We present what we believe to be the first implementation of nonequilibrium two-dimensional IR spectroscopy (2DIR) combining electronic excitation within the Fourier transform (FT) approach. Nonequilibrium 2DIR spectra of ${\mathrm{Mn}}_2{\left(\mathrm{C}\mathrm{O}\right)}_{10}$ and its photoproducts are obtained in two modalities: photoexcitation at $400\mathrm{nm}$ , either before a 2DIR probe or during the waiting time of the FT 2DIR measurement. Extending FT 2DIR to nonequilibrium systems offers insight into complex condensed-phase reaction dynamics.

© 2008 Optical Society of America

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