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  • Vol. 14, Iss. 10 — May. 15, 1989
  • pp: 488–490

Observation of the Stark effect in high-overtone band transitions of NH3

Ken’ichi Nakagawa, Yoshiki Moriwaki, and Tadao Shimizu  »View Author Affiliations


Optics Letters, Vol. 14, Issue 10, pp. 488-490 (1989)
http://dx.doi.org/10.1364/OL.14.000488


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Abstract

A sensitive dye-laser spectrometer is constructed to observe the Stark effect of weak-overtone transitions in NH3. A ΔP/P sensitivity of 10−6 is achieved with the help of a laser-noise-reduction system. A relatively short (30-cm) and narrow-gap (0.25-mm) Stark electrode makes it possible to apply a high electric field on molecular gas at low pressure (~1 Torr). The Stark components of the v = 5 overtone band transitions of The rotational assignments are confirmed, and the dipole moment in the v = 5 excited vibrational state is determined to be 1.40 ± 0.02 D.

© 1989 Optical Society of America

History
Original Manuscript: November 14, 1988
Manuscript Accepted: February 17, 1989
Published: May 15, 1989

Citation
Ken’ichi Nakagawa, Yoshiki Moriwaki, and Tadao Shimizu, "Observation of the Stark effect in high-overtone band transitions of NH3," Opt. Lett. 14, 488-490 (1989)
http://www.opticsinfobase.org/ol/abstract.cfm?URI=ol-14-10-488


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