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Optical Materials Express

Optical Materials Express

  • Editor: David Hagan
  • Vol. 4, Iss. 4 — Apr. 1, 2014
  • pp: 638–648

Broadband Cr3+-sensitized upconversion luminescence in La3Ga5GeO14: Cr3+,Yb3+,Er3+

S. Ye, E. H. Song, E. Ma, S. J. Zhang, J. Wang, X. Y. Chen, Q. Y. Zhang, and J. R. Qiu  »View Author Affiliations


Optical Materials Express, Vol. 4, Issue 4, pp. 638-648 (2014)
http://dx.doi.org/10.1364/OME.4.000638


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Abstract

Broadband-light-sensitized upconversion (UC) photon management phenomenon in La3Ga5GeO14:Cr3+,Yb3+,Er3+ is reported, featuring the concentrated broadband noncoherent light excitable at room temperature. Energy transfer among Cr3+/Yb3+/Er3+ in the Stokes and UC luminescence processes reveals that Yb3+ as a “bridge” is requisite for Cr3+-sensitized UC luminescence of Er3+. Low Cr3+ contents are preferred for UC luminescence of Yb3+-Er3+, since it would be quenched by high Cr3+ contents. The designed UC emissions 2H11/24I15/2 and 4S3/24I15/2 of Er3+ at around 510 ~560 nm are proposed to through Energy transfer upconversion (ETU) mechanism based on the Cr3+-Yb3+ dimer model with superexchange interaction according to crystallographic data and the decay curves of Er3+ UC emission. This research may open up a new perspective to design novel photonic materials excitable by broadband noncoherent light for improving the photoresponse of solar cells.

© 2014 Optical Society of America

OCIS Codes
(160.2540) Materials : Fluorescent and luminescent materials
(160.4670) Materials : Optical materials
(160.5690) Materials : Rare-earth-doped materials
(160.6990) Materials : Transition-metal-doped materials

ToC Category:
Fluorescent and Luminescent Materials

History
Original Manuscript: January 14, 2014
Revised Manuscript: March 2, 2014
Manuscript Accepted: March 2, 2014
Published: March 7, 2014

Citation
S. Ye, E. H. Song, E. Ma, S. J. Zhang, J. Wang, X. Y. Chen, Q. Y. Zhang, and J. R. Qiu, "Broadband Cr3+-sensitized upconversion luminescence in La3Ga5GeO14: Cr3+,Yb3+,Er3+," Opt. Mater. Express 4, 638-648 (2014)
http://www.opticsinfobase.org/ome/abstract.cfm?URI=ome-4-4-638


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