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Optical Materials Express

Optical Materials Express

  • Editor: David J. Hagan
  • Vol. 2, Iss. 6 — Jun. 1, 2012
  • pp: 757–764

Near-infrared photoluminescence spectra in Bi-doped CsI crystal: evidence for Bi-valence conversions and Bi ion aggregation

Liangbi Su, Hengyu Zhao, Hongjun Li, Lihe Zheng, Xiao Fan, Xiantao Jiang, Huili Tang, Guohao Ren, Jun Xu, Witold Ryba-Romanowski, Radosław Lisiecki, and Piotr Solarz  »View Author Affiliations


Optical Materials Express, Vol. 2, Issue 6, pp. 757-764 (2012)
http://dx.doi.org/10.1364/OME.2.000757


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Abstract

Bi-doped CsI crystals exhibited near-infrared ultra-broadband photoluminescence around 1216 nm and 1560 nm, depending on the bismuth doping levels, which were ascribed to Bi+ and Bi2+ centers, respectively. The crystal chemistry of the Bi3+ to Bi+ reduction and Bi2+ dimer formation in CsI lattice were investigated. Thermal treatments including annealing and quenching were carried out to study the thermal behaviors of the two emission bands. The evolution of absorption and emission spectra of Bi:CsI crystals indicating the Bi-aggregation and valence conversions under thermal activation. The process of Bi aggregation was observed to be a second-order reaction with activation energy of 0.33 eV. Bi2+ was identified as the origin of the 1560 nm emission band with ESR spectra. A simple lattice structure diagram was developed to illustrate the physical processes in Bi:CsI crystals induced by thermal activation.

© 2012 OSA

OCIS Codes
(160.3380) Materials : Laser materials
(300.6280) Spectroscopy : Spectroscopy, fluorescence and luminescence

ToC Category:
Laser Materials

History
Original Manuscript: March 22, 2012
Revised Manuscript: April 22, 2012
Manuscript Accepted: April 23, 2012
Published: May 4, 2012

Citation
Liangbi Su, Hengyu Zhao, Hongjun Li, Lihe Zheng, Xiao Fan, Xiantao Jiang, Huili Tang, Guohao Ren, Jun Xu, Witold Ryba-Romanowski, Radosław Lisiecki, and Piotr Solarz, "Near-infrared photoluminescence spectra in Bi-doped CsI crystal: evidence for Bi-valence conversions and Bi ion aggregation," Opt. Mater. Express 2, 757-764 (2012)
http://www.opticsinfobase.org/ome/abstract.cfm?URI=ome-2-6-757


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References

  1. P. P. Power, “Main-group elements as transition metals,” Nature463(7278), 171–177 (2010). [CrossRef] [PubMed]
  2. J. Beck and T. Hilbert, “Crystal structure and magnetic properties of Bi(Bi9)[NbCl6]3, a new member of the structure family Bi(Bi9)[MX6]3, and the crystal structure of Bi8[Ta2O2Br7]2,” Eur. J. Inorg. Chem.2004(10), 2019–2026 (2004). [CrossRef]
  3. Y. Fujimoto and M. Nakatsuka, “Infrared luminescence from bismuth-doped silica glass,” Jpn. J. Appl. Phys.40(Part 2, No. 3B), L279–L281 (2001). [CrossRef]
  4. H.-P. Xia and X.-J. Wang, “Near infrared broadband emission from Bi5+-doped Al2O3–GeO2–X (X=Na2O, BaO, Y2O3) glasses,” Appl. Phys. Lett.89(5), 051917 (2006). [CrossRef]
  5. J. Ren, J. Qiu, D. Chen, C. Wang, X. Jiang, and C. Zhu, “Infrared luminescence properties of bismuth-doped barium silicate glasses,” J. Mater. Res.22(07), 1954–1958 (2007). [CrossRef]
  6. X. G. Meng, J. R. Qiu, M. Y. Peng, D. P. Chen, Q. Z. Zhao, X. W. Jiang, and C. S. Zhu, “Near infrared broadband emission of bismuth-doped aluminophosphate glass,” Opt. Express13(5), 1628–1634 (2005). [CrossRef] [PubMed]
  7. V. Truong, L. Bigot, A. Lerouge, M. Douay, and I. Razdobreev, “Study of thermal stability and luminescence quenching properties of bismuth-doped silicate glasses for fiber laser applications,” Appl. Phys. Lett.92(4), 041908 (2008). [CrossRef]
  8. S. Zhou, N. Jiang, B. Zhu, H. Yang, S. Ye, G. Lakshminarayana, J. Hao, and J. Qiu, “Multifunctional Bismuth-Doped Nanoporous Silica Glass: From Blue-Green, Orange, Red, and White Light Sources to Ultra-Broadband Infrared Amplifiers,” Adv. Funct. Mater.18(9), 1407–1413 (2008). [CrossRef]
  9. M. Y. Sharonov, A. B. Bykov, V. Petricevic, and R. R. Alfano, “Spectroscopic study of optical centers formed in Bi-, Pb-, Sb-, Sn-, Te-, and In-doped germanate glasses,” Opt. Lett.33(18), 2131–2133 (2008). [CrossRef] [PubMed]
  10. Y. Arai, T. Suzuki, Y. Ohishi, S. Morimoto, and S. Khonthon, “Ultrabroadband near-infrared emission from a colorless bismuth-doped glass,” Appl. Phys. Lett.90(26), 261110 (2007). [CrossRef]
  11. M. Peng, J. Qiu, D. Chen, X. Meng, and C. Zhu, “Superbroadband 1310 nm emission from bismuth and tantalum codoped germanium oxide glasses,” Opt. Lett.30(18), 2433–2435 (2005). [CrossRef] [PubMed]
  12. H. Sun, A. Hosokawa, Y. Miwa, F. Shimaoka, M. Fujii, M. Mizuhata, S. Hayashi, and S. Deki, “Strong Ultra-Broadband Near-Infrared Photoluminescence from Bismuth-Embedded Zeolites and Their Derivatives,” Adv. Mater.21(36), 3694–3698 (2009). [CrossRef]
  13. E. Dianov, V. Dvoyrin, V. Mashinsky, A. Umnikov, M. Yashkov, and A. Guryanov, “CW bismuth fibre laser,” Quantum Electron.35(12), 1083–1084 (2005). [CrossRef]
  14. I. Bufetov and E. Dianov, “Bi-doped fiber lasers,” Laser Phys. Lett.6(7), 487–504 (2009). [CrossRef]
  15. H. T. Sun, J. Yang, M. Fujii, Y. Sakka, Y. Zhu, T. Asahara, N. Shirahata, M. Ii, Z. Bai, J. G. Li, and H. Gao, “Highly fluorescent silica-coated bismuth-doped aluminosilicate nanoparticles for near-infrared bioimaging,” Small7(2), 199–203 (2011). [CrossRef] [PubMed]
  16. V. O. Sokolov, V. G. Plotnichenko, and E. M. Dianov, “Origin of broadband near-infrared luminescence in bismuth-doped glasses,” Opt. Lett.33(13), 1488–1490 (2008). [CrossRef] [PubMed]
  17. M. Peng, C. Zollfrank, and L. Wondraczek, “Origin of broad NIR photoluminescence in bismuthate glass and Bi-doped glasses at room temperature,” J. Phys. Condens. Matter21(28), 285106 (2009). [CrossRef] [PubMed]
  18. H. Sun, Y. Sakka, Y. Miwa, N. Shirahata, M. Fujii, and H. Gao, “Spectroscopic characterization of bismuth embedded Y zeolites,” Appl. Phys. Lett.97(13), 131908 (2010). [CrossRef]
  19. H. T. Sun, Y. Sakka, M. Fujii, N. Shirahata, and H. Gao, “Ultrabroad near-infrared photoluminescence from ionic liquids containing subvalent bismuth,” Opt. Lett.36(2), 100–102 (2011). [CrossRef] [PubMed]
  20. H. Sun, Y. Sakka, H. Gao, Y. Miwa, M. Fujii, N. Shirahata, Z. Bai, and J. Li, “Ultrabroad near-infrared photoluminescence from Bi5(AlCl4)3 crystal,” J. Mater. Chem.21(12), 4060–4063 (2011). [CrossRef]
  21. A. G. Okhrimchuk, L. N. Butvina, E. M. Dianov, N. V. Lichkova, V. N. Zagorodnev, and K. N. Boldyrev, “Near-infrared luminescence of RbPb2Cl5:Bi crystals,” Opt. Lett.33(19), 2182–2184 (2008). [CrossRef] [PubMed]
  22. V. O. Sokolov, V. G. Plotnichenko, and E. M. Dianov, “Origin of broadband near-infrared luminescence in bismuth-doped glasses,” Opt. Lett.33(13), 1488–1490 (2008). [CrossRef] [PubMed]
  23. H. T. Sun, Y. Miwa, F. Shimaoka, M. Fujii, A. Hosokawa, M. Mizuhata, S. Hayashi, and S. Deki, “Superbroadband near-IR nano-optical source based on bismuth-doped high-silica nanocrystalline zeolites,” Opt. Lett.34(8), 1219–1221 (2009). [CrossRef] [PubMed]
  24. J. Ruan, L. Su, J. Qiu, D. Chen, and J. Xu, “Bi-doped BaF2 crystal for broadband near-infrared light source,” Opt. Express17(7), 5163–5169 (2009). [CrossRef] [PubMed]
  25. L. Su, P. Zhou, J. Yu, H. Li, L. Zheng, F. Wu, Y. Yang, Q. Yang, and J. Xu, “Spectroscopic properties and near-infrared broadband luminescence of Bi-doped SrB4O7 glasses and crystalline materials,” Opt. Express17(16), 13554–13560 (2009). [CrossRef] [PubMed]
  26. L. Su, J. Yu, P. Zhou, H. Li, L. Zheng, Y. Yang, F. Wu, H. Xia, and J. Xu, “Broadband near-infrared luminescence in γ-irradiated Bi-doped α-BaB2O4 single crystals,” Opt. Lett.34(16), 2504–2506 (2009). [CrossRef] [PubMed]
  27. L. Su, H. Zhao, H. Li, L. Zheng, G. Ren, J. Xu, W. Ryba-Romanowski, R. Lisiecki, and P. Solarz, “Near-infrared ultrabroadband luminescence spectra properties of subvalent bismuth in CsI halide crystals,” Opt. Lett.36(23), 4551–4553 (2011). [CrossRef] [PubMed]
  28. L. Mollenauer, N. Vieira, and L. Szeto, “Optical properties of the Tl0(1) center in KCl,” Phys. Rev. B27(9), 5332–5346 (1983). [CrossRef]
  29. M. Fockele, F. Lohse, J.-M. Spaeth, and R. H. Bartram, “Identification and optical properties of axial lead centres in alkaline-earth fluorides,” J. Phys. Condens. Matter1(1), 13–26 (1989). [CrossRef]
  30. M. Srivastava, “Luminescence of divalent bismuth in M2+BPO5 (M2+=Ba2+, Sr2+ and Ca2+),” J. Lumin.78(4), 239–243 (1998). [CrossRef]
  31. G. Stoicescu, S. Nistor, and C. Mateescu, “Aggregation of Bismuth in NaCl Crystals,” Phys. Status Solidi B156(2), 411–418 (1989). [CrossRef]
  32. S. Nistor, G. Stoicescu, and C. Mateescu, “Incorporation and Aggregation Properties of Bismuth Ions in KCl Crystals,” Phys. Status Solidi B160(2), 423–431 (1990). [CrossRef]
  33. A. Romanov, Z. Fattakhova, D. Zhigunov, V. Korchak, and V. Sulimov, “On the origin of near-IR luminescence in Bi-doped materials (I). Generation of low-valence bismuth species by Bi3+ and Bi0 synproportionation,” Opt. Mater.33(4), 631–634 (2011). [CrossRef]
  34. J. Sierro, “Paramagnetic resonance of the VF center in CaF2,” Phys. Rev.138(2A), A648–A650 (1965). [CrossRef]
  35. M. Grinberg, A. Mandelis, K. Fjeldsted, and A. Othonos, “Spectroscopy and analysis of radiative and nonradiative processes in Ti3+:Al2O3 crystals,” Phys. Rev. B Condens. Matter48(9), 5922–5934 (1993). [CrossRef] [PubMed]

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