Adaptive feature specific spectroscopy for rapid chemical identification

doi:10.1364/OE.19.004595

Adaptive feature specific spectroscopy for rapid chemical identification

D. V. Dinakarababu, D. R. Golish, and M. E. Gehm »View Author Affiliations

Optics Express, Vol. 19, Issue 5, pp. 4595-4610 (2011)
http://dx.doi.org/10.1364/OE.19.004595

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Abstract
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References (25)
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Abstract

Spectroscopic chemical classification based on adaptive, feature-specific measurements has been implemented and demonstrated to provide significant performance gain over traditional systems. The measurement scheme and the decision model are discussed. A prototype system with a digital micro-mirror device as the adaptive element has been constructed and validates the theoretical findings and simulation results.

OCIS Codes
(300.6190) Spectroscopy : Spectrometers
(280.4788) Remote sensing and sensors : Optical sensing and sensors

ToC Category:
Spectroscopy

History
Original Manuscript: November 11, 2010
Revised Manuscript: February 11, 2011
Manuscript Accepted: February 21, 2011
Published: February 24, 2011

Virtual Issues
Vol. 6, Iss. 3 Virtual Journal for Biomedical Optics

Citation
D. V. Dinakarababu, D. R. Golish, and M. E. Gehm, "Adaptive feature specific spectroscopy for rapid chemical identification," Opt. Express 19, 4595-4610 (2011)
http://www.opticsinfobase.org/vjbo/abstract.cfm?URI=oe-19-5-4595

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References

Y. Sun, and K. Ong, Detection technologies for chemical warfare agents and toxic vapors (CRC, 2005).
W. Pearman, and A. Fountain, “Classification of chemical and biological warfare agent simulants by surfaceenhanced Raman spectroscopy and multivariate statistical techniques,” J. Appl. Spectrosc. 60(4), 356–365 (2006). [CrossRef]
H. Liu, Y. Chen, G. Bastiaans, and X. Zhang, “Detection and identification of explosive RDX by THz diffuse reflection spectroscopy,” J. Appl. Spectrosc. 43, 414–417 (2004).
H. Liu, H. Zhong, N. Karpowicz, Y. Chen, and X. Zhang, “Terahertz spectroscopy and imaging for defense and security applications,” Proc. IEEE 95(8), 1514–1527 (2007). [CrossRef]
K. Maquelin, T. van Vreeswijk, H. Endtz, B. Smith, R. Bennett, H. Bruining, and G. Puppels, “Raman spectroscopic method for identification of clinically relevant microorganisms growing on solid culture medium,” Anal. Chem. 72(1), 12–19 (2000). [CrossRef] [PubMed]
K. Maquelin, C. Kirschner, L. Choo-Smith, N. Van den Braak, H. Endtz, D. Naumann, and G. Puppels, “Identification of medically relevant microorganisms by vibrational spectroscopy,” J. Microbiol. Methods 51(3), 255–271 (2002). [CrossRef] [PubMed]
A. Manz, N. Graber, and H. Widmer, “Miniaturized total chemical analysis systems: a novel concept for chemical sensing,” Sens. Actuators B 1(1–6), 244–248 (1990). [CrossRef]
D. Harrison, P. Glavina, and A. Manz, “Towards miniaturized electrophoresis and chemical analysis systems on silicon: an alternative to chemical sensors,” Sens. Actuators B Chem. 10(2), 107–116 (1993). [CrossRef]
R. Kopelman, and W. Tan, “Near-field optical microscopy, spectroscopy, and chemical sensors,” Appl. Spectrosc. Rev. 29(1), 39–66 (1994). [CrossRef]
J. Chou, Y. Han, and B. Jalali, “Time-wavelength spectroscopy for chemical sensing,” IEEE Photon. Technol. Lett. 16(4), 1140–1142 (2004). [CrossRef]
H. Pal, D. Ganotra, and M. Neifeld, “Face recognition by using feature-specific imaging,” Appl. Opt. 44(18), 3784–3794 (2005). [CrossRef] [PubMed]
M. Neifeld, and P. Shankar, “Feature-specific imaging,” Appl. Opt. 42(17), 3379–3389 (2003). [CrossRef] [PubMed]
P. Fellgett, “Conclusions on multiplex methods,” J. Phys. Colloques 28, C2–165–C2–171 (1967). [CrossRef]
F. Robey, D. Fuhrmann, E. Kelly, and R. Nitzberg, “A CFAR adaptive matched filter detector,” IEEE Aerosp. Electron. Syst. 28(1), 208–216 (1992). [CrossRef]
I. Reed, R. Gagliardi, and L. Stotts, “Optical moving target detection with 3-D matched filtering,” IEEE Aerosp. Electron. Syst. 24(4), 327–336 (1988). [CrossRef]
S. Kay, Fundamentals of Statistical Signal Processing, Volume 2: Detection Theory (Prentice Hall PTR, 1998).
C. Helstrom, Statistical theory of signal detection (Pergamon Oxford, 1968).
T. Wickens, Elementary signal detection theory (Oxford University Press, USA, 2002).
A. Wald, Sequential analysis (Dover Pubns, 2004).
P. Armitage, “Sequential analysis with more than two alternative hypotheses, and its relation to discriminant function analysis,” J. R. Stat. Soc., B 12(1), 137–144 (1950).
I. Jolliffe, Principal component analysis (Springer verlag, 2002).
J. Ke, P. Baheti, and M. Neifeld, “Applications of adaptive feature-specific imaging,” Proc. SPIE 6575, 657505 (2007). [CrossRef]
Texas Instruments, .17 HVGA DMD Datasheet.
Multicomp Corporation, Multicomp RGB LED Array Datasheet.
M. Neifeld, A. Ashok, and P. Baheti, “Task-specific information for imaging system analysis,” J. Opt. Soc. Am. A 24(12), B25–B41 (2007). [CrossRef]

Armitage, P.
Ashok, A.
Baheti, P.
Bastiaans, G.
Bennett, R.
Bruining, H.
Chen, Y.
Choo-Smith, L.
Chou, J.
Endtz, H.
Fellgett, P.
Fountain, A.
Fuhrmann, D.
Gagliardi, R.
Ganotra, D.
Glavina, P.
Graber, N.
Han, Y.
Harrison, D.
Jalali, B.
Karpowicz, N.
Ke, J.
Kelly, E.
Kirschner, C.
Kopelman, R.
Liu, H.
Manz, A.
Maquelin, K.
Naumann, D.
Neifeld, M.
Nitzberg, R.
Pal, H.
Pearman, W.
Puppels, G.
Reed, I.
Robey, F.
Shankar, P.
Smith, B.
Stotts, L.
Tan, W.
Van den Braak, N.
van Vreeswijk, T.
Widmer, H.
Zhang, X.
Zhong, H.

Anal. Chem.

K. Maquelin, T. van Vreeswijk, H. Endtz, B. Smith, R. Bennett, H. Bruining, and G. Puppels, “Raman spectroscopic method for identification of clinically relevant microorganisms growing on solid culture medium,” Anal. Chem. 72(1), 12–19 (2000). [CrossRef] [PubMed]

Appl. Opt.

Appl. Spectrosc. Rev.

R. Kopelman, and W. Tan, “Near-field optical microscopy, spectroscopy, and chemical sensors,” Appl. Spectrosc. Rev. 29(1), 39–66 (1994). [CrossRef]

IEEE Aerosp. Electron. Syst.

F. Robey, D. Fuhrmann, E. Kelly, and R. Nitzberg, “A CFAR adaptive matched filter detector,” IEEE Aerosp. Electron. Syst. 28(1), 208–216 (1992). [CrossRef]
I. Reed, R. Gagliardi, and L. Stotts, “Optical moving target detection with 3-D matched filtering,” IEEE Aerosp. Electron. Syst. 24(4), 327–336 (1988). [CrossRef]

IEEE Photon. Technol. Lett.

J. Chou, Y. Han, and B. Jalali, “Time-wavelength spectroscopy for chemical sensing,” IEEE Photon. Technol. Lett. 16(4), 1140–1142 (2004). [CrossRef]

J. Appl. Spectrosc.

W. Pearman, and A. Fountain, “Classification of chemical and biological warfare agent simulants by surfaceenhanced Raman spectroscopy and multivariate statistical techniques,” J. Appl. Spectrosc. 60(4), 356–365 (2006). [CrossRef]
H. Liu, Y. Chen, G. Bastiaans, and X. Zhang, “Detection and identification of explosive RDX by THz diffuse reflection spectroscopy,” J. Appl. Spectrosc. 43, 414–417 (2004).

J. Microbiol. Methods

K. Maquelin, C. Kirschner, L. Choo-Smith, N. Van den Braak, H. Endtz, D. Naumann, and G. Puppels, “Identification of medically relevant microorganisms by vibrational spectroscopy,” J. Microbiol. Methods 51(3), 255–271 (2002). [CrossRef] [PubMed]

J. Opt. Soc. Am. A

M. Neifeld, A. Ashok, and P. Baheti, “Task-specific information for imaging system analysis,” J. Opt. Soc. Am. A 24(12), B25–B41 (2007). [CrossRef]

J. Phys. Colloques

P. Fellgett, “Conclusions on multiplex methods,” J. Phys. Colloques 28, C2–165–C2–171 (1967). [CrossRef]

J. R. Stat. Soc., B

P. Armitage, “Sequential analysis with more than two alternative hypotheses, and its relation to discriminant function analysis,” J. R. Stat. Soc., B 12(1), 137–144 (1950).

Proc. IEEE

H. Liu, H. Zhong, N. Karpowicz, Y. Chen, and X. Zhang, “Terahertz spectroscopy and imaging for defense and security applications,” Proc. IEEE 95(8), 1514–1527 (2007). [CrossRef]

Proc. SPIE

J. Ke, P. Baheti, and M. Neifeld, “Applications of adaptive feature-specific imaging,” Proc. SPIE 6575, 657505 (2007). [CrossRef]

Sens. Actuators B

A. Manz, N. Graber, and H. Widmer, “Miniaturized total chemical analysis systems: a novel concept for chemical sensing,” Sens. Actuators B 1(1–6), 244–248 (1990). [CrossRef]

Sens. Actuators B Chem.

D. Harrison, P. Glavina, and A. Manz, “Towards miniaturized electrophoresis and chemical analysis systems on silicon: an alternative to chemical sensors,” Sens. Actuators B Chem. 10(2), 107–116 (1993). [CrossRef]

Other

I. Jolliffe, Principal component analysis (Springer verlag, 2002).
S. Kay, Fundamentals of Statistical Signal Processing, Volume 2: Detection Theory (Prentice Hall PTR, 1998).
C. Helstrom, Statistical theory of signal detection (Pergamon Oxford, 1968).
T. Wickens, Elementary signal detection theory (Oxford University Press, USA, 2002).
A. Wald, Sequential analysis (Dover Pubns, 2004).
Texas Instruments, .17 HVGA DMD Datasheet.
Multicomp Corporation, Multicomp RGB LED Array Datasheet.
Y. Sun, and K. Ong, Detection technologies for chemical warfare agents and toxic vapors (CRC, 2005).

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