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Influence of thermal treatment on the near-infrared broadband luminescence of Bi:CsI crystalsXiao Fan, Liangbi Su, Guohao Ren, Xiantao Jiang, Haibo Xing, Jun Xu, Huili Tang, Hongjun Li, Lihe Zheng, Xiaobo Qian, and He Feng »View Author Affiliations
Xiao Fan,1
Liangbi Su,1,*
Guohao Ren,1
Xiantao Jiang,1
Haibo Xing,1
Jun Xu,1,2
Huili Tang,1,3
Hongjun Li,1
Lihe Zheng,1
Xiaobo Qian,1
and He Feng1
1Key Laboratory of Transparent and Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, China 2xujun@mail.shcnc.ac.cn 3custang@163.com *Corresponding author: su_lb@163.com |
Optical Materials Express, Vol. 3, Issue 3, pp. 400-406 (2013)
http://dx.doi.org/10.1364/OME.3.000400
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Abstract
Near-infrared (NIR) emitting active centers can exist abundant in Bi:CsI crystal. In addition, Bi:CsI have the simplest crystal structure, body-centered cubic (BCC). In this paper, annealing and quenching treatments were carried out in detail to identify the nature of NIR emitting active centers in Bi:CsI crystals. The changes of absorption and emission spectra with increasing the thermal treatment temperature indicated that the two NIR emission bands at 1210 nm and 1580 nm were related to Bi+ and Bi2+, respectively. Besides, the assignments of absorption bands and the thermal behaviors of Bi3+, Bi2+, Bi+ and Bi2+ were discussed as well.
© 2013 OSA
OCIS Codes
(160.3380) Materials : Laser materials
(300.6280) Spectroscopy : Spectroscopy, fluorescence and luminescence
ToC Category:
Laser Materials
History
Original Manuscript: December 10, 2012
Revised Manuscript: February 2, 2013
Manuscript Accepted: February 8, 2013
Published: February 11, 2013
Citation
Xiao Fan, Liangbi Su, Guohao Ren, Xiantao Jiang, Haibo Xing, Jun Xu, Huili Tang, Hongjun Li, Lihe Zheng, Xiaobo Qian, and He Feng, "Influence of thermal treatment on the near-infrared broadband luminescence of Bi:CsI crystals," Opt. Mater. Express 3, 400-406 (2013)
http://www.opticsinfobase.org/ome/abstract.cfm?URI=ome-3-3-400
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References
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- A. Cremades, J. Piqueras, A. Remon, J. A. Garcia, M. T. Santos, and E. Diéguez, “Luminescence study of thermal treated and laser irradiated Bi12GeO20 and Bi12SiO20 crystals,” J. Appl. Phys.83(12), 7948–7952 (1998). [CrossRef]
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- A. Romanov, V. Haula, Z. Fattakhova, A. A. Veber, V. B. Tsvetkov, D. M. Zhigunov, V. N. Korchak, and V. B. Sulimov, “Near-IR luminescence from subvalent bismuth species in fluoride glass,” Opt. Mater.34(1), 155–158 (2011). [CrossRef]
- A. N. Romanov, Z. T. Fattakhova, A. A. Veber, O. V. Usovich, E. V. Haula, V. N. Korchak, V. B. Tsvetkov, L. A. Trusov, P. E. Kazin, and V. B. Sulimov, “On the origin of near-IR luminescence in Bi-doped materials (II). Subvalent monocation Bi+ and cluster Bi53+ luminescence in AlCl3/ZnCl2/BiCl3 chloride glass,” Opt. Express20(7), 7212–7220 (2012). [CrossRef] [PubMed]
- H. Sun, Y. Sakka, H. Gao, Y. Miwa, M. Fujii, N. Shirahata, Z. Bai, and J. Li, “Ultrabroad near-infrared photoluminescence from Bi5(AlCl4)3 crystal,” J. Mater. Chem.21(12), 4060–4063 (2011). [CrossRef]
- H. T. Sun, Y. Sakka, M. Fujii, N. Shirahata, and H. Gao, “Ultrabroad near-infrared photoluminescence from ionic liquids containing subvalent bismuth,” Opt. Lett.36(2), 100–102 (2011). [CrossRef] [PubMed]
- H. Sun, Y. Sakka, Y. Miwa, N. Shirahata, M. Fujii, and H. Gao, “Spectroscopic characterization of bismuth embedded Y zeolites,” Appl. Phys. Lett.97(13), 131908 (2010). [CrossRef]
- Y. Fujimoto and M. Nakatsuka, “Infrared luminescence from bismuth-doped silica glass,” J. Appl. Phys.40(Part 2, No. 3B), L279–L281 (2001).
- H. T. Sun, Y. Matsushita, Y. Sakka, N. Shirahata, M. Tanaka, Y. Katsuya, H. Gao, and K. Kobayashi, “Synchrotron X-ray, photoluminescence, and quantum chemistry studies of bismuth-embedded dehydrated zeolite Y,” J. Am. Chem. Soc.134(6), 2918–2921 (2012). [CrossRef] [PubMed]
- H. T. Sun, Y. Sakka, M. Fujii, N. Shirahata, and H. Gao, “Ultrabroad near-infrared photoluminescence from ionic liquids containing subvalent bismuth,” Opt. Lett.36(2), 100–102 (2011). [CrossRef] [PubMed]
- H. Sun, Y. Sakka, H. Gao, Y. Miwa, M. Fujii, N. Shirahata, Z. Bai, and J. Li, “Ultrabroad near-infrared photoluminescence from Bi5(AlCl4)3 crystal,” J. Mater. Chem.21(12), 4060–4063 (2011). [CrossRef]
- H. Sun, Y. Sakka, Y. Miwa, N. Shirahata, M. Fujii, and H. Gao, “Spectroscopic characterization of bismuth embedded Y zeolites,” Appl. Phys. Lett.97(13), 131908 (2010). [CrossRef]
- A. Cremades, J. Piqueras, A. Remon, J. A. Garcia, M. T. Santos, and E. Diéguez, “Luminescence study of thermal treated and laser irradiated Bi12GeO20 and Bi12SiO20 crystals,” J. Appl. Phys.83(12), 7948–7952 (1998). [CrossRef]
- A. N. Romanov, Z. T. Fattakhova, A. A. Veber, O. V. Usovich, E. V. Haula, V. N. Korchak, V. B. Tsvetkov, L. A. Trusov, P. E. Kazin, and V. B. Sulimov, “On the origin of near-IR luminescence in Bi-doped materials (II). Subvalent monocation Bi+ and cluster Bi53+ luminescence in AlCl3/ZnCl2/BiCl3 chloride glass,” Opt. Express20(7), 7212–7220 (2012). [CrossRef] [PubMed]
- A. Romanov, V. Haula, Z. Fattakhova, A. A. Veber, V. B. Tsvetkov, D. M. Zhigunov, V. N. Korchak, and V. B. Sulimov, “Near-IR luminescence from subvalent bismuth species in fluoride glass,” Opt. Mater.34(1), 155–158 (2011). [CrossRef]
- M. Qian, C. Yu, J. Cheng, K. Li, and L. Hu, “The broadband NIR emission properties of Bi doped La2O3-Al2O3-SiO2 glass,” J. Lumin.132(10), 2634–2638 (2012). [CrossRef]
- L. Su, H. Zhao, H. Li, L. Zheng, X. Fan, X. Jiang, H. Tang, G. Ren, J. Xu, W. Ryba-Romanowski, R. Lisiecki, and P. Solarz, “Near-infrared photoluminescence spectra in Bi-doped CsI crystal: evidence for Bi-valence conversions and Bi ion aggregation,” Opt. Mater. Express2(6), 757–764 (2012). [CrossRef]
- M. Peng, D. Chen, J. Qiu, X. Jiang, and C. Zhu, “Bismuth-doped zinc aluminosilicate glasses and glass-ceramics with ultra-broadband infrared luminescence,” Opt. Mater.29(5), 556–561 (2007). [CrossRef]
- H. T. Sun, Y. Matsushita, Y. Sakka, N. Shirahata, M. Tanaka, Y. Katsuya, H. Gao, and K. Kobayashi, “Synchrotron X-ray, photoluminescence, and quantum chemistry studies of bismuth-embedded dehydrated zeolite Y,” J. Am. Chem. Soc.134(6), 2918–2921 (2012). [CrossRef] [PubMed]
- A. N. Romanov, Z. T. Fattakhova, A. A. Veber, O. V. Usovich, E. V. Haula, V. N. Korchak, V. B. Tsvetkov, L. A. Trusov, P. E. Kazin, and V. B. Sulimov, “On the origin of near-IR luminescence in Bi-doped materials (II). Subvalent monocation Bi+ and cluster Bi53+ luminescence in AlCl3/ZnCl2/BiCl3 chloride glass,” Opt. Express20(7), 7212–7220 (2012). [CrossRef] [PubMed]
- U. Keller, “Recent developments in compact ultrafast lasers,” Nature424(6950), 831–838 (2003). [CrossRef] [PubMed]
- H. T. Sun, Y. Matsushita, Y. Sakka, N. Shirahata, M. Tanaka, Y. Katsuya, H. Gao, and K. Kobayashi, “Synchrotron X-ray, photoluminescence, and quantum chemistry studies of bismuth-embedded dehydrated zeolite Y,” J. Am. Chem. Soc.134(6), 2918–2921 (2012). [CrossRef] [PubMed]
- A. Romanov, Z. Fattakhova, D. Zhigunov, V. Korchak, and Z. Sulimov, “On the origin of near-IR luminescence in Bi-doped materials (I). Generation of low-valence bismuth species by Bi3+ and Bi0 synproportionation,” Opt. Mater.33(4), 631–634 (2011). [CrossRef]
- A. N. Romanov, Z. T. Fattakhova, A. A. Veber, O. V. Usovich, E. V. Haula, V. N. Korchak, V. B. Tsvetkov, L. A. Trusov, P. E. Kazin, and V. B. Sulimov, “On the origin of near-IR luminescence in Bi-doped materials (II). Subvalent monocation Bi+ and cluster Bi53+ luminescence in AlCl3/ZnCl2/BiCl3 chloride glass,” Opt. Express20(7), 7212–7220 (2012). [CrossRef] [PubMed]
- A. Romanov, V. Haula, Z. Fattakhova, A. A. Veber, V. B. Tsvetkov, D. M. Zhigunov, V. N. Korchak, and V. B. Sulimov, “Near-IR luminescence from subvalent bismuth species in fluoride glass,” Opt. Mater.34(1), 155–158 (2011). [CrossRef]
- L. Su, H. Zhao, H. Li, L. Zheng, X. Fan, X. Jiang, H. Tang, G. Ren, J. Xu, W. Ryba-Romanowski, R. Lisiecki, and P. Solarz, “Near-infrared photoluminescence spectra in Bi-doped CsI crystal: evidence for Bi-valence conversions and Bi ion aggregation,” Opt. Mater. Express2(6), 757–764 (2012). [CrossRef]
- L. Su, H. Zhao, H. Li, L. Zheng, G. Ren, J. Xu, W. Ryba-Romanowski, R. Lisiecki, and P. Solarz, “Near-infrared ultrabroadband luminescence spectra properties of subvalent bismuth in CsI halide crystals,” Opt. Lett.36(23), 4551–4553 (2011). [CrossRef] [PubMed]
- L. Su, P. Zhou, J. Yu, H. Li, L. Zheng, F. Wu, Y. Yang, Q. Yang, and J. Xu, “Spectroscopic properties and near-infrared broadband luminescence of Bi-doped SrB4O7 glasses and crystalline materials,” Opt. Express17(16), 13554–13560 (2009). [CrossRef] [PubMed]
- L. Su, J. Yu, P. Zhou, H. Li, L. Zheng, Y. Yang, F. Wu, H. Xia, and J. Xu, “Broadband near-infrared luminescence in γ-irradiated Bi-doped α-BaB2O4 single crystals,” Opt. Lett.34(16), 2504–2506 (2009). [CrossRef] [PubMed]
- H. Sun, Y. Sakka, H. Gao, Y. Miwa, M. Fujii, N. Shirahata, Z. Bai, and J. Li, “Ultrabroad near-infrared photoluminescence from Bi5(AlCl4)3 crystal,” J. Mater. Chem.21(12), 4060–4063 (2011). [CrossRef]
- M. Qian, C. Yu, J. Cheng, K. Li, and L. Hu, “The broadband NIR emission properties of Bi doped La2O3-Al2O3-SiO2 glass,” J. Lumin.132(10), 2634–2638 (2012). [CrossRef]
- L. Su, H. Zhao, H. Li, L. Zheng, X. Fan, X. Jiang, H. Tang, G. Ren, J. Xu, W. Ryba-Romanowski, R. Lisiecki, and P. Solarz, “Near-infrared photoluminescence spectra in Bi-doped CsI crystal: evidence for Bi-valence conversions and Bi ion aggregation,” Opt. Mater. Express2(6), 757–764 (2012). [CrossRef]
- L. Su, H. Zhao, H. Li, L. Zheng, G. Ren, J. Xu, W. Ryba-Romanowski, R. Lisiecki, and P. Solarz, “Near-infrared ultrabroadband luminescence spectra properties of subvalent bismuth in CsI halide crystals,” Opt. Lett.36(23), 4551–4553 (2011). [CrossRef] [PubMed]
- C. Luo, H. Xia, C. Yu, and J. Xu, “Luminescence of Bi-doped CdWO4 single crystals,” Acta Phys. Sin.60(7), 077806 (2011).
- H. T. Sun, Y. Matsushita, Y. Sakka, N. Shirahata, M. Tanaka, Y. Katsuya, H. Gao, and K. Kobayashi, “Synchrotron X-ray, photoluminescence, and quantum chemistry studies of bismuth-embedded dehydrated zeolite Y,” J. Am. Chem. Soc.134(6), 2918–2921 (2012). [CrossRef] [PubMed]
- H. Sun, Y. Sakka, H. Gao, Y. Miwa, M. Fujii, N. Shirahata, Z. Bai, and J. Li, “Ultrabroad near-infrared photoluminescence from Bi5(AlCl4)3 crystal,” J. Mater. Chem.21(12), 4060–4063 (2011). [CrossRef]
- H. Sun, Y. Sakka, Y. Miwa, N. Shirahata, M. Fujii, and H. Gao, “Spectroscopic characterization of bismuth embedded Y zeolites,” Appl. Phys. Lett.97(13), 131908 (2010). [CrossRef]
- N. Tokitoh, Y. Arai, R. Okazaki, and S. Nagase, “Synthesis and characterization of a stable dibismuthene: Evidence for a Bi-Bi double bond,” Science277(5322), 78–80 (1997). [CrossRef]
- Y. Fujimoto and M. Nakatsuka, “Infrared luminescence from bismuth-doped silica glass,” J. Appl. Phys.40(Part 2, No. 3B), L279–L281 (2001).
- N. Tokitoh, Y. Arai, R. Okazaki, and S. Nagase, “Synthesis and characterization of a stable dibismuthene: Evidence for a Bi-Bi double bond,” Science277(5322), 78–80 (1997). [CrossRef]
- Q. Zheng, T. Zhang, and Z. Pei, “Luminescence of unusual bismuth in barium berates BaB8O13: Bi,” J. Mater. Sci. Technol.15(3), 281–282 (1999).
- M. Peng, D. Chen, J. Qiu, X. Jiang, and C. Zhu, “Bismuth-doped zinc aluminosilicate glasses and glass-ceramics with ultra-broadband infrared luminescence,” Opt. Mater.29(5), 556–561 (2007). [CrossRef]
- A. Cremades, J. Piqueras, A. Remon, J. A. Garcia, M. T. Santos, and E. Diéguez, “Luminescence study of thermal treated and laser irradiated Bi12GeO20 and Bi12SiO20 crystals,” J. Appl. Phys.83(12), 7948–7952 (1998). [CrossRef]
- M. Qian, C. Yu, J. Cheng, K. Li, and L. Hu, “The broadband NIR emission properties of Bi doped La2O3-Al2O3-SiO2 glass,” J. Lumin.132(10), 2634–2638 (2012). [CrossRef]
- J. Ruan, L. Su, J. Qiu, D. Chen, and J. Xu, “Bi-doped BaF2 crystal for broadband near-infrared light source,” Opt. Express17(7), 5163–5169 (2009). [CrossRef] [PubMed]
- J. Ren, G. Dong, S. Xu, R. Bao, and J. Qiu, “Inhomogeneous broadening, luminescence origin and optical amplification in bismuth-doped glass,” J. Phys. Chem. A112(14), 3036–3039 (2008). [CrossRef] [PubMed]
- M. Peng, D. Chen, J. Qiu, X. Jiang, and C. Zhu, “Bismuth-doped zinc aluminosilicate glasses and glass-ceramics with ultra-broadband infrared luminescence,” Opt. Mater.29(5), 556–561 (2007). [CrossRef]
- A. Cremades, J. Piqueras, A. Remon, J. A. Garcia, M. T. Santos, and E. Diéguez, “Luminescence study of thermal treated and laser irradiated Bi12GeO20 and Bi12SiO20 crystals,” J. Appl. Phys.83(12), 7948–7952 (1998). [CrossRef]
- L. Su, H. Zhao, H. Li, L. Zheng, X. Fan, X. Jiang, H. Tang, G. Ren, J. Xu, W. Ryba-Romanowski, R. Lisiecki, and P. Solarz, “Near-infrared photoluminescence spectra in Bi-doped CsI crystal: evidence for Bi-valence conversions and Bi ion aggregation,” Opt. Mater. Express2(6), 757–764 (2012). [CrossRef]
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