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Optical Materials Express

Optical Materials Express

  • Editor: David J. Hagan
  • Vol. 3, Iss. 9 — Sep. 1, 2013
  • pp: 1504–1515

Complex third-order nonlinear optical susceptibility spectrum of a CdS film coat on a silver nanoparticle

Toshihiro Okamoto, Hiroki Koizumi, Masanobu Haraguchi, Masuo Fukui, and Akira Otomo  »View Author Affiliations


Optical Materials Express, Vol. 3, Issue 9, pp. 1504-1515 (2013)
http://dx.doi.org/10.1364/OME.3.001504


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Abstract

We have fabricated a CdS-coated Ag nanoparticle using the reverse micelle method and observed the nonlinear optical response of the scattered light intensity caused by an individual particle. In addition, we succeeded in obtaining the complex third-order nonlinear susceptibility χ(3) spectrum near the energy band edge of the CdS film by comparing the experimental result and the result of the Mie calculation that considered the optical Kerr effect of the CdS. At ħωi = 2.43 eV, the χ(3) of the CdS was (1.1 + i0.6) × 10−17m2/V2. We conjecture that an increase in the carriers in the interband transition of the CdS originates from the increase in the χ(3) of the CdS at ħωi > 2.4eV.

© 2013 OSA

OCIS Codes
(120.6710) Instrumentation, measurement, and metrology : Susceptibility
(190.3270) Nonlinear optics : Kerr effect
(240.6680) Optics at surfaces : Surface plasmons
(290.4020) Scattering : Mie theory
(300.6470) Spectroscopy : Spectroscopy, semiconductors
(160.4236) Materials : Nanomaterials

ToC Category:
Nonlinear Optical Materials

History
Original Manuscript: July 11, 2013
Revised Manuscript: August 18, 2013
Manuscript Accepted: August 19, 2013
Published: August 27, 2013

Citation
Toshihiro Okamoto, Hiroki Koizumi, Masanobu Haraguchi, Masuo Fukui, and Akira Otomo, "Complex third-order nonlinear optical susceptibility spectrum of a CdS film coat on a silver nanoparticle," Opt. Mater. Express 3, 1504-1515 (2013)
http://www.opticsinfobase.org/ome/abstract.cfm?URI=ome-3-9-1504


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References

  1. D. Sarid and W. Challener, Modern Introduction to Surface Plasmons (Cambridge, 2010).
  2. M. Pelton and G. W. Bryant, Introduction to Metal-Nanoparticle Plasmonics (Wiley, 2013).
  3. Y. Inouye and S. Kawata, “Near-field scanning optical microscope with a metallic probe tip,” Opt. Lett.19(3), 159–161 (1994). [CrossRef] [PubMed]
  4. S. Kawata, Y. Inouye, and P. Verma, “Plasmonics for near-field nano-imaging and superlensing,” Nat. Photonics3(7), 388–394 (2009). [CrossRef]
  5. T. Okamoto, I. Yamaguchi, and T. Kobayashi, “Local plasmon sensor with gold colloid monolayers deposited upon glass substrates,” Opt. Lett.25(6), 372–374 (2000). [CrossRef] [PubMed]
  6. G. Raschke, S. Kowarik, T. Franzl, C. Sönnichsen, T. A. Klar, J. Feldmann, A. Nichtl, and K. Kürzinger, “Biomolecular Recognition Based on Single Gold Nanoparticle Light Scattering,” Nano Lett.3(7), 935–938 (2003). [CrossRef]
  7. J. N. Anker, W. P. Hall, O. Lyandres, N. C. Shah, J. Zhao, and R. P. Van Duyne, “Biosensing with plasmonic nanosensors,” Nat. Mater.7(6), 442–453 (2008). [CrossRef] [PubMed]
  8. A. N. Goldstein, C. M. Echer, and A. P. Alivisatos, “Melting in Semiconductor Nanocrystals,” Science256(5062), 1425–1427 (1992). [CrossRef] [PubMed]
  9. K. Rajeshwar, N. R. de Tacconi, and C. R. Chenthamarakshan, “Semiconductor-Based Composite Materials: Preparation, Properties, and Performance,” Chem. Mater.13(9), 2765–2782 (2001). [CrossRef]
  10. P. M. Petersen, “Nonlinear refraction of Gaussian laser beams in CdS at λ =532nm,” J. Lumin.40–41, 533–534 (1988). [CrossRef]
  11. V. N. Semioshko and Y. P. Tsiashchenko, “The Temperature Dependence of The Third-Order Nonlinear Susceptibility in CdS in the Vicinity of the Absorption Edge,” Phys. Status Solidi184(1), K37–K40 (1994) (b). [CrossRef]
  12. Z. Li, G. Xiong, Z. Zhao, and X. Fan, “Measurement of optical nonlinear susceptibility of CdS single crystal using a single beam,” J. Cryst. Growth138(1-4), 231–233 (1994). [CrossRef]
  13. T. D. Krauss and F. W. Wise, “Femtosecond measurement of nonlinear absorption and refraction in CdS, ZnSe, and ZnS,” Appl. Phys. Lett.65(14), 1739–1741 (1994). [CrossRef]
  14. H. P. Li, C. H. Kam, Y. L. Lam, and W. Ji, “Optical nonlinearities and photo-excited carrier lifetime in CdS at 532 nm,” Opt. Commun.190(1-6), 351–356 (2001). [CrossRef]
  15. Y. Nosaka, K. Tanaka, and N. Fujii, “Nonlinear optical susceptibility of ultrasmall CdS particles by means of the polarization-discriminated forward degenerate four-wave mixing in a resonant region,” Appl. Phys. Lett.62(16), 1863–1865 (1993). [CrossRef]
  16. N. Sugimoto, A. Koiwai, S. Hyodo, T. Hioki, and S. Noda, “Nonresonant third-order nonlinear optical susceptibility of CdS clusters encapsulated in zeolite A and X,” Appl. Phys. Lett.66(8), 923–925 (1995). [CrossRef]
  17. Yu. P. Rakovich, M. V. Artemyev, A. G. Rolo, M. I. Vasilevskiy, and M. J. M. Gomes, “Third-Order Optical Nonlinearities in Thin Films of CdS Nanocrystals,” Phys. Status Solidi224(1), 319–324 (2001) (b). [CrossRef]
  18. H. Du, G. Q. Xu, W. S. Chin, L. Huang, and W. Ji, “Synthesis, Characterization, and Nonlinear Optical Properties of Hybridized CdS−Polystyrene Nanocomposites,” Chem. Mater.14(10), 4473–4479 (2002). [CrossRef]
  19. M. Etienne, A. Biney, A. D. Walser, R. Dorsinville, D. L. V. Bauer, and V. Balogh-Nair, “Third-order nonlinear optical properties of a cadmiun sulfide-dendrimer nanocomposite,” Appl. Phys. Lett.87(18), 181913 (2005). [CrossRef]
  20. J. He, W. Ji, G. H. Ma, S. H. Tang, E. S. W. Kong, S. Y. Chow, X. H. Zhang, Z. L. Hua, and J. L. Shi, “Ultrafast and Large Third-Order Nonlinear Optical Properties of CdS Nanocrystals in Polymeric Film,” J. Phys. Chem. B109(10), 4373–4376 (2005). [CrossRef] [PubMed]
  21. Y. Yang, J. Shi, H. Chen, S. Dai, and Y. Liu, “Enhanced off-resonance optical nonlinearities of Au@CdS core-shell nanoparticles embedded in BaTiO3 thin films,” Chem. Phys. Lett.370(1-2), 1–6 (2003). [CrossRef]
  22. W. Jia, F. Guo, E. P. Douglas, and W. Sun, “Two-Photon Absorption and Degenerate Four-Wave Mixing Studies of Sulfide Semiconductor Nanoparticles in Polymeric Solutions,” J. Nanosci. Nanotechnol.8(3), 1364–1370 (2008). [PubMed]
  23. T. Okamoto, M. Haraguchi, and M. Fukui, “Numerical studies of optical switching and optical bistability phenomena of nano- or meso-size spheres,” J. Microsc.210(3), 193–197 (2003). [CrossRef] [PubMed]
  24. T. Okamoto, M. Haraguchi, and M. Fukui, “Light Intensity Enhancement and Optical Nonlinear Response due to Localized Surface Plasmons in Nanosize Ag Sphere,” Jpn. J. Appl. Phys.43(9A), 6507–6512 (2004). [CrossRef]
  25. M. Haraguchi, T. Okamoto, T. Inoue, M. Nakagaki, H. Koizumi, K. Yamaguchi, C. Lai, M. Fukui, M. Kamano, and M. Fujii, “Linear and Nonlinear Optical Phenomena of Metallic Nanoparticles,” IEEE J. Sel. Top. Quantum Electron.14(6), 1540–1551 (2008). [CrossRef]
  26. T. Okamoto, H. Koizumi, M. Haraguchi, M. Fukui, and A. Otomo, “Nonlinear optical response of a CdS-coated Ag particle,” Appl. Phys. Express1, 062003 (2008). [CrossRef]
  27. U. Kreibig and M. Vollmer, Optical Properties of Metal Crusters (Springer, 1995).
  28. P. B. Johnson and R. W. Christy, “Optical Constants of the Noble Metals,” Phys. Rev. B6(12), 4370–4379 (1972). [CrossRef]
  29. J. Gottesman and W. F. C. Ferguson, “Optical Properties of Thin Films of Cadmium Sulfide,” J. Opt. Soc. Am.44(5), 368–370 (1954). [CrossRef]
  30. A. Curry, G. Nusz, A. Chilkoti, and A. Wax, “Substrate effect on refractive index dependence of plasmon resonance for individual silver nanoparticles observed using darkfield microspectroscopy,” Opt. Express13(7), 2668–2677 (2005). [CrossRef] [PubMed]

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