Phosphorous doping and drawing effects on the Raman spectroscopic properties of O = P bond in silica-based fiber and preform

doi:10.1364/OME.2.001391

Phosphorous doping and drawing effects on the Raman spectroscopic properties of O = P bond in silica-based fiber and preform

A. Alessi, S. Girard, M. Cannas, A. Boukenter, and Y. Ouerdane »View Author Affiliations

Optical Materials Express, Vol. 2, Issue 10, pp. 1391-1396 (2012)
http://dx.doi.org/10.1364/OME.2.001391

View Full Text Article

Enhanced HTML Acrobat PDF (845 KB)

Journal Search
Article Lookup

Article Tools

Citations

Alert me when this article is cited
Export Citation/Save

Abstract
Article Info
References (16)
Cited By
Figures (5)
Metrics
Related Content

Abstract

We report an experimental study of the doping and drawing effects on the Raman activities of phosphorus (P)-doped silica-based optical fiber and its related preform. Our data reveal a high sensitivity level in the full width at half maximum value of the 1330 cm⁻¹ (O = P) Raman band to the P-doping level. Its increase with the P doping level does not clash with an increase in the disorder of the O = P surrendering matrix. In addition, we observe that in the central core region of the sample (higher doping level), the drawing process decreases the relative band amplitude. We tentatively suggest that this phenomenon is due to the change in the first derivate of the bond polarizability as a function of the normal vibration coordinates.

OCIS Codes
(060.2280) Fiber optics and optical communications : Fiber design and fabrication
(060.2290) Fiber optics and optical communications : Fiber materials
(060.2310) Fiber optics and optical communications : Fiber optics
(160.2750) Materials : Glass and other amorphous materials
(300.6450) Spectroscopy : Spectroscopy, Raman

ToC Category:
Materials for Fiber Optics

History
Original Manuscript: June 8, 2012
Revised Manuscript: July 28, 2012
Manuscript Accepted: July 28, 2012
Published: September 14, 2012

Citation
A. Alessi, S. Girard, M. Cannas, A. Boukenter, and Y. Ouerdane, "Phosphorous doping and drawing effects on the Raman spectroscopic properties of O = P bond in silica-based fiber and preform," Opt. Mater. Express 2, 1391-1396 (2012)
http://www.opticsinfobase.org/ome/abstract.cfm?URI=ome-2-10-1391

Sort: Author | Year | Journal | Reset

References

G. Pacchioni, L. Skuja, and D. L. Griscom, eds., Defects in SiO2 and Related Dielectrics: Science and Technology (Kluwer Academic, Dordrecht, 2000).
R. Kitamura, L. Pilon, and M. Jonasz, “Optical constants of silica glass from extreme ultraviolet to far infrared at near room temperature,” Appl. Opt.46(33), 8118–8133 (2007). [CrossRef] [PubMed]
A. J. Ikushima, T. Fujiwara, and K. Saito, “Silica glass: A material for photonics,” J. Appl. Phys.88(3), 1201–1213 (2000). [CrossRef]
R. A. B. Devine, J. P. Duraud, and E. Dooryhée, eds., Structure and Imperfections in Amorphous and Crystalline Silicon Dioxide (John Wiley & Sons, LTD, New York, 2000).
D. Ehrt, P. Ebeling, and U. Natura, “UV Transmission and radiation-induced defects in phosphate and fluoride-phosphate glasses,” J. Non-Cryst. Solids263-264, 240–250 (2000). [CrossRef]
P. L. Kelly, I. Kaminov, and G. Agrawal, eds., Erbium-Doped Fiber Amplifiers, Fundamental and Technology (Academic, London, 1999).
E. M. Dianov, M. V. Grekov, I. A. Bufetov, S. A. Vasiliev, O. I. Medvedkov, V. G. Plotnichenko, V. V. Koltashev, A. V. Belov, M. M. Bubnov, S. L. Semjonov, and A. M. Prokhorov, “CW high power 1.24 μm and 1.48 μm Raman lasers based on low loss phosphosilicate fibre,” Electron. Lett.33(18), 1542–1544 (1997). [CrossRef]
G. Origlio, F. Messina, S. Girard, M. Cannas, A. Boukenter, and Y. Ouerdane, “Spectroscopic studies of the origin of radiation-induced degradation in phosphorus-doped optical fibers and preforms,” J. Appl. Phys.108(12), 123103 (2010). [CrossRef]
V. G. Plotnichenko, V. O. Sokolov, V. V. Koltashev, and E. M. Dianov, “On the structure of phosphosilicate glasses,” J. Non-Cryst. Solids306(3), 209–226 (2002). [CrossRef]
N. Shibata, M. Horigudhi, and T. Edahiro, “Raman spectra of binary high-silica glasses and fibers containing GeO2, P2O5 and B2O3,” J. Non-Cryst. Solids45(1), 115–126 (1981). [CrossRef]
F. L. Galeener and A. E. Geissberger, “Vibrational dynamics in 30Si-substituted vitreous SiO2,” Phys. Rev. B27(10), 6199–6204 (1983). [CrossRef]
F. L. Galeener and G. Lucovsky, “Longitudinal optical vibrations in glasses: GeO2 and SiO2,” Phys. Rev. Lett.37(22), 1474–1478 (1976). [CrossRef]
M. Fanciulli, E. Bonera, S. Nokhrin, and G. Pacchioni, “Phosphorous–oxygen hole centers in phosphosilicate glass films,” Phys. Rev. B74(13), 134102 (2006). [CrossRef]
V. G. Plotnichenko, V. O. Sokolov, V. V. Koltashev, V. B. Sulimov, and E. M. Dianov, “UV-irradiation-induced structural transformation in phosphosilicate glass fiber,” Opt. Lett.23(18), 1447–1449 (1998). [CrossRef] [PubMed]
D. L. Griscom, E. J. Friebele, K. J. Long, and J. W. Fleming, “Fundamental defect centers in glass: Electron spin resonance and optical absorption studies of irradiated phosphorus-doped silica glass and optical fibers,” J. Appl. Phys.54(7), 3743–3762 (1983). [CrossRef]
E. M. Dianov, V. V. Koltashev, P. G. Plotnichenko, V. O. Sokolov, and V. B. Sulimov, “UV irradiation-induced structural transformation in phosphosilicate glass,” J. Non-Cryst. Solids249(1), 29–40 (1999). [CrossRef]

Belov, A. V.
Bonera, E.
Boukenter, A.
Bubnov, M. M.
Bufetov, I. A.
Cannas, M.
Dianov, E. M.
Ebeling, P.
Edahiro, T.
Ehrt, D.
Fanciulli, M.
Fleming, J. W.
Friebele, E. J.
Fujiwara, T.
Galeener, F. L.
Geissberger, A. E.
Girard, S.
Grekov, M. V.
Griscom, D. L.
Horigudhi, M.
Ikushima, A. J.
Jonasz, M.
Kitamura, R.
Koltashev, V. V.
Long, K. J.
Lucovsky, G.
Medvedkov, O. I.
Messina, F.
Natura, U.
Nokhrin, S.
Origlio, G.
Ouerdane, Y.
Pacchioni, G.
Pilon, L.
Plotnichenko, P. G.
Plotnichenko, V. G.
Prokhorov, A. M.
Saito, K.
Semjonov, S. L.
Shibata, N.
Sokolov, V. O.
Sulimov, V. B.
Vasiliev, S. A.

Appl. Opt.

R. Kitamura, L. Pilon, and M. Jonasz, “Optical constants of silica glass from extreme ultraviolet to far infrared at near room temperature,” Appl. Opt.46(33), 8118–8133 (2007). [CrossRef] [PubMed]

Electron. Lett.

E. M. Dianov, M. V. Grekov, I. A. Bufetov, S. A. Vasiliev, O. I. Medvedkov, V. G. Plotnichenko, V. V. Koltashev, A. V. Belov, M. M. Bubnov, S. L. Semjonov, and A. M. Prokhorov, “CW high power 1.24 μm and 1.48 μm Raman lasers based on low loss phosphosilicate fibre,” Electron. Lett.33(18), 1542–1544 (1997). [CrossRef]

J. Appl. Phys.

G. Origlio, F. Messina, S. Girard, M. Cannas, A. Boukenter, and Y. Ouerdane, “Spectroscopic studies of the origin of radiation-induced degradation in phosphorus-doped optical fibers and preforms,” J. Appl. Phys.108(12), 123103 (2010). [CrossRef]
A. J. Ikushima, T. Fujiwara, and K. Saito, “Silica glass: A material for photonics,” J. Appl. Phys.88(3), 1201–1213 (2000). [CrossRef]
D. L. Griscom, E. J. Friebele, K. J. Long, and J. W. Fleming, “Fundamental defect centers in glass: Electron spin resonance and optical absorption studies of irradiated phosphorus-doped silica glass and optical fibers,” J. Appl. Phys.54(7), 3743–3762 (1983). [CrossRef]

J. Non-Cryst. Solids

E. M. Dianov, V. V. Koltashev, P. G. Plotnichenko, V. O. Sokolov, and V. B. Sulimov, “UV irradiation-induced structural transformation in phosphosilicate glass,” J. Non-Cryst. Solids249(1), 29–40 (1999). [CrossRef]
D. Ehrt, P. Ebeling, and U. Natura, “UV Transmission and radiation-induced defects in phosphate and fluoride-phosphate glasses,” J. Non-Cryst. Solids263-264, 240–250 (2000). [CrossRef]
V. G. Plotnichenko, V. O. Sokolov, V. V. Koltashev, and E. M. Dianov, “On the structure of phosphosilicate glasses,” J. Non-Cryst. Solids306(3), 209–226 (2002). [CrossRef]
N. Shibata, M. Horigudhi, and T. Edahiro, “Raman spectra of binary high-silica glasses and fibers containing GeO2, P2O5 and B2O3,” J. Non-Cryst. Solids45(1), 115–126 (1981). [CrossRef]

Opt. Lett.

V. G. Plotnichenko, V. O. Sokolov, V. V. Koltashev, V. B. Sulimov, and E. M. Dianov, “UV-irradiation-induced structural transformation in phosphosilicate glass fiber,” Opt. Lett.23(18), 1447–1449 (1998). [CrossRef] [PubMed]

Phys. Rev. B

M. Fanciulli, E. Bonera, S. Nokhrin, and G. Pacchioni, “Phosphorous–oxygen hole centers in phosphosilicate glass films,” Phys. Rev. B74(13), 134102 (2006). [CrossRef]
F. L. Galeener and A. E. Geissberger, “Vibrational dynamics in 30Si-substituted vitreous SiO2,” Phys. Rev. B27(10), 6199–6204 (1983). [CrossRef]

Phys. Rev. Lett.

F. L. Galeener and G. Lucovsky, “Longitudinal optical vibrations in glasses: GeO2 and SiO2,” Phys. Rev. Lett.37(22), 1474–1478 (1976). [CrossRef]

Other

P. L. Kelly, I. Kaminov, and G. Agrawal, eds., Erbium-Doped Fiber Amplifiers, Fundamental and Technology (Academic, London, 1999).
R. A. B. Devine, J. P. Duraud, and E. Dooryhée, eds., Structure and Imperfections in Amorphous and Crystalline Silicon Dioxide (John Wiley & Sons, LTD, New York, 2000).
G. Pacchioni, L. Skuja, and D. L. Griscom, eds., Defects in SiO2 and Related Dielectrics: Science and Technology (Kluwer Academic, Dordrecht, 2000).

Cited By

Alert me when this paper is cited

OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.

Click here to see a list of articles that cite this paper