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Characteristics of 2-photon ultraviolet laser etching of diamondR. P. Mildren, J. E. Downes, J. D. Brown, B. F. Johnston, E. Granados, D. J. Spence, A. Lehmann, L. Weston, and A. Bramble »View Author Affiliations
R. P. Mildren,*
J. E. Downes,
J. D. Brown,
B. F. Johnston,
E. Granados,
D. J. Spence,
A. Lehmann,
L. Weston,
and A. Bramble
MQ Photonics Research Centre, Macquarie University, Sydney, NSW 2109, Australia *Corresponding author: rich.mildren@mq.edu.au |
Optical Materials Express, Vol. 1, Issue 4, pp. 576-585 (2011)
http://dx.doi.org/10.1364/OME.1.000576
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Abstract
We report graphite-free laser etching of diamond surfaces using 266 nm laser pulses for a wide range of incident fluences below the threshold for ablation. The etching rate is proportional to the (fluence) x where x = 1.88 ± 0.16 over the range 10−6 - 10−2 nm per pulse for incident pulse fluences 1 – 60 J/cm2. Surface sensitive near edge x-ray fine absorption structure measurements (partial electron yield NEXAFS) reveal that etching does not significantly alter the surface structure from the initial oxygen terminated and graphite-free state. The etching process, which is consistent with a mechanism involving the desorption of carbon species via the decay of 2-photon excited excitons near the surface, appears to have no threshold and is promising for creating a range of high resolution structures.
© 2011 OSA
OCIS Codes
(140.3610) Lasers and laser optics : Lasers, ultraviolet
(160.4670) Materials : Optical materials
(220.1920) Optical design and fabrication : Diamond machining
(220.4000) Optical design and fabrication : Microstructure fabrication
(220.4610) Optical design and fabrication : Optical fabrication
ToC Category:
Laser Materials Processing
History
Original Manuscript: June 21, 2011
Revised Manuscript: July 4, 2011
Manuscript Accepted: July 4, 2011
Published: July 12, 2011
Citation
R. P. Mildren, J. E. Downes, J. D. Brown, B. F. Johnston, E. Granados, D. J. Spence, A. Lehmann, L. Weston, and A. Bramble, "Characteristics of 2-photon ultraviolet laser etching of diamond," Opt. Mater. Express 1, 576-585 (2011)
http://www.opticsinfobase.org/ome/abstract.cfm?URI=ome-1-4-576
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References
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- E. Gu, H. W. Choi, C. Liu, C. Griffin, J. M. Girkin, I. M. Watson, M. D. Dawson, G. McConnell, and A. M. Gurney, “Reflection/transmission confocal microscopy characterization of single-crystal diamond microlens arrays,” Appl. Phys. Lett. 84(15), 2754–2756 (2004). [CrossRef]
- S. Castelletto, J. P. Harrison, L. Marseglia, A. C. Stanley-Clarke, B. C. Gibson, B. A. Fairchild, J. P. Hadden, Y.-L. D. Ho, M. P. Hiscocks, K. Ganesan, S. T. Huntington, F. Ladouceur, A. D. Greentree, S. Prawer, J. L. O’Brien, and J. G. Rarity, “Diamond-based structures to collect and guide light,” N. J. Phys. 13(2), 025020 (2011). [CrossRef]
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- S. Castelletto, J. P. Harrison, L. Marseglia, A. C. Stanley-Clarke, B. C. Gibson, B. A. Fairchild, J. P. Hadden, Y.-L. D. Ho, M. P. Hiscocks, K. Ganesan, S. T. Huntington, F. Ladouceur, A. D. Greentree, S. Prawer, J. L. O’Brien, and J. G. Rarity, “Diamond-based structures to collect and guide light,” N. J. Phys. 13(2), 025020 (2011). [CrossRef]
- A. Stacey, B. Cowie, J. Orwa, S. Prawer, and A. Hoffman, “Diamond C 1s core-level excitons: surface sensitivity,” Phys. Rev. B 82(12), 125427 (2010). [CrossRef]
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- T. Gaebel, M. Domhan, I. Popa, C. Wittmann, P. Neumann, F. Jelezko, J. R. Rabeau, N. Stavrias, A. D. Greentree, S. Prawer, J. Meijer, J. Twamley, P. R. Hemmer, and J. Wrachtrup, “Room-temperature coherent coupling of single spins in diamond,” Nat. Phys. 2(6), 408–413 (2006). [CrossRef]
- M. J. A. de Dood, A. Polman, T. Zijlstra, and E. W. J. M. van der Drift, “Amorphous silicon waveguides for microphotonics,” J. Appl. Phys. 92(2), 649–653 (2002). [CrossRef]
- E. Gu, H. W. Choi, C. Liu, C. Griffin, J. M. Girkin, I. M. Watson, M. D. Dawson, G. McConnell, and A. M. Gurney, “Reflection/transmission confocal microscopy characterization of single-crystal diamond microlens arrays,” Appl. Phys. Lett. 84(15), 2754–2756 (2004). [CrossRef]
- V. V. Kononenko, T. V. Kononenko, S. M. Pimenov, V. I. Konov, P. Fischer, V. Romano, H. P. Weber, A. V. Khomich, R. A. Khmelnitskiy, and V. N. Strekalov, “Laser-induced structure transformations of diamonds,” Proc. SPIE 5121, 259–270 (2003). [CrossRef]
- J. C. Zheng, X. N. Xie, A. T. S. Wee, and K. P. Loh, “Oxygen-induced surface state on diamond (100),” Diamond Related Materials 10(3-7), 500–505 (2001). [CrossRef]
- T. Gaebel, M. Domhan, I. Popa, C. Wittmann, P. Neumann, F. Jelezko, J. R. Rabeau, N. Stavrias, A. D. Greentree, S. Prawer, J. Meijer, J. Twamley, P. R. Hemmer, and J. Wrachtrup, “Room-temperature coherent coupling of single spins in diamond,” Nat. Phys. 2(6), 408–413 (2006). [CrossRef]
- W. J. Zhang, Y. Wu, W. K. Wong, X. M. Meng, C. Y. Chan, I. Bello, Y. Lifshitz, and S. T. Lee, “Structuring nanodiamond cone arrays for improved field emission,” Appl. Phys. Lett. 83(16), 3365–3367 (2003). [CrossRef]
- T. Gaebel, M. Domhan, I. Popa, C. Wittmann, P. Neumann, F. Jelezko, J. R. Rabeau, N. Stavrias, A. D. Greentree, S. Prawer, J. Meijer, J. Twamley, P. R. Hemmer, and J. Wrachtrup, “Room-temperature coherent coupling of single spins in diamond,” Nat. Phys. 2(6), 408–413 (2006). [CrossRef]
- J. Smedley, J. Bohon, Q. Wu, and T. Rao, “Laser patterning of diamond. Part I. Characterization of surface morphology,” J. Appl. Phys. 105(12), 123107 (2009). [CrossRef]
- W. J. Zhang, Y. Wu, W. K. Wong, X. M. Meng, C. Y. Chan, I. Bello, Y. Lifshitz, and S. T. Lee, “Structuring nanodiamond cone arrays for improved field emission,” Appl. Phys. Lett. 83(16), 3365–3367 (2003). [CrossRef]
- J. C. Zheng, X. N. Xie, A. T. S. Wee, and K. P. Loh, “Oxygen-induced surface state on diamond (100),” Diamond Related Materials 10(3-7), 500–505 (2001). [CrossRef]
- H. Yoshida, Y. Yamashita, M. Kuwabara, and H. Kan, “Demonstration of an ultraviolet 336 nm AlGaN multiple-quantum-well laser diode,” Appl. Phys. Lett. 93(24), 241106 (2008). [CrossRef]
- H. Yoshida, Y. Yamashita, M. Kuwabara, and H. Kan, “Demonstration of an ultraviolet 336 nm AlGaN multiple-quantum-well laser diode,” Appl. Phys. Lett. 93(24), 241106 (2008). [CrossRef]
- D. Zeisel, S. Nettesheim, B. Dutoit, and R. Zenobi, “Pulsed laser-induced desorption and optical imaging on a nanometer scale with scanning near-field microscopy using chemically etched fiber tips,” Appl. Phys. Lett. 68(18), 2491–2492 (1996). [CrossRef]
- D. Zeisel, S. Nettesheim, B. Dutoit, and R. Zenobi, “Pulsed laser-induced desorption and optical imaging on a nanometer scale with scanning near-field microscopy using chemically etched fiber tips,” Appl. Phys. Lett. 68(18), 2491–2492 (1996). [CrossRef]
- W. J. Zhang, Y. Wu, W. K. Wong, X. M. Meng, C. Y. Chan, I. Bello, Y. Lifshitz, and S. T. Lee, “Structuring nanodiamond cone arrays for improved field emission,” Appl. Phys. Lett. 83(16), 3365–3367 (2003). [CrossRef]
- J. C. Zheng, X. N. Xie, A. T. S. Wee, and K. P. Loh, “Oxygen-induced surface state on diamond (100),” Diamond Related Materials 10(3-7), 500–505 (2001). [CrossRef]
- M. J. A. de Dood, A. Polman, T. Zijlstra, and E. W. J. M. van der Drift, “Amorphous silicon waveguides for microphotonics,” J. Appl. Phys. 92(2), 649–653 (2002). [CrossRef]
Adv. Mater. (Deerfield Beach Fla.)
- P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Ion-beam-assisted lift-off technique for three-dimensional micromachining of freestanding single-crystal diamond,” Adv. Mater. (Deerfield Beach Fla.) 17(20), 2427–2430 (2005). [CrossRef]
Appl. Opt.
- A. Harasaki, J. Schmit, and J. C. Wyant, “Improved vertical-scanning interferometry,” Appl. Opt. 39(13), 2107–2115 (2000). [CrossRef] [PubMed]
Appl. Phys. Lett.
- S. Preuss and M. Stuke, “Subpicosecond ultraviolet laser ablation of diamond: nonlinear properties at 248 nm and time-resolved characterization of ablation dynamics,” Appl. Phys. Lett. 67(3), 338–340 (1995). [CrossRef]
- W. J. Zhang, Y. Wu, W. K. Wong, X. M. Meng, C. Y. Chan, I. Bello, Y. Lifshitz, and S. T. Lee, “Structuring nanodiamond cone arrays for improved field emission,” Appl. Phys. Lett. 83(16), 3365–3367 (2003). [CrossRef]
- E. Gu, H. W. Choi, C. Liu, C. Griffin, J. M. Girkin, I. M. Watson, M. D. Dawson, G. McConnell, and A. M. Gurney, “Reflection/transmission confocal microscopy characterization of single-crystal diamond microlens arrays,” Appl. Phys. Lett. 84(15), 2754–2756 (2004). [CrossRef]
- L. Sekaric, J. M. Parpia, H. G. Craighead, T. Feygelson, B. H. Houston, and J. E. Butler, “Nanomechanical resonant structures in nanocrystalline diamond,” Appl. Phys. Lett. 81(23), 4455–4457 (2002). [CrossRef]
- M. Frenklach, D. Huang, R. E. Thomas, R. A. Rudder, and R. J. Markunas, “Activation energy and mechanism of CO desorption from (100) diamond surface,” Appl. Phys. Lett. 63(22), 3090–3092 (1993). [CrossRef]
- D. Zeisel, S. Nettesheim, B. Dutoit, and R. Zenobi, “Pulsed laser-induced desorption and optical imaging on a nanometer scale with scanning near-field microscopy using chemically etched fiber tips,” Appl. Phys. Lett. 68(18), 2491–2492 (1996). [CrossRef]
- H. Yoshida, Y. Yamashita, M. Kuwabara, and H. Kan, “Demonstration of an ultraviolet 336 nm AlGaN multiple-quantum-well laser diode,” Appl. Phys. Lett. 93(24), 241106 (2008). [CrossRef]
Appl. Phys., A Mater. Sci. Process.
- I. P. Sytov, “Estimation of the capabilities of maskless micropatterning by laser-induced chemical etching,” Appl. Phys., A Mater. Sci. Process. 61(1), 75–80 (1995). [CrossRef]
Appl. Surf. Sci.
- H. Jeschke and M. Garcia, “Theoretical description of the ultrafast ablation of diamond and graphite: dependence of thresholds on pulse duration,” Appl. Surf. Sci. 197–198, 107–113 (2002). [CrossRef]
Diamond Related Materials
- J. C. Zheng, X. N. Xie, A. T. S. Wee, and K. P. Loh, “Oxygen-induced surface state on diamond (100),” Diamond Related Materials 10(3-7), 500–505 (2001). [CrossRef]
J. Appl. Phys.
- M. J. A. de Dood, A. Polman, T. Zijlstra, and E. W. J. M. van der Drift, “Amorphous silicon waveguides for microphotonics,” J. Appl. Phys. 92(2), 649–653 (2002). [CrossRef]
- J. Smedley, C. Jaye, J. Bohon, T. Rao, and D. A. Fischer, “Laser patterning of diamond. Part II. Surface nondiamond carbon formation and its removal,” J. Appl. Phys. 105(12), 123108 (2009). [CrossRef]
- J. Smedley, J. Bohon, Q. Wu, and T. Rao, “Laser patterning of diamond. Part I. Characterization of surface morphology,” J. Appl. Phys. 105(12), 123107 (2009). [CrossRef]
- M. Shinoda, R. R. Gattass, and E. Mazur, “Femtosecond laser-induced formation of nanometer-width grooves on synthetic single-crystal diamond surfaces,” J. Appl. Phys. 105(5), 053102 (2009). [CrossRef]
J. Manuf. Sci. Eng.
- D. Ramanathan and P. A. Molian, “Micro- and sub-micromachining of Type IIa single crystal diamond using a Ti:sapphire femtosecond laser,” J. Manuf. Sci. Eng. 124(2), 389–396 (2002). [CrossRef]
J. Raman Spectrosc.
- S. K. Sudheer, V. P. M. Pillai, and V. U. Nayar, “Characterization of laser processing of single-crystal natural diamonds using micro-Raman spectroscopic investigations,” J. Raman Spectrosc. 38(4), 427–435 (2007). [CrossRef]
J. Vac. Sci. Technol.
- M. Rothschild, C. Arnone, and D. J. Ehrlich, “Excimer-laser etching of diamond and hard carbon films by direct writing and optical projection,” J. Vac. Sci. Technol. 4(1), 310–314 (1986). [CrossRef]
J. Vac. Sci. Technol. B
- D. J. Ehrlich and J. Y. Tsao, “A review of laser–microchemical processing,” J. Vac. Sci. Technol. B 1(4), 969–984 (1983). [CrossRef]
Jpn. J. Appl. Phys.
- Y. Muramatsu, K. Shimomura, T. Katayama, and E. M. Gullikson, “Total electron yield soft x-ray absorption spectroscopy in the CK region of the mixtures of graphitic carbons and diamond for quantitative analysis of the sp2/sp3-hybridized carbon ratio,” Jpn. J. Appl. Phys. 48(6), 066514 (2009). [CrossRef]
- M. Tarutani, Y. Takai, and R. Shimizu, “Application of the focused-ion-beam technique for preparing the cross-sectional sample of chemical vapor deposition diamond thin film for high-resolution transmission electron microscope observation,” Jpn. J. Appl. Phys. 31(Part 2, No. 9A), L1305–L1308 (1992). [CrossRef]
N. J. Phys.
- S. Castelletto, J. P. Harrison, L. Marseglia, A. C. Stanley-Clarke, B. C. Gibson, B. A. Fairchild, J. P. Hadden, Y.-L. D. Ho, M. P. Hiscocks, K. Ganesan, S. T. Huntington, F. Ladouceur, A. D. Greentree, S. Prawer, J. L. O’Brien, and J. G. Rarity, “Diamond-based structures to collect and guide light,” N. J. Phys. 13(2), 025020 (2011). [CrossRef]
Nat. Photonics
- A. Faraon, P. E. Barclay, C. Santori, K.-M. C. Fu, and R. G. Beausoleil, “Resonant enhancement of the zero-phonon emission from a colour centre in a diamond cavity,” Nat. Photonics 5(5), 301–305 (2011). [CrossRef]
Nat. Phys.
- T. Gaebel, M. Domhan, I. Popa, C. Wittmann, P. Neumann, F. Jelezko, J. R. Rabeau, N. Stavrias, A. D. Greentree, S. Prawer, J. Meijer, J. Twamley, P. R. Hemmer, and J. Wrachtrup, “Room-temperature coherent coupling of single spins in diamond,” Nat. Phys. 2(6), 408–413 (2006). [CrossRef]
Opt. Eng.
- B. Luther-Davies, A. V. Rode, N. R. Madsen, and E. Gamaly, “Picosecond high-repetition-rate pulsed laser ablation of dielectrics: the effect of energy accumulation between pulses,” Opt. Eng. 44(5), 051102 (2005). [CrossRef]
Opt. Express
- E. Granados, D. J. Spence, and R. P. Mildren, “Deep ultraviolet diamond Raman laser,” Opt. Express 19(11), 10857–10863 (2011). [CrossRef] [PubMed]
- R. P. Mildren, J. E. Butler, and J. R. Rabeau, “CVD-diamond external cavity Raman laser at 573 nm,” Opt. Express 16(23), 18950–18955 (2008). [CrossRef] [PubMed]
Opt. Lett.
- M. Karlsson, K. Hjort, and F. Nikolajeff, “Transfer of continuous-relief diffractive structures into diamond by use of inductively coupled plasma dry etching,” Opt. Lett. 26(22), 1752–1754 (2001). [CrossRef] [PubMed]
Phys. Rev. B
- A. Stacey, B. Cowie, J. Orwa, S. Prawer, and A. Hoffman, “Diamond C 1s core-level excitons: surface sensitivity,” Phys. Rev. B 82(12), 125427 (2010). [CrossRef]
- J. Cui, J. Ristein, and L. Ley, “Low threshold electron emission from diamond,” Phys. Rev. B 60(23), 16135–16142 (1999). [CrossRef]
Phys. Rev. Lett.
- C. Bandis and B. B. Pate, “Electron emission due to exciton breakup from negative electron affinity diamond,” Phys. Rev. Lett. 74(5), 777–780 (1995). [CrossRef] [PubMed]
- J. Ristein, W. Stein, and L. Ley, “Defect spectroscopy and determination of the electron diffusion length in single crystal diamond by total photoelectron yield spectroscopy,” Phys. Rev. Lett. 78(9), 1803–1806 (1997). [CrossRef]
Proc. SPIE
- V. V. Kononenko, T. V. Kononenko, S. M. Pimenov, V. I. Konov, P. Fischer, V. Romano, H. P. Weber, A. V. Khomich, R. A. Khmelnitskiy, and V. N. Strekalov, “Laser-induced structure transformations of diamonds,” Proc. SPIE 5121, 259–270 (2003). [CrossRef]
Quantum Electron.
- V. V. Kononenko, M. S. Komlenok, S. M. Pimenov, and V. I. Konov, “Photoinduced laser etching of a diamond surface,” Quantum Electron. 37(11), 1043–1046 (2007). [CrossRef]
Other
- A. Piqué and D. B. Chrisey, Direct-Write Technologies for Rapid Prototyping Applications: Sensor, Electronics, and Integrated Power Devices (Academic Press, 2002), p. 440.
2011, Faraon, Nat. Photonics
- A. Faraon, P. E. Barclay, C. Santori, K.-M. C. Fu, and R. G. Beausoleil, “Resonant enhancement of the zero-phonon emission from a colour centre in a diamond cavity,” Nat. Photonics 5(5), 301–305 (2011). [CrossRef]
- S. Castelletto, J. P. Harrison, L. Marseglia, A. C. Stanley-Clarke, B. C. Gibson, B. A. Fairchild, J. P. Hadden, Y.-L. D. Ho, M. P. Hiscocks, K. Ganesan, S. T. Huntington, F. Ladouceur, A. D. Greentree, S. Prawer, J. L. O’Brien, and J. G. Rarity, “Diamond-based structures to collect and guide light,” N. J. Phys. 13(2), 025020 (2011). [CrossRef]
- A. Stacey, B. Cowie, J. Orwa, S. Prawer, and A. Hoffman, “Diamond C 1s core-level excitons: surface sensitivity,” Phys. Rev. B 82(12), 125427 (2010). [CrossRef]
- Y. Muramatsu, K. Shimomura, T. Katayama, and E. M. Gullikson, “Total electron yield soft x-ray absorption spectroscopy in the CK region of the mixtures of graphitic carbons and diamond for quantitative analysis of the sp2/sp3-hybridized carbon ratio,” Jpn. J. Appl. Phys. 48(6), 066514 (2009). [CrossRef]
- J. Smedley, C. Jaye, J. Bohon, T. Rao, and D. A. Fischer, “Laser patterning of diamond. Part II. Surface nondiamond carbon formation and its removal,” J. Appl. Phys. 105(12), 123108 (2009). [CrossRef]
- J. Smedley, J. Bohon, Q. Wu, and T. Rao, “Laser patterning of diamond. Part I. Characterization of surface morphology,” J. Appl. Phys. 105(12), 123107 (2009). [CrossRef]
- M. Shinoda, R. R. Gattass, and E. Mazur, “Femtosecond laser-induced formation of nanometer-width grooves on synthetic single-crystal diamond surfaces,” J. Appl. Phys. 105(5), 053102 (2009). [CrossRef]
- H. Yoshida, Y. Yamashita, M. Kuwabara, and H. Kan, “Demonstration of an ultraviolet 336 nm AlGaN multiple-quantum-well laser diode,” Appl. Phys. Lett. 93(24), 241106 (2008). [CrossRef]
- S. K. Sudheer, V. P. M. Pillai, and V. U. Nayar, “Characterization of laser processing of single-crystal natural diamonds using micro-Raman spectroscopic investigations,” J. Raman Spectrosc. 38(4), 427–435 (2007). [CrossRef]
- V. V. Kononenko, M. S. Komlenok, S. M. Pimenov, and V. I. Konov, “Photoinduced laser etching of a diamond surface,” Quantum Electron. 37(11), 1043–1046 (2007). [CrossRef]
- T. Gaebel, M. Domhan, I. Popa, C. Wittmann, P. Neumann, F. Jelezko, J. R. Rabeau, N. Stavrias, A. D. Greentree, S. Prawer, J. Meijer, J. Twamley, P. R. Hemmer, and J. Wrachtrup, “Room-temperature coherent coupling of single spins in diamond,” Nat. Phys. 2(6), 408–413 (2006). [CrossRef]
- P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Ion-beam-assisted lift-off technique for three-dimensional micromachining of freestanding single-crystal diamond,” Adv. Mater. (Deerfield Beach Fla.) 17(20), 2427–2430 (2005). [CrossRef]
- B. Luther-Davies, A. V. Rode, N. R. Madsen, and E. Gamaly, “Picosecond high-repetition-rate pulsed laser ablation of dielectrics: the effect of energy accumulation between pulses,” Opt. Eng. 44(5), 051102 (2005). [CrossRef]
- E. Gu, H. W. Choi, C. Liu, C. Griffin, J. M. Girkin, I. M. Watson, M. D. Dawson, G. McConnell, and A. M. Gurney, “Reflection/transmission confocal microscopy characterization of single-crystal diamond microlens arrays,” Appl. Phys. Lett. 84(15), 2754–2756 (2004). [CrossRef]
- W. J. Zhang, Y. Wu, W. K. Wong, X. M. Meng, C. Y. Chan, I. Bello, Y. Lifshitz, and S. T. Lee, “Structuring nanodiamond cone arrays for improved field emission,” Appl. Phys. Lett. 83(16), 3365–3367 (2003). [CrossRef]
- V. V. Kononenko, T. V. Kononenko, S. M. Pimenov, V. I. Konov, P. Fischer, V. Romano, H. P. Weber, A. V. Khomich, R. A. Khmelnitskiy, and V. N. Strekalov, “Laser-induced structure transformations of diamonds,” Proc. SPIE 5121, 259–270 (2003). [CrossRef]
- L. Sekaric, J. M. Parpia, H. G. Craighead, T. Feygelson, B. H. Houston, and J. E. Butler, “Nanomechanical resonant structures in nanocrystalline diamond,” Appl. Phys. Lett. 81(23), 4455–4457 (2002). [CrossRef]
- M. J. A. de Dood, A. Polman, T. Zijlstra, and E. W. J. M. van der Drift, “Amorphous silicon waveguides for microphotonics,” J. Appl. Phys. 92(2), 649–653 (2002). [CrossRef]
- H. Jeschke and M. Garcia, “Theoretical description of the ultrafast ablation of diamond and graphite: dependence of thresholds on pulse duration,” Appl. Surf. Sci. 197–198, 107–113 (2002). [CrossRef]
- D. Ramanathan and P. A. Molian, “Micro- and sub-micromachining of Type IIa single crystal diamond using a Ti:sapphire femtosecond laser,” J. Manuf. Sci. Eng. 124(2), 389–396 (2002). [CrossRef]
- J. C. Zheng, X. N. Xie, A. T. S. Wee, and K. P. Loh, “Oxygen-induced surface state on diamond (100),” Diamond Related Materials 10(3-7), 500–505 (2001). [CrossRef]
- J. Cui, J. Ristein, and L. Ley, “Low threshold electron emission from diamond,” Phys. Rev. B 60(23), 16135–16142 (1999). [CrossRef]
- J. Ristein, W. Stein, and L. Ley, “Defect spectroscopy and determination of the electron diffusion length in single crystal diamond by total photoelectron yield spectroscopy,” Phys. Rev. Lett. 78(9), 1803–1806 (1997). [CrossRef]
- D. Zeisel, S. Nettesheim, B. Dutoit, and R. Zenobi, “Pulsed laser-induced desorption and optical imaging on a nanometer scale with scanning near-field microscopy using chemically etched fiber tips,” Appl. Phys. Lett. 68(18), 2491–2492 (1996). [CrossRef]
- C. Bandis and B. B. Pate, “Electron emission due to exciton breakup from negative electron affinity diamond,” Phys. Rev. Lett. 74(5), 777–780 (1995). [CrossRef] [PubMed]
- S. Preuss and M. Stuke, “Subpicosecond ultraviolet laser ablation of diamond: nonlinear properties at 248 nm and time-resolved characterization of ablation dynamics,” Appl. Phys. Lett. 67(3), 338–340 (1995). [CrossRef]
- I. P. Sytov, “Estimation of the capabilities of maskless micropatterning by laser-induced chemical etching,” Appl. Phys., A Mater. Sci. Process. 61(1), 75–80 (1995). [CrossRef]
- M. Frenklach, D. Huang, R. E. Thomas, R. A. Rudder, and R. J. Markunas, “Activation energy and mechanism of CO desorption from (100) diamond surface,” Appl. Phys. Lett. 63(22), 3090–3092 (1993). [CrossRef]
- M. Tarutani, Y. Takai, and R. Shimizu, “Application of the focused-ion-beam technique for preparing the cross-sectional sample of chemical vapor deposition diamond thin film for high-resolution transmission electron microscope observation,” Jpn. J. Appl. Phys. 31(Part 2, No. 9A), L1305–L1308 (1992). [CrossRef]
- M. Rothschild, C. Arnone, and D. J. Ehrlich, “Excimer-laser etching of diamond and hard carbon films by direct writing and optical projection,” J. Vac. Sci. Technol. 4(1), 310–314 (1986). [CrossRef]
- D. J. Ehrlich and J. Y. Tsao, “A review of laser–microchemical processing,” J. Vac. Sci. Technol. B 1(4), 969–984 (1983). [CrossRef]
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