Near-infrared luminescence of RbPb<sub>2</sub>Cl<sub>5</sub>:Bi crystals

Andrey G. Okhrimchuk; Leonid N. Butvina; Evgueni M. Dianov; Ninel V. Lichkova; Vladimir N. Zagorodnev; Kirill N. Boldyrev

doi:10.1364/OL.33.002182

Optics Letters
Vol. 33,
Issue 19,
pp. 2182-2184
(2008)
•https://doi.org/10.1364/OL.33.002182

Near-infrared luminescence of $Rb {Pb}_{2} {Cl}_{5} : Bi$ crystals

Andrey G. Okhrimchuk, Leonid N. Butvina, Evgueni M. Dianov, Ninel V. Lichkova, Vladimir N. Zagorodnev, and Kirill N. Boldyrev

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Andrey G. Okhrimchuk, Leonid N. Butvina, Evgueni M. Dianov, Ninel V. Lichkova, Vladimir N. Zagorodnev, and Kirill N. Boldyrev, "Near-infrared luminescence of RbPb₂Cl₅:Bi crystals," Opt. Lett. 33, 2182-2184 (2008)

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Abstract

A wideband near-IR (NIR) luminescence centered at $1080 nm$ was found in a $Rb {Pb}_{2} {Cl}_{5} : Bi$ single crystal grown by the Bridgman technique. Absorption, luminescence, and excitation of luminescence spectra were investigated at room and cryogenic temperatures. The luminescence was proposed to be due to the ${}^{3}P_{1} \to {}^{3}P_{0}$ transition in ${Bi}^{+}$ ion.

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${Bi}^{+}$			${Pb}^{+}$
Configuration	Multiplet	Energy $({cm}^{- 1})$	Configuration	Multiplet	Energy $({cm}^{- 1})$
$6 s^{2} 6 p^{2}$	${}^{3}P_{0}$	0	$6 s^{2} 6 p$	${}^{2}P^{0}_{1 ∕ 2}$	0
	${}^{3}P_{1}$	13325.401		${}^{2}P^{0}_{3 ∕ 2}$	14081.074
	${}^{3}P_{2}$	17031.698	$6 s 6 p^{2}$	${}^{4}P_{1 ∕ 2}$	57910.48
	${}^{1}D_{2}$	33938.718		${}^{4}P_{3 ∕ 2}$	66124.53
	${}^{1}S_{0}$	44173.768		${}^{4}P_{5 ∕ 2}$	73905.708
$6 s^{2} 6 p 7 s$	${}^{3}P^{0}_{0}$	69133.891
	${}^{3}P^{0}_{1}$	69598.475

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