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Optical Materials Express

Optical Materials Express

  • Editor: David J. Hagan
  • Vol. 2, Iss. 10 — Oct. 1, 2012
  • pp: 1391–1396

Phosphorous doping and drawing effects on the Raman spectroscopic properties of O = P bond in silica-based fiber and preform

A. Alessi, S. Girard, M. Cannas, A. Boukenter, and Y. Ouerdane  »View Author Affiliations


Optical Materials Express, Vol. 2, Issue 10, pp. 1391-1396 (2012)
http://dx.doi.org/10.1364/OME.2.001391


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Abstract

We report an experimental study of the doping and drawing effects on the Raman activities of phosphorus (P)-doped silica-based optical fiber and its related preform. Our data reveal a high sensitivity level in the full width at half maximum value of the 1330 cm−1 (O = P) Raman band to the P-doping level. Its increase with the P doping level does not clash with an increase in the disorder of the O = P surrendering matrix. In addition, we observe that in the central core region of the sample (higher doping level), the drawing process decreases the relative band amplitude. We tentatively suggest that this phenomenon is due to the change in the first derivate of the bond polarizability as a function of the normal vibration coordinates.

© 2012 OSA

OCIS Codes
(060.2280) Fiber optics and optical communications : Fiber design and fabrication
(060.2290) Fiber optics and optical communications : Fiber materials
(060.2310) Fiber optics and optical communications : Fiber optics
(160.2750) Materials : Glass and other amorphous materials
(300.6450) Spectroscopy : Spectroscopy, Raman

ToC Category:
Materials for Fiber Optics

History
Original Manuscript: June 8, 2012
Revised Manuscript: July 28, 2012
Manuscript Accepted: July 28, 2012
Published: September 14, 2012

Citation
A. Alessi, S. Girard, M. Cannas, A. Boukenter, and Y. Ouerdane, "Phosphorous doping and drawing effects on the Raman spectroscopic properties of O = P bond in silica-based fiber and preform," Opt. Mater. Express 2, 1391-1396 (2012)
http://www.opticsinfobase.org/ome/abstract.cfm?URI=ome-2-10-1391


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