Bichromatic optical switch of diffractive light from a BCT photonic crystal based on an azo component-doped HPDLC

doi:10.1364/OE.20.025545

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Bichromatic optical switch of diffractive light from a BCT photonic crystal based on an azo component-doped HPDLC

Ming Shian Li, Andy Ying-Guey Fuh, Jui-Hsiang Liu, and Shing-Trong Wu »View Author Affiliations

Optics Express, Vol. 20, Issue 23, pp. 25545-25553 (2012)
http://dx.doi.org/10.1364/OE.20.025545

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Abstract

This study demonstrates all optical switches between the four diffractive light levels of a body-centered tetragonal photonic crystal. The sample is based on holographic polymer-dispersed liquid crystals that are fabricated using a two-beam interference with multiple exposures. The switching mechanism bases on the effective index modulation of the PC that contains a liquid crystal/azo-dye mixture could be controlled by two pumping laser beams. The switching time between the blue-laser-pumped and the blue-and-green-laser-pumped levels is fast. The study also discusses the switching time of the various levels.

1. Introduction

The reversible and fast light driven dye-doped liquid crystal (LC) system has attracted considerable attention not only in nonlinear optics but also in all optical switching devices, including the Z-scan [1

H. C. Lin, C. W. Chu, M. S. Li, and A. Y.-G. Fuh, “Biphotonic-induced reorientation inversion in azo-dye-doped liquid crystal films,” Opt. Express 19(14), 13118–13125 (2011), http://www.opticsinfobase.org/oe/abstract.cfm?uri=oe-19-14-13118. [CrossRef] [PubMed]

], photorefractive grating [2

P. Klysubun and G. Indebetouw, “Transient and steady state photorefractive responses in dye-doped nematic liquid crystal cells,” J. Appl. Phys. 91(3), 897–903 (2002), http://jap.aip.org/resource/1/japiau/v91/i3/p897_s1. [CrossRef]

–6

L. De Sio, S. Serak, N. Tabiryan, S. Ferjani, A. Veltri, and C. Umeton, “Composite Holographic gratings containing light-responsive liquid crystals for visible bichromatic switching,” Adv. Mater. (Deerfield Beach Fla.) 22(21), 2316–2319 (2010), http://onlinelibrary.wiley.com/doi/10.1002/adma.200903838/abstract. [CrossRef] [PubMed]

], photoalignments [7

A. Y.-G. Fuh and K. T. Cheng, “Partially erasable photoalignment layer formed in dye-doped liquid crystal films,” Jpn. J. Appl. Phys. 45(11), 8778–8781 (2006), http://jjap.jsap.jp/link?JJAP/45/8778/. [CrossRef]

O. Yaroshchuk and Y. Reznikov, “Photoalignment of liquid crystals: basics and current trends,” J. Mater. Chem. 22(2), 286–300 (2011), http://pubs.rsc.org/en/Content/ArticleLanding/2012/JM/C1JM13485J. [CrossRef]

], and photonic crystals [9

M. Shian Li, A. Y.-G. Fuh, and S. T. Wu, “Optical switch of diffractive light from a BCT photonic crystal based on HPDLC doped with azo component,” Opt. Lett. 36(19), 3864–3866 (2011), http://www.opticsinfobase.org/ol/abstract.cfm?uri=ol-36-19-3864. [CrossRef] [PubMed]

,10

S. Y. Huang, Y. S. Chen, H. C. Jau, M. S. Li, J. H. Liu, P. C. Yang, and A. Y.-G. Fuh, “Biphotonic effect-induced phase transition in dye-doped cholesteric liquid crystals and their applications,” Opt. Commun. 283(9), 1726–1731 (2010), http://www.sciencedirect.com/science/article/pii/S0030401809013558. [CrossRef]

]. Photochromic guest azo dyes control the refractive index of the host LC system by affecting the order parameter, or by isothermally inducing the nematic-isotropic phase transition of the LCs. The absorptions of the photochromic molecules, including the quantum efficiency, absorption cross-section, and the rate constant of the thermal cis-trans back-relaxation (lifetime) of the dye during photoisomerization, govern the characteristics of the switching. Some studies reported that photoisomerization occurs in picosecond timescales at quantum efficiencies below 60% [11

D. Statman and I. Jánossy, “Study of photoisomerization of azo dyes in liquid crystals,” J. Chem. Phys. 118(7), 3222–3232 (2003), http://jcp.aip.org/resource/1/jcpsa6/v118/i7/p3222_s1. [CrossRef]

–14

U. A. Hrozhyk, S. V. Serak, N. V. Tabiryan, L. Hoke, D. M. Steeves, and B. R. Kimball, “Azobenzene liquid crystalline materials for efficient optical switching with pulsed and/or continuous wave laser beams,” Opt. Express 18(8), 8697–8704 (2010), http://www.opticsinfobase.org/oe/abstract.cfm?uri=oe-18-8-8697. [CrossRef] [PubMed]

]. The lifetime of the photoexcited state of molecules that contain azobenzene moieties can be varied from nanoseconds to several hours or even days by changing the donor and acceptor strengths at the molecule ends [13

O. Tsutsumi, A. Kanazawa, T. Shiono, T. Ikeda, and L.-S. Park, “Photoinduced phase transition of nematic liquid crystals with donor-acceptor azobenzenes: mechanism of the thermal recovery of the nematic phase,” Phys. Chem. Chem. Phys. 1(18), 4219–4224 (1999), http://pubs.rsc.org/en/Content/ArticleLanding/1999/CP/a905172d. [CrossRef]

In our previous study [9

], we discussed the optical switch of azo-dye-doped holographic polymer-dispersed liquid crystal (HPDLC) films, which was achieved by controlling the index modulation of the LC and of the polymer matrix. The cis isomer can disrupt the order parameter of LC droplets, which results in the reduction of the LC droplet effective index. In turn, the diffraction beams are switched off. In addition, the concentrations of the trans-cis isomers are in a dynamic equilibrium, which affects by the intensity and wavelength of the pumping laser beams. In this study, two laser beams are used to improve the optical switching of the body-centered tetragonal photonic crystal (BCT PC) based on an azo component-doped HPDLC. The switching time is significantly shortened to less than 1 ms, and gray levels are added in the switching.

2. Sample fabrication

Experimentally in this study, the recording medium for the fabrication of optically switchable PCs is a PDLC film, which consists of an LC (26.2 wt% E7, Merck), polymer (69.3 wt% NOA81, Norland), photoinitiator (1.3 wt% Rose Bengal, Aldrich), and an azo component (3.2 wt% M5C, home-synthesized [15

J. H. Liu, Y. L. Chou, R. Balamurugan, K. H. Tien, W. T. Chuang, and M. Z. Wu, “Optical properties of chiral nematic side-chain copolymers bearing cholesteryl and azobenzene building blocks,” J Polym. Sci., Part A: Polym. Chem., 49, 770–780 (2011), http://onlinelibrary.wiley.com/doi/10.1002/pola.24490/abstract.

]). The function of the photoinitiator is to produce free radicals, and then to initiate polymerization of NOA81 with exposure of the film to green-blue laser. The azo component is first added into the liquid crystal and is then vibrated using an ultrasonic oscillator prior to the addition of other components to ensure solubility. M5C is an azobenzene derivative (a 4-pentyloxy-phenyl-4-methoxyphenyldiazene photochromic molecule) whose azobenzenes can undergo reversible photoisomerization between two molecular forms (trans-cis isomers) upon irradiation. The trans isomer is thermally stable as a ground state and transforms into a cis isomer after excitation by blue light (λ = 350–400 nm; π–π* molecular transition). The photoisomerization of cis isomers to trans isomers occurs by itself or is accelerated under visible-light exposure. The time of transition from the trans isomer to the cis isomer is on the scale of a few nanoseconds, which meets the requirements of fast and efficient all-optical switching applications. The cured polymer has a refractive index of ~1.56, and the liquid crystal has ordinary and extraordinary indices of n_o = 1.5216 and n_e = 1.7462, respectively, at 589 nm, 20 °C. Drops of homogeneously mixed compounds are sandwiched between two indium-tin-oxide-coated glasses that are separated by ~20 μm glass spacers to produce a sample.

Three-dimensional (3D) PCs have a great diversity of applications in communication and transmission field than that of 2D gratings, since the additional symmetry (say at the z-axis) also provides light managements that contribute to better photon manipulation [16

T. Ochiai and J. Sánchez-Dehesa, “Superprism effect in opal-based photonic crystals,” Phys. Rev. B 64(24), 245113 (2001), http://prb.aps.org/abstract/PRB/v64/i24/e245113. [CrossRef]

–18

A. Y.-G. Fuh, M. S. Li, and S. T. Wu, “Transverse wave propagation in photonic crystal based on holographic polymer-dispersed liquid crystal,” Opt. Express 19(14), 13428–13435 (2011), http://www.opticsinfobase.org/oe/abstract.cfm?uri=oe-19-14-13428. [CrossRef] [PubMed]

]. In the study, the 3D BCT PCs are fabricated by exposing the sample to light interference using a two-beam interference with a point-by-point multi-exposure in an off-axis holographic setup [18

]. In a typical fabrication, a transverse electric (TE)-polarized, continuous-wave, diode-pumped, solid-state laser beam (Verdi, λ□ = 532 nm) is expanded and divided into two TE-polarized beams, namely, the reference (~400 mW/cm²) and object beams (~400 mW/cm²), using a beam splitter. These beams simultaneously illuminate the sample. The former is normally incident to the sample, whereas the latter is incident at an angle of ~39° to the normal incident beam. The sample is placed on a rotating stage that revolves around the reference beam. The sample is exposed four times to a two-beam interference and then subjected to rotations of 90° intervals, i.e., exposed at 0°, 90°, 180°, and 270°. The exposure times are 30, 20, 20, and 30 s, respectively. Because the off-axial holographic recording has an oblique incident beam; the grating vector of resulting grating is not parallel to the surface. Hence, the recorded samples present periodic modulations in z-axis that contribute to fabricate 3D PCs in multi-exposures. Notably, if the exposure time reduces to two exposures (with the sample being rotated by only 0° and 90° but ignored 180° and 270°), the top-view intensity profile is similar to that of the four exposures. However, the side-view intensity profile is different (α≠90°, see the definition in Fig. 1(a) ), in which the elliptic bright regions also tilt with respect to the z-axis.

Fig. 1 Simulated intensity profile of interference region, (b) top-view SEM image of HPDLC profile, and (c) far field view of the diffraction image of the BCT sample.

Figure 1(a) gives the 3D simulated intensity profile of the interference region which is constructed using two-beam interference with four exposures. The figure also gives the illustration of a unit BCT cell. As the sample is exposed to the interference pattern, the photoreactive monomers diffuse to the bright regions (red regions in Fig. 1(a)) of the interference pattern, while the liquid crystal molecules consequently congregate in the dark regions (blue regions in Fig. 1(a)) which locate at the lattice point of the PC. By removing the LCs, Fig. 1(b) shows the top-view scanning electron microscope (SEM) image of the sample in which the polymer surface structure contains a matrix (polymer-rich region) as well as voids (LC-rich region). The primitive cell of the BCT structure has the dimension a = b ≠ c. The a and c lattice constants are ~0.813 ± 0.016 μm and ~3.416 ± 0.068 μm, respectively, and the diameter of the voids that contain the LC droplets is ~0.25 μm [18

]. Figure 1(c) presents the far field diffraction image from the sample. The maximum diffraction efficiency of the 1st-order diffractive beams is approximately ~15%.

3. Analysis of the concentration of cis isomer upon irradiation of laser beams

The HPDLC-based BCT sample contains the polymer matrix and voids at the lattice points, which contain the LC/dye mixture. Under pumping light exposure, the guest photoisomers affect the effective index in two ways. First, the cis isomers disrupt the host LC configurations in the voids. As the cis isomer fraction increases after laser light exposure, the effective indices of the LCs simultaneously decrease. Second, the cis isomers reduce the nematic-to-isotropic transition temperature of the LCs [19

C. H. Legge and G. R. Mitchell, “Photo-induced phase transitions in azobenzene-doped liquid crystals,” J. Phys. D Appl. Phys. 25(3), 492–499 (1992), http://iopscience.iop.org/0022-3727/25/3/024. [CrossRef]

,20

Y. Norikane, Y. Hirai, and M. Yoshida, “Photoinduced isothermal phase transitions of liquid-crystalline macrocyclic azobenzenes,” Chem. Commun. (Camb.) 47(6), 1770–1772 (2011), http://pubs.rsc.org/en/Content/ArticleLanding/2011/CC/C0CC04052E. [CrossRef] [PubMed]

]. The phase transition temperature continuously decreases as the cis isomer concentration increases. If the cis isomer concentration is sufficiently high, the LCs exhibit an isotropic phase. The dynamic equilibrium of the as-pumped trans and cis isomers under various exposure conditions are the key to diffraction beam switching. The cis isomer fraction (N_cis) can be expressed as [11

\frac{d N_{c i s}}{d t} = (1 - N_{c i s}) [σ_{B, t - c} φ_{B, t - c} \frac{I_{B}}{h ν} + σ_{G, t - c} φ_{G, t - c} \frac{I_{G}}{h ν^{'}}] - σ_{G, c - t} φ_{G, c - t} \frac{I_{G}}{h ν^{'}} N_{c i s} - \frac{N_{c i s}}{τ},

(1)

where I_B, I_G are the light intensity of the blue and green pumping laser beams, respectively; σ_t-c and σ_c-t are the absorption cross-section of the trans-cis and cis-trans transitions, respectively; φ_t-c and φ_c-t are the quantum efficiencies of the trans-cis and cis-trans transitions, respectively; and τ is the relaxation time to return to the steady state in the absence of light. The first term describes the light-induced trans-cis transition, the second term represents the cis-trans transition, and the third term accounts for the thermal relaxation of the cis component. The relationships of the absorption cross-section are σ_B,trans > σ_G,trans and σ_B,cis << σ_G,cis, as determined from the absorption spectrum of the azo component. Thus, the equation neglects the contribution from the blue laser in the second term.

Hence, in the steady state, the fraction of cis isomers can be simplified as

{(N_{c i s})}_{e q} = 1 - \frac{\frac{I_{G}^{T}}{I_{G}} + X_{T}}{1 + (1 + \frac{I_{B}}{I_{B}^{T}}) \frac{I_{G}^{T}}{I_{G}}},

(2)

where

I_{G}^{T}

I_{B}^{T}

and X_T are the threshold intensity of the green, blue laser beams and the saturation fraction of trans isomers induced by the green laser. These are defined as follows;

\begin{array}{l} I_{G}^{T} = [^{(σ_{G, t - c} φ_{G, t - c} + σ_{G, c - t} φ_{G, c - t}) \frac{τ}{h ν^{'}}] - 1}, \\ I_{B}^{T} = [^{σ_{B, t - c} φ_{B, t - c} \frac{τ}{h ν}] - 1}, \\ X_{T} = \frac{σ_{G, c - t} φ_{G, c - t}}{σ_{G, t - c} φ_{G, t - c} + σ_{G, c - t} φ_{G, c - t}} . \end{array}

(3)

(N_cis)_eq can be numerically simulated from Eq. (2) with the parameters of

I_{G}^{T}

I_{B}^{T}

and X_T under various pumping conditions. The simulation assumes that X_T is a constant which is independent of the concentration of cis fraction upon pumping. The inset of Fig. 2 gives the concentration of cis isomer upon irradiation of a single blue or green laser beam, by applying the

I_{G}^{T}

= 50 mW/cm²,

I_{B}^{T}

= 10 mW/cm², and X_T = 0.7. It is seen that N_cis increases much faster by a blue pumping laser beam than that by a green laser beam. Figure 2 shows the simulated concentration of cis isomers under the excitation by the blue (fixed intensity I_B = 100 mW/cm²) and the green pumping laser beams (intensity ranges from 0 to 800 mW/cm²), simultaneously. As the intensity of the green laser increases, the N_cis decreases. The reason is that the green laser transforms the cis isomers generated by the blue pumping laser to trans isomers. In other words, the fraction of cis isomer generated from the simultaneous exposures of the blue and green lasers is lower compared with that generated by a single blue laser.

Fig. 2 Simulated concentration of cis isomers versus the pumping intensity of a green laser beam with the pumping intensity of the blue laser beam being fixed at 100 mW/cm². The inset shows the concentration of cis isomer upon irradiation of single blue or green laser beams, respectively.

4. Experimental setup in optical switching

Figure 3 shows the experimental setup used to measure the optical switch properties of the BCT PC. A TE-polarized Ar + laser (green, λ = 514.5 nm, intensity = 400 mW/cm²) beam and a diode laser (blue, λ = 403 nm, intensity = 100 mW/cm²) illuminate the sample at 30°, whereas a He-Ne laser is used to probe the BCT sample. In the experiment, shutters are used to control the exposure time of the green and blue laser beams. An aperture and a color filter were placed behind detector 2 to prevent laser light reflection. The pumping conditions of non-exposure and exposure to green, blue and green, and blue laser beams are simplified into OFF, ON_G, ON_{B + G}, and ON_B, respectively, for convenience.

Fig. 3 Experimental setup used to measure the optical switch properties of a HPDLC-based PC. D: detector; S: shutter; A: aperture; CF: color filter; BS: beam splitter.

5. Experimental results and discussions

Figure 4 shows the diffraction beam intensity when the samples are pumped using a blue and/or a green beam. The exposure time is set at 40 s. Curves 1 to 3 in Fig. 4 represent the diffraction intensities of the He-Ne laser beam from the BCT PC, which is subjected to the OFF-ON_G-ON_B-OFF, OFF-ON_B-ON_G-OFF, and OFF-ON_B-ON_{B + G}-OFF laser pumping process. As mentioned above, the intensity of the diffraction beam depends on the cis isomer concentration shown in Eq. (2). The intensity weakens when the cis isomer concentration increases upon exposure to either green or blue laser beams. However, the wavelength of the pumping blue laser is close to the absorption band that generates a higher cis isomer concentration than that of the green laser. The high cis isomer concentration induces the transition of the LCs in the voids into an isotropic state. The diffraction intensity is relatively low compared with that pumped by the green laser. As the first pumping green laser is replaced by the blue laser, the diffraction intensity rapidly drops (curve 1). Similarly, the intensity increases as the pumping laser beam sequence is inverted (curve 2). The diffraction intensity rapidly decreases and increases when the blue pumping laser beam is replaced by the green one. However, a comparison of the OFF-ON_G and ON_B-ON_G paths shows that the ON_G levels are different, with the ON_G level of the latter requiring a few seconds to recover to the former. This phenomenon becomes apparent when the exposure time to the blue laser exceeds several minutes. Thus, the thermal effect may be affecting the order parameter of the LCs. The newly created level is constant until the heat dissipates or even when no external disturbance exists. When the green laser beam is added to the pumping blue laser, the diffraction light intensity increases (curve 3). This result is expected because the green laser not only increases the trans isomer concentration but also promotes the organization of the host LCs by the newly transformed trans isomers. In other words, the trans isomer produced under the green laser beam reconverts the LC structure to the initial configuration. This change is temporary and disappears as soon as the green pumping laser is off.

Fig. 4 Intensities of the diffraction beam when the samples were pumped by various laser beam combinations. The pumping conditions of non-exposure and exposure to green, blue and green, and blue laser beams are simplified into OFF, ON_G, ON_{B + G}, and ON_B for convenience.

Figure 5 shows the curves of the AC voltage applied to the shutter, the green laser light, and the diffraction light versus time. The switching times of the transition from ON_{B + G} to ON_B and back are calculated on the basis of the curves. The used shutter is a ferroelectric shutter (FLC) shutter (Newport, M50075) that is driven by a 50 Hz AC voltage in order to fast switch the green laser beam. The FLC shutter is ON (OFF) when the AC voltage is 5 V (−5 V). The plots of the green laser intensities from detector 3 are shown in Fig. 5 for reference. In the process, the sample pumps by a sequential ON/OFF period of the green laser, with the blue laser always ON. Hence, the cis isomer concentration is sufficiently high initially. The transition times of the trans-to-cis and cis-to-trans isomers are on the nanosecond scale. The trans isomer concentration generated by the pumping green laser beam immediately affects the order parameter of LCs. The ON_B-ON_{B + G} switching times are estimated at ~600 μs, whereas those of ON_{B + G}-ON_B are estimated as ~800 μs. Thus, ON_B-ON_{B + G} is slightly slower than ON_{B + G}-ON_B. When the green laser beam is switched off, the time of isomer transformation from trans to cis may be on the same order as that from cis to trans when the green laser beam is opened. However, LC reconstruction in the system is faster than LC disruption because the LC phase transition from isotropic to nematic is generally faster than that from nematic to isotropic.

Fig. 5 Intensities of the diffraction beam as the samples transition between ON_{B + G} and ON_B.

For convenience, the intensities of the diffraction beams in these curves can be classified into four levels, namely, level 4 (OFF), level 3 (ON_G), level 2 (ON_{B + G}), and level 1 (ON_B), according to the exposure conditions. Figure 6 shows the level upsteps and downsteps by combinations of exposures to the two lasers. One of the curves represents a level up that corresponds to the raising of level 1 to level 4 under ON_B-ON_{B + G}-ON_G-OFF exposure. The other curve represents a level down that corresponds to the decrease from level 4 to 1 under OFF-ON_G-ON_{B + G}-ON_B exposure. The contrast of levels 4, 3, and 2 are 7.5, 5–6, and 2, respectively, as compared to that of level 1. As seen from the curves, the ON_G level is sensitive to the thermal effect during laser optical pumping. Hence, the immediate contrast of the ON_G level depends on the path used to reach this level.

Fig. 6 Upstep and downstep of the levels. One of the curves represents a level up that corresponds to the increase from level 1 to level 4, whereas the other represents a level down that corresponds to the decrease from level 4 to level 1.

Table 1 gives the summarized switching time between the four levels. The switching times of the levels are affected by the guest dye, the governing factors (i.e., quantum efficiency, absorption cross-section, and rate constant of the thermal cis-trans back-relaxation), and the thermal effect. The thermal dissipation and phase transition of LCs apparently inhibit the switching. Thus, the LCs in the ON_B-OFF process has a delayed relaxation time during phase transition (curve 1 of Fig. 6). The thermal effect slows down the ON_{B + G}-ON_G switching (curve 2 of Fig. 6). Therefore, the ON_B-OFF and ON_{B + G}-ON_G level transitions that are affected are generally avoided in applications because of their relatively slow switching time. Given the long distance of the trans isomer absorption band from the green laser wavelength, trans isomer production is not efficient. Thus, the overall LC distribution is difficult to change, which results in a relatively slow OFF-ON_G switching time. Therefore, the switching times for OFF-ON_G, ON_B- OFF, and ON_{B + G}-ON_G are on the order of tens of seconds. The ON_B-OFF switching time can be improved by exposure to the green laser because ON_B-ON_G transition is faster than that of ON_B-OFF. Here, a small amount of trans isomers produced under green laser exposure significantly promotes the recovery of the LC order. In addition, the switching from level 1 (ON_B) to level 4 (OFF) in applications can be significantly improved by a short-pulse exposure to green laser. The level recovery from ON_{B + G} to ON_G is relatively slow because the ON_{B + G} level contains some trans isomers. The newly produced trans isomers also do not exert a strong effect. The back processes to levels ON_G and OFF are long because LC relaxation from a disordered state to the normal state is required.

Table 1 Switching times between the OFF, ON_G, ON_B, and ON_{B + G} levels.

Final	Level 1 (ON_B)	Level 2 (ON_{B + G})	Level 3 (ON_G)	Level4 (OFF)
Initial	Level 1 (ON_B)	Level 2 (ON_{B + G})	Level 3 (ON_G)	Level4 (OFF)
Level 1 (ON_B)	X	<600μs	~14s	~29s
Level 2 (ON_{B + G})	<800μs	X	>40s	34s
Level 3 (ON_G)	200ms	60ms	X	27s
Level 4 (OFF)	120ms	150ms	>40s	X

6. Conclusion

In conclusion, a four-level optical switching is established using two laser beams that are based on an azo dye-doped HPDLC film. The switching time between the ON_B and ON_{B + G} levels is short. Since the electrical switching of nano-sized HPDLCs requires a sufficiently high voltage (~10 V/μm), and is difficult to switch off completely, the optical switching provides us a better switching in these respects. Furthermore, the pumping laser wavelength and intensities can be optimized to increase the contrast ratio of ON_B to ON_{B + G}. The CR of the ON_{B + G}-ON_G level can be increased by increasing the green laser intensity. The optical switching of PCs based on HPDLC has high potential in electro-optical applications.

Acknowledgments

The authors would like to thank the National Science Council of Taiwan for financially supporting this research under Grant No. NSC 98-2112-M-006-001-MY3 and NSC 101-2112-M-006-011-MY3. Additionally, this work is partially supported by Advanced Optoelectronic Technology Center as well.

References and links

1.	H. C. Lin, C. W. Chu, M. S. Li, and A. Y.-G. Fuh, “Biphotonic-induced reorientation inversion in azo-dye-doped liquid crystal films,” Opt. Express 19(14), 13118–13125 (2011), http://www.opticsinfobase.org/oe/abstract.cfm?uri=oe-19-14-13118. [CrossRef] [PubMed]
2.	P. Klysubun and G. Indebetouw, “Transient and steady state photorefractive responses in dye-doped nematic liquid crystal cells,” J. Appl. Phys. 91(3), 897–903 (2002), http://jap.aip.org/resource/1/japiau/v91/i3/p897_s1. [CrossRef]
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6.	L. De Sio, S. Serak, N. Tabiryan, S. Ferjani, A. Veltri, and C. Umeton, “Composite Holographic gratings containing light-responsive liquid crystals for visible bichromatic switching,” Adv. Mater. (Deerfield Beach Fla.) 22(21), 2316–2319 (2010), http://onlinelibrary.wiley.com/doi/10.1002/adma.200903838/abstract. [CrossRef] [PubMed]
7.	A. Y.-G. Fuh and K. T. Cheng, “Partially erasable photoalignment layer formed in dye-doped liquid crystal films,” Jpn. J. Appl. Phys. 45(11), 8778–8781 (2006), http://jjap.jsap.jp/link?JJAP/45/8778/. [CrossRef]
8.	O. Yaroshchuk and Y. Reznikov, “Photoalignment of liquid crystals: basics and current trends,” J. Mater. Chem. 22(2), 286–300 (2011), http://pubs.rsc.org/en/Content/ArticleLanding/2012/JM/C1JM13485J. [CrossRef]
9.	M. Shian Li, A. Y.-G. Fuh, and S. T. Wu, “Optical switch of diffractive light from a BCT photonic crystal based on HPDLC doped with azo component,” Opt. Lett. 36(19), 3864–3866 (2011), http://www.opticsinfobase.org/ol/abstract.cfm?uri=ol-36-19-3864. [CrossRef] [PubMed]
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11.	D. Statman and I. Jánossy, “Study of photoisomerization of azo dyes in liquid crystals,” J. Chem. Phys. 118(7), 3222–3232 (2003), http://jcp.aip.org/resource/1/jcpsa6/v118/i7/p3222_s1. [CrossRef]
12.	C. M. Stuart, R. R. Frontiera, and R. A. Mathies, “Excited-state structure and dynamics of cis- and trans-azobenzene from resonance raman intensity analysis,” J. Phys. Chem. A 111(48), 12072–12080 (2007), http://pubs.acs.org/doi/abs/10.1021/jp0751460. [CrossRef] [PubMed]
13.	O. Tsutsumi, A. Kanazawa, T. Shiono, T. Ikeda, and L.-S. Park, “Photoinduced phase transition of nematic liquid crystals with donor-acceptor azobenzenes: mechanism of the thermal recovery of the nematic phase,” Phys. Chem. Chem. Phys. 1(18), 4219–4224 (1999), http://pubs.rsc.org/en/Content/ArticleLanding/1999/CP/a905172d. [CrossRef]
14.	U. A. Hrozhyk, S. V. Serak, N. V. Tabiryan, L. Hoke, D. M. Steeves, and B. R. Kimball, “Azobenzene liquid crystalline materials for efficient optical switching with pulsed and/or continuous wave laser beams,” Opt. Express 18(8), 8697–8704 (2010), http://www.opticsinfobase.org/oe/abstract.cfm?uri=oe-18-8-8697. [CrossRef] [PubMed]
15.	J. H. Liu, Y. L. Chou, R. Balamurugan, K. H. Tien, W. T. Chuang, and M. Z. Wu, “Optical properties of chiral nematic side-chain copolymers bearing cholesteryl and azobenzene building blocks,” J Polym. Sci., Part A: Polym. Chem., 49, 770–780 (2011), http://onlinelibrary.wiley.com/doi/10.1002/pola.24490/abstract.
16.	T. Ochiai and J. Sánchez-Dehesa, “Superprism effect in opal-based photonic crystals,” Phys. Rev. B 64(24), 245113 (2001), http://prb.aps.org/abstract/PRB/v64/i24/e245113. [CrossRef]
17.	R. B. Wehrspohn and J. Üpping, “3D photonic crystals for photon management in solar cells,” J. Opt. 14(2), 024003 (2012), http://iopscience.iop.org/2040-8986/14/2/024003. [CrossRef]
18.	A. Y.-G. Fuh, M. S. Li, and S. T. Wu, “Transverse wave propagation in photonic crystal based on holographic polymer-dispersed liquid crystal,” Opt. Express 19(14), 13428–13435 (2011), http://www.opticsinfobase.org/oe/abstract.cfm?uri=oe-19-14-13428. [CrossRef] [PubMed]
19.	C. H. Legge and G. R. Mitchell, “Photo-induced phase transitions in azobenzene-doped liquid crystals,” J. Phys. D Appl. Phys. 25(3), 492–499 (1992), http://iopscience.iop.org/0022-3727/25/3/024. [CrossRef]
20.	Y. Norikane, Y. Hirai, and M. Yoshida, “Photoinduced isothermal phase transitions of liquid-crystalline macrocyclic azobenzenes,” Chem. Commun. (Camb.) 47(6), 1770–1772 (2011), http://pubs.rsc.org/en/Content/ArticleLanding/2011/CC/C0CC04052E. [CrossRef] [PubMed]

OCIS Codes
(160.3710) Materials : Liquid crystals
(160.5470) Materials : Polymers
(050.5298) Diffraction and gratings : Photonic crystals

ToC Category:
Optical Devices

History
Original Manuscript: September 5, 2012
Revised Manuscript: October 11, 2012
Manuscript Accepted: October 19, 2012
Published: October 25, 2012

Citation
Ming Shian Li, Andy Ying-Guey Fuh, Jui-Hsiang Liu, and Shing-Trong Wu, "Bichromatic optical switch of diffractive light from a BCT photonic crystal based on an azo component-doped HPDLC," Opt. Express 20, 25545-25553 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-23-25545

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References

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A. Y.-G. Fuh and K. T. Cheng, “Partially erasable photoalignment layer formed in dye-doped liquid crystal films,” Jpn. J. Appl. Phys.45(11), 8778–8781 (2006), http://jjap.jsap.jp/link?JJAP/45/8778/ . [CrossRef]
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M. Shian Li, A. Y.-G. Fuh, and S. T. Wu, “Optical switch of diffractive light from a BCT photonic crystal based on HPDLC doped with azo component,” Opt. Lett.36(19), 3864–3866 (2011), http://www.opticsinfobase.org/ol/abstract.cfm?uri=ol-36-19-3864 . [CrossRef] [PubMed]
S. Y. Huang, Y. S. Chen, H. C. Jau, M. S. Li, J. H. Liu, P. C. Yang, and A. Y.-G. Fuh, “Biphotonic effect-induced phase transition in dye-doped cholesteric liquid crystals and their applications,” Opt. Commun.283(9), 1726–1731 (2010), http://www.sciencedirect.com/science/article/pii/S0030401809013558 . [CrossRef]
D. Statman and I. Jánossy, “Study of photoisomerization of azo dyes in liquid crystals,” J. Chem. Phys.118(7), 3222–3232 (2003), http://jcp.aip.org/resource/1/jcpsa6/v118/i7/p3222_s1 . [CrossRef]
C. M. Stuart, R. R. Frontiera, and R. A. Mathies, “Excited-state structure and dynamics of cis- and trans-azobenzene from resonance raman intensity analysis,” J. Phys. Chem. A111(48), 12072–12080 (2007), http://pubs.acs.org/doi/abs/10.1021/jp0751460 . [CrossRef] [PubMed]
O. Tsutsumi, A. Kanazawa, T. Shiono, T. Ikeda, and L.-S. Park, “Photoinduced phase transition of nematic liquid crystals with donor-acceptor azobenzenes: mechanism of the thermal recovery of the nematic phase,” Phys. Chem. Chem. Phys.1(18), 4219–4224 (1999), http://pubs.rsc.org/en/Content/ArticleLanding/1999/CP/a905172d . [CrossRef]
U. A. Hrozhyk, S. V. Serak, N. V. Tabiryan, L. Hoke, D. M. Steeves, and B. R. Kimball, “Azobenzene liquid crystalline materials for efficient optical switching with pulsed and/or continuous wave laser beams,” Opt. Express18(8), 8697–8704 (2010), http://www.opticsinfobase.org/oe/abstract.cfm?uri=oe-18-8-8697 . [CrossRef] [PubMed]
J. H. Liu, Y. L. Chou, R. Balamurugan, K. H. Tien, W. T. Chuang, and M. Z. Wu, “Optical properties of chiral nematic side-chain copolymers bearing cholesteryl and azobenzene building blocks,” J Polym. Sci., Part A: Polym. Chem., 49, 770–780 (2011), http://onlinelibrary.wiley.com/doi/10.1002/pola.24490/abstract .
T. Ochiai and J. Sánchez-Dehesa, “Superprism effect in opal-based photonic crystals,” Phys. Rev. B64(24), 245113 (2001), http://prb.aps.org/abstract/PRB/v64/i24/e245113 . [CrossRef]
R. B. Wehrspohn and J. Üpping, “3D photonic crystals for photon management in solar cells,” J. Opt.14(2), 024003 (2012), http://iopscience.iop.org/2040-8986/14/2/024003 . [CrossRef]
A. Y.-G. Fuh, M. S. Li, and S. T. Wu, “Transverse wave propagation in photonic crystal based on holographic polymer-dispersed liquid crystal,” Opt. Express19(14), 13428–13435 (2011), http://www.opticsinfobase.org/oe/abstract.cfm?uri=oe-19-14-13428 . [CrossRef] [PubMed]
C. H. Legge and G. R. Mitchell, “Photo-induced phase transitions in azobenzene-doped liquid crystals,” J. Phys. D Appl. Phys.25(3), 492–499 (1992), http://iopscience.iop.org/0022-3727/25/3/024 . [CrossRef]
Y. Norikane, Y. Hirai, and M. Yoshida, “Photoinduced isothermal phase transitions of liquid-crystalline macrocyclic azobenzenes,” Chem. Commun. (Camb.)47(6), 1770–1772 (2011), http://pubs.rsc.org/en/Content/ArticleLanding/2011/CC/C0CC04052E . [CrossRef] [PubMed]

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