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Optics Letters

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  • Editor: Alan E. Willner
  • Vol. 38, Iss. 24 — Dec. 15, 2013
  • pp: 5224–5227

Enhanced photoluminescence emission from anthracene-doped polyphenylsiloxane glass

Megumi Kimura, Naoki Tarutani, Masahide Takahashi, Sanjay Karna, Arup Neogi, and Ryoko Shimada  »View Author Affiliations


Optics Letters, Vol. 38, Issue 24, pp. 5224-5227 (2013)
http://dx.doi.org/10.1364/OL.38.005224


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Abstract

Anthracene-doped polyphenylsiloxane (PPS) glass containing silver nanoparticles (AgNPs) of appropriate size was synthesized in a form of solid thin films for modifying light emission characteristics. The photoluminescence (PL) emission from the anthracene molecules at 2.95eV was resonantly coupled to the localized surface plasmon (LSP) polariton modes that were induced by the excitation of 30nm sized AgNPs. The increase in absorption of incident photons within a highly scattering medium, energy transfer from the localized excitons to the LSP modes, and the electrostatic Coulomb effects of the excitons in the presence of metal NPs all resulted in a significant enhancement of PL emission. The PL enhancement is dependent on the concentration of the anthracene molecules. The integrated PL intensity enhancement at the optimum concentration of anthracene molecules in the PPS glass with AgNPs is found to exceed 50.

© 2013 Optical Society of America

OCIS Codes
(160.2540) Materials : Fluorescent and luminescent materials
(240.6680) Optics at surfaces : Surface plasmons
(250.5230) Optoelectronics : Photoluminescence

ToC Category:
Optoelectronics

History
Original Manuscript: August 7, 2013
Revised Manuscript: October 21, 2013
Manuscript Accepted: October 23, 2013
Published: December 3, 2013

Citation
Megumi Kimura, Naoki Tarutani, Masahide Takahashi, Sanjay Karna, Arup Neogi, and Ryoko Shimada, "Enhanced photoluminescence emission from anthracene-doped polyphenylsiloxane glass," Opt. Lett. 38, 5224-5227 (2013)
http://www.opticsinfobase.org/ol/abstract.cfm?URI=ol-38-24-5224


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