE/ICP recipe presented in Table 2 is very similar to the one in Table 1 and the last row in the table describes the purpose of each step. At the end of the RIE/ICP procedure, the glass slide contains pixelated nanowires polarization filters oriented at 0°. The pixel pitch of the polarization filters is 18 μm by 18 μm and the individual pixelated filters are composed of aluminum nanowires with 140nm height, 140nm periodicity and ~50% duty cycle (Fig. 2g).Table 2 Reactive Ion Etching Recipe for Etching 18 μm by 18 μm Pixelated Polarization Filters
- (10) The next step is to generate a second layer of pixelated nanowire polarization filters oriented at 45° offset from the first layer filters. First, a 250nm thick layer of SiO2 is deposited on the filter slide via PECVD. The SiO2 layer is polished and planerized via a CMP procedure. The thickness of the SiO2 layer is reduced by ~150 nm, such that the start of the second layer is immediately after the first layer of the aluminum nanowires (Fig. 2h).
- (11) Steps 2 through 10 are repeated in order to generate a second layer of pixelated aluminum nanowires polarization filters and are illustrate in Fig. 2i through Fig. 2o. In order to fabricate nanowires in the second tier whose orientation is offset by 45° with respect to the first layer, the glass sample is physically rotated by 45° prior to the interference lithography exposure described in step (4), i.e. Figure 2j. Also the same chromium mask with 18 μm by 18 μm openings is used as in step (9) and the mask is physically shifter by one pixel to the left and one pixel down compared to the first layer alignment in order to generate the necessary checker board pattern of pixelated polarization filters.
4. Results and measurements
V. Gruev, Z. Yang, J. Van der Spiegel, and R. Etienne-Cummings, “Current mode image sensor with two transistors per pixel,” IEEE Trans. Circuits Syst. I: Fundam. Theory Appl. 57(6), 1154–1165 (2010). [CrossRef]
V. Gruev, Z. Yang, J. Van der Spiegel, and R. Etienne-Cummings, “Current mode image sensor with two transistors per pixel,” IEEE Trans. Circuits Syst. I: Fundam. Theory Appl. 57(6), 1154–1165 (2010). [CrossRef]
http:\\www.opalkelly.com.
5. Summary
Acknowledgment
References and links
J. Wang, F. Walters, X. Liu, P. Sciortino, and X. Deng, “High-performance, large area, deep ultraviolet to infrared polarizers based on 40 nm line/78 nm space nanowire grids,” Appl. Phys. Lett. 90, 061104.1–061104.3 (2007). | |
T. Weber, T. Käsebier, E. B. Kley, and A. Tünnermann, “Broadband iridium wire grid polarizer for UV applications,” Opt. Lett. 36(4), 445–447 (2011). [CrossRef] [PubMed] | |
J. G. Ok, H. J. Park, M. K. Kwak, C. A. Pina-Hernandez, S. H. Ahn, and L. J. Guo, “Continuous patterning of nanogratings by nanochannel-guided lithography on liquid resists,” Adv. Mater. (Deerfield Beach Fla.) 23(38), 4444–4448 (2011). [CrossRef] [PubMed] | |
V. Gruev, R. Perkins, and T. York, “CCD polarization imaging sensor with aluminum nanowire optical filters,” Opt. Express 18(18), 19087–19094 (2010). [CrossRef] [PubMed] | |
R. Perkins and V. Gruev, “Signal-to-noise analysis of Stokes parameters in division of focal plane polarimeters,” Opt. Express 18(25), 25815–25824 (2010). [CrossRef] [PubMed] | |
V. Gruev, J. Van der Spiegel, and N. Engheta, “Dual-tier thin film polymer polarization imaging sensor,” Opt. Express 18(18), 19292–19303 (2010). [CrossRef] [PubMed] | |
M. Momeni and A. H. Titus, “An analog VLSI chip emulating polarization vision of Octopus retina,” IEEE Trans. Neural Netw. 17(1), 222–232 (2006). [CrossRef] [PubMed] | |
T. Tokuda, S. Sato, H. Yamada, K. Sasagawa, and J. Ohta, “Polarisation-analysing CMOS photosensor with monolithically embedded wire grid polarizer,” Electron. Lett. 45(4), 228–230 (2009). [CrossRef] | |
X. Zhao, F. Boussaid, A. Bermak, and V. G. Chigrinov, “Thin Photo-Patterned Micropolarizer Array for CMOS Image Sensors,” IEEE Photon. Technol. Lett. 21(12), 805–807 (2009). [CrossRef] | |
B. E. Bayer, Color Imaging Array U.S. Patent 3,971,065, (July 20, 1976). | |
G. P. Nordin, J. T. Meier, P. C. Deguzman, and M. W. Jones, “Micropolarizer array for infrared imaging polarimetry,” J. Opt. Soc. Am. A 16(5), 1168–1174 (1999). [CrossRef] | |
S. Franssila, Introduction to Microfabrication (John Wiley & Sons, West Sussex, UK, 2010). | |
J. S. Tyo, “Optimum linear combination strategy for an N-channel polarization-sensitive imaging or vision system,” J. Opt. Soc. Am. A 15(2), 359–366 (1998). [CrossRef] | |
M. L. Schattenburg, R. J. Aucoin, and R. C. Fleming, “Optically matched trilevel resist process for nanostructure fabrication,” J. Vac. Sci. Technol. B 13(6), 3007–3011 (1995). [CrossRef] | |
V. Gruev, Z. Yang, J. Van der Spiegel, and R. Etienne-Cummings, “Current mode image sensor with two transistors per pixel,” IEEE Trans. Circuits Syst. I: Fundam. Theory Appl. 57(6), 1154–1165 (2010). [CrossRef] | |
http:\\www.opalkelly.com. |
OCIS Codes
(120.5410) Instrumentation, measurement, and metrology : Polarimetry
(230.5440) Optical devices : Polarization-selective devices
(260.5430) Physical optics : Polarization
(110.5405) Imaging systems : Polarimetric imaging
ToC Category:
Instrumentation, Measurement, and Metrology
History
Original Manuscript: September 22, 2011
Revised Manuscript: November 3, 2011
Manuscript Accepted: November 3, 2011
Published: November 14, 2011
Citation
Viktor Gruev, "Fabrication of a dual-layer aluminum nanowires polarization filter array," Opt. Express 19, 24361-24369 (2011)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-19-24-24361
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References
- J. Wang, F. Walters, X. Liu, P. Sciortino, and X. Deng, “High-performance, large area, deep ultraviolet to infrared polarizers based on 40 nm line/78 nm space nanowire grids,” Appl. Phys. Lett. 90, 061104.1–061104.3 (2007).
- T. Weber, T. Käsebier, E. B. Kley, and A. Tünnermann, “Broadband iridium wire grid polarizer for UV applications,” Opt. Lett. 36(4), 445–447 (2011). [CrossRef] [PubMed]
- J. G. Ok, H. J. Park, M. K. Kwak, C. A. Pina-Hernandez, S. H. Ahn, and L. J. Guo, “Continuous patterning of nanogratings by nanochannel-guided lithography on liquid resists,” Adv. Mater. (Deerfield Beach Fla.) 23(38), 4444–4448 (2011). [CrossRef] [PubMed]
- V. Gruev, R. Perkins, and T. York, “CCD polarization imaging sensor with aluminum nanowire optical filters,” Opt. Express 18(18), 19087–19094 (2010). [CrossRef] [PubMed]
- R. Perkins and V. Gruev, “Signal-to-noise analysis of Stokes parameters in division of focal plane polarimeters,” Opt. Express 18(25), 25815–25824 (2010). [CrossRef] [PubMed]
- V. Gruev, J. Van der Spiegel, and N. Engheta, “Dual-tier thin film polymer polarization imaging sensor,” Opt. Express 18(18), 19292–19303 (2010). [CrossRef] [PubMed]
- M. Momeni and A. H. Titus, “An analog VLSI chip emulating polarization vision of Octopus retina,” IEEE Trans. Neural Netw. 17(1), 222–232 (2006). [CrossRef] [PubMed]
- T. Tokuda, S. Sato, H. Yamada, K. Sasagawa, and J. Ohta, “Polarisation-analysing CMOS photosensor with monolithically embedded wire grid polarizer,” Electron. Lett. 45(4), 228–230 (2009). [CrossRef]
- X. Zhao, F. Boussaid, A. Bermak, and V. G. Chigrinov, “Thin Photo-Patterned Micropolarizer Array for CMOS Image Sensors,” IEEE Photon. Technol. Lett. 21(12), 805–807 (2009). [CrossRef]
- B. E. Bayer, Color Imaging Array U.S. Patent 3,971,065, (July 20, 1976).
- G. P. Nordin, J. T. Meier, P. C. Deguzman, and M. W. Jones, “Micropolarizer array for infrared imaging polarimetry,” J. Opt. Soc. Am. A 16(5), 1168–1174 (1999). [CrossRef]
- S. Franssila, Introduction to Microfabrication (John Wiley & Sons, West Sussex, UK, 2010).
- J. S. Tyo, “Optimum linear combination strategy for an N-channel polarization-sensitive imaging or vision system,” J. Opt. Soc. Am. A 15(2), 359–366 (1998). [CrossRef]
- M. L. Schattenburg, R. J. Aucoin, and R. C. Fleming, “Optically matched trilevel resist process for nanostructure fabrication,” J. Vac. Sci. Technol. B 13(6), 3007–3011 (1995). [CrossRef]
- V. Gruev, Z. Yang, J. Van der Spiegel, and R. Etienne-Cummings, “Current mode image sensor with two transistors per pixel,” IEEE Trans. Circuits Syst. I: Fundam. Theory Appl. 57(6), 1154–1165 (2010). [CrossRef]
- http:\\ www.opalkelly.com .
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